Printable Functional Materials

Potential technical applications of printable functional inks.

The videos and information in this post relate to an ECS Journal of Solid State Science and Technology focus issue called: Printable Functional Materials for Electronics and Energy Applications.

(Read/download the focus issue now. It’s entirely free.)

Printing technologies in an atmospheric environment offer the potential for low-cost and materials-efficient alternatives for manufacturing electronics and energy devices such as luminescent displays, thin-film transistors, sensors, thin-film photovoltaics, fuel cells, capacitors, and batteries. Significant progress has been made in the area of printable functional organic and inorganic materials including conductors, semiconductors, and dielectric and luminescent materials.

These new printable functional materials have and will continue to enable exciting advances in printed electronics and energy devices. Some examples are printed amorphous oxide semiconductors, organic conductors and semiconductors, inorganic semiconductor nanomaterials, silicon, chalcogenide semiconductors, ceramics, metals, intercalation compounds, and carbon-based materials.

A special focus issue of the ECS Journal of Solid State Science and Technology was created about the publication of state-of-the-art efforts that address a variety of approaches to printable functional materials and device. This focus issue, consisting of a total of 15 papers, includes both invited and contributed papers reflecting recent achievements in printable functional materials and devices.

The topics of these papers span several key ECS technical areas, including batteries, sensors, fuel cells, carbon nanostructures and devices, electronic and photonic devices, and display materials, devices, and processing. The overall collection of this focus issue covers an impressive scope from fundamental science and engineering of printing process, ink chemistry and ink conversion processes, printed devices, and characterizations to the future outlook for printable functional materials and devices.

The video below demonstrates Printed Metal Oxide Thin-Film Transistors by J. Gorecki, K. Eyerly, C.-H. Choi, and C.-H. Chang, School of Chemical, Biological and Environmental Engineering, Oregon State University.

Step-by-step explanation of the video:

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Researchers believe that as work continues in relation to this study, battery technology will accelerate forward.Image: Stony Brook University

Researchers believe that as work continues in relation to this study, battery technology will accelerate forward.
Image: Stony Brook University

A collaborative group of six researchers from Stony Brook University and Brookhaven National Laboratory are using pioneering x-ray techniques to build a better and more efficient battery.

The researchers—four of whom are active ECS members, including Esther Takeuchi, Kenneth Takeuchi, Amy Marschilok, and Kevin Kirshenbaum—have recently published their internal mapping of atomic transformations of the highly conductive silver matrix formation within lithium-based batteries in the journal Science.

(PS: You can find more of these scientists’ cutting-edge research by attending the 228th ECS Meeting in Phoenix, where they will be giving presentations. Also, Esther Takeuchi will be giving a talk at this years Electrochemical Energy Summit.)

This from Stony Brook University:

In a promising lithium-based battery, the formation of a silver matrix transforms a material otherwise plagued by low conductivity. To optimize these multi-metallic batteries—and enhance the flow of electricity—scientists need a way to see where, when, and how these silver, nanoscale “bridges” emerge. In the research paper, the Stony Brook and Brookhaven Lab team successfully mapped this changing atomic architecture and revealed its link to the battery’s rate of discharge. The study shows that a slow discharge rate early in the battery’s life creates a more uniform and expansive conductive network, suggesting new design approaches and optimization techniques.

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U.S. Begins Utilizing Hydro Power (Video)

The United States has focused the majority of its solar energy efforts on solar and wind power for the grid. For the first time ever, wave power is being utilized in the U.S. to power homes off the coast of Hawaii.

Waves are being turned into electricity through the Azura prototype, which captures the complex motion of waves to more efficiently capture wave movement for better electricity generation.

The device, which was deployed last month, will be monitored for one year to measure effectiveness and efficiency. If all goes as well as researchers predict, a larger version will hit the seas in 2017.

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Chemical Bonds On-Demand

PhysRevLett.114.233003

Tailored laser pulse controls the formation of a molecular bond between two atoms.
Image: Christiane Koch

Until now, the idea of controlling reactions with the light from lasers was only theoretical. However, new research shows that a laser pulse has the ability to control the formation of a molecular bond between two atoms.

Due to this new development, researchers can now control the path of the chemical process with extreme precision.

This from APS Physics:

For the first time, researchers demonstrate the coherent control of the reaction by which two atoms form a molecule. The achievement—coupled with other photocatalyst tools—could potentially lead to a chemical assembly line, in which lasers slice and weld molecular pieces into a desired end product.

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The new solar cell developed by the University of Texas at Arlington team is more efficient and can store solar energy at night.
Image: UT Arlington

A research team from the University of Texas at Arlington comprised of both present and past ECS members has developed a new energy cell for large-scale solar energy storage even when it’s dark.

Solar energy systems that are currently in the market and limited in efficiency levels on cloudy days, and are typically unable to convert energy when the sun goes down.

The team, including ECS student member Chiajen Hsu and two former ECS members, has developed an all-vanadium photoelectrochemical flow cell that allows for energy storage during the night.

“This research has a chance to rewrite how we store and use solar power,” said Fuqiang Liu, past member of ECS and assistant professor in the Materials Science and Engineering Department who led the research team. “As renewable energy becomes more prevalent, the ability to store solar energy and use it as a renewable alternative provides a sustainable solution to the problem of energy shortage. It also can effectively harness the inexhaustible energy from the sun.”

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Nanogenerator Harvests Power from Tires

During initial trials, the team tested the nanogenerator's capabilities on a toy car with LED lights.Image: UW-Madison College of Engineering

During initial trials, the team tested the nanogenerator’s capabilities on a toy car with LED lights.
Image: UW-Madison College of Engineering

Earlier this year, the company Goodyear announced its concept of a tire that can harvest heat in a variety of ways to help power electric vehicles. Since then, researchers from the University of Wisconsin-Madison have been hard at work on their own accord to develop a tire that can harvest the typically wasted power produced from friction.

A team of UW-Madison researchers got together, led by Dr. Xudong Wang, to develop a nanogenerator that has the ability to harvest the energy from a car’s rolling tire friction, which will potentially make care tires a much more efficient product.

Find the paper in the journal Nano Energy, and take a look at Wang’s past paper, “3D Nanowire Architectures for Highly-Efficient Photoelectrochemical Anodes,” published in ECS Transactions.

This from UW-Madison:

The nanogenerator relies on the triboelectric effect to harness energy from the changing electric potential between the pavement and a vehicle’s wheels. The triboelectric effect is the electric charge that results from the contact or rubbing together of two dissimilar objects.

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Researchers aim to assess the economic and technical feasibility of these luminescent solar concentrators. Image: Eindhoven University of Technology

Researchers aim to assess the economic and technical feasibility of these luminescent solar concentrators.
Image: University of Technology

The Netherlands is making a push toward renewable energy sources with their new testing of solar energy generating noise barriers, which will be installed along highways. Researchers are currently testing the first phase of these energy storage devices, which generate electricity using solar cells integrated in noise barriers.

Researchers from Eindhoven University of Technology have implemented luminescent solar concentrators (LSCs) that are aesthetically attractive and should lead to promising energy efficiency levels.

“Further benefits are that the principle used is low cost, they can be produced in any desired, regular color, is robust, and the LSCs will even work when the sky is cloudy. That means it offers tremendous potential,” said Michael Debije of Eindhoven University of Technology’s Department of Chemical Engineering and Chemistry.

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The new structure has high mobility of Na+ ions and a robust framework.Ia

The new structure has high mobility of Na+ ions and a robust framework.
Image: Nature Communications

With the demand for hand-held electronics at an all-time high, the costs of the materials used to make them are also rising. That includes materials used to make lithium batteries, which is a cause for concern when projecting the development of large-scale grid storage.

In order to find an alternative solution to the high material costs connected with lithium batteries, the researchers at the Australian Nuclear Science and Technology Organisation (ANSTO) and the Institute of Physics at the Chinese Academy of Science in Beijing have begun focusing their attention on sodium-ion batteries.

The science around sodium-ion batteries dates back to the 1980s, but the technology never took off due to resulting low energy densities and short life cycles.

However, the new research looks to combat those issues by improving the properties of a class of electrode materials by manipulating their electron structure in the sodium-ion battery.

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Researcher from Stanford University have developed a new device that has made water-splitting more practical and boosted efficiency levels to an unprecedented 82 percent.

With just one catalyst, the novel water-splitting device can continuously generate hydrogen and oxygen for more than 200 hours with a steady input of just 1.5 volts of electricity.

Through this new device, researchers can produce renewable sources of clean-burning hydrogen fuel.

The Stanford researchers are using just one catalyst instead of the traditional two in water-splitting processes, which allows the cost to drop significantly.

“For practical water splitting, an expensive barrier is needed to separate the two electrolytes, adding to the cost of the device. But our single-catalyst water splitter operates efficiently in one electrolyte with a uniform pH,” said Haotian Wang, lead author of the study and graduate student at Stanford.

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Alvin J. Salkind

Alvin J. Salkind in an undated photo.

“My nature is curiosity and The Electrochemical Society has gone a long way to satisfy my curiosity…” — A. Salkind

About two years ago, ECS began a conversation with Prof. Salkind about his proposal for a revised edition of Alkaline Storage Batteries. In the proposal we presented to John A. Wiley & Sons (our partner in publishing monographs), I said it was from “one of the ECS ‘giants’.”

That was quite true about Dr. Salkind. When I first met him (and ever after), I was engaged by his tremendous intellect, his wide-ranging curiosity, and his still being very much involved with his science.

Prof. Salkind was an emeritus member of ECS, having joined in 1952 as a student. He served the Society very well — as a Chair of our Battery Division and on an innovative committee called the New Technology Subcommittee. He became an ECS Fellow only in 2014, but over the course of his many years of involvement with ECS, he organized symposia, edited proceedings volumes, and chaired many committees.

Alkaline-Storage-Batteries

Cover of the Alkaline Storage Batteries book from 1969

In conjunction with developing a new edition of the Alkaline Storage Batteries book, Prof. Salkind began visiting ECS headquarters. We were immediately drawn in by his still-vibrant enthusiasm for the field and his fascinating anecdotes about other ECS notables in the field: Vladimir Bagotsky, Ernest Yeager, and Vittorio de Nora, among others. He was always willing to teach and to share. We were very fortunate to be able to “capture” Prof. Salkind in a very recent interview at the HQ office.

(Listen to it as a podcast. Watch the video.)

Professor Salkind generously considered ECS his technological home and brought his important monograph to be published by ECS. ECS is grateful to Dr. Salkind for his years of service to the Society and his contributions to the entire battery community; and we thank his family for supporting this remarkable person and sharing him with ECS.