197th Meeting - Toronto, Ontario, Canada

May 14-18, 2000


R1 - Electrochemistry in the Preparation of Fluorine and Its Compounds

Industrial Electrolysis and Electrochemical Engineering Division/ Organic and Biological Electrochemistry Division

Wednesday, May 17, 2000

Civic Ballroom North, 2nd Floor

Fluorine Production

Co-Chairs: C.L. Gross and T. Fuchigami

10:001003 An Overview of the Fluorine Preparation Process - H. Groult, D. Devilliers (Universite P. & M. Curie), and F. Nicolas (Comurhex-Cogema) PDF
10:351004 Advances in Science and Technology for the Electrochemical Preparation of Fluorine - T. Tojo (Toyo Tanso Co., Ltd.) PDF
11:101005 Fluorine Production in a Proton Exchange Membrane Reactor - R. Lowrey, T. Anderson (University of Florida), and M. Doyle (DuPont) PDF

Electrodes and Cell Processes

Co-Chairs: T. Fuchigami and C.L. Gross

2:001006 Understanding Simons Electrochemical Fluorination - W.V. Childs, C. Gross, and S. Polson (3M Fluoromaterials Research Group) PDF
2:251007 Electrochemical and Spectroscopic Studies of Polycrystalline Nickel Surfaces with Relevance to the Simons Electrochemical Fluorination Process - G. Totir, G. Chottiner, D.A. Scherson (Case Western Reserve University), C. Gross, and V. Childs (3M Chemicals) PDF
2:501008 Multiple Steady State and Transient Simulations of a Simons Gas-Liquid Electrochemical Reactor - J.A. Drake, C.J. Radke, and J. Newman (University of California, Berkeley) PDF
3:15 Fifteen-Minute Intermission
3:301009 Effect of CsF and HF Concentrations on Anodic Behavior of Nickel in the Mixed Melts of (Ch3)4NF-mHF and CsF-2HF - A. Tasaka, T. Kimura, J. Yamashita (Doshisha University), and K. Momota (Morita Chemicals Industries Co. Ltd.) GIF
3:551010 Electrochemical Fluorination of Metals - Y. Matsuo, T. Kakiya, and Y. Sugie (Himeji Institute of Technology) PDF
4:201011 Application of Diamond Electrodes to Electrochemical Fluorination - F. Okino, S. Kawasaki, H. Touhara (Shinshu University), K. Momota (Morita Chemical Industries Co. Ltd.), M. Nishitani-Gama, I. Sakaguchi, and T. Ando (National Institute for Research in Organic Materials) GIF
4:451012 Active, Passive and Inert Electrodes in Fluorine Elecrochemistry. Some Receent Studies in Triethylamine-Tris Hydrogen Fluorine - M. Noel (Central Electrochemical Research Institute) GIF

Civic Ballroom South, 2nd Floor

Reception (5:30 PM - 7:00 PM)

Co-Chairs: C.L. Gross and T. Fuchigami

7:00 Symposium Reception

Thursday, May 18, 2000

Civic Ballroom North, 2nd Floor

Anodic Substitution and Molecular Conversion

Co-Chairs: C.L. Gross and T. Fuchigami

8:301013 Electrolytic Partial Fluorination of Pyridine and Bipyridyl Derivatives - A. Konno and H. Takeuchi (Shizuoka University) PDF
8:551014 Marked Solvent Effects on Selective Anodic Fluorination of Heterocyclic Sulfides - T. Fuchigami and Y. Hou (Tokyo Institute of Technology) GIF
9:201015 Anodic Oxidative Fluorination of Phenols in HF-Base Electrolyte - N. Yoneda and T. Fukuhara (Hokkaido University) PDF
9:451016 Electrochemical Synthesis of Fluorinated Organo-Phosphorus Compounds via Simons Process - N. Ignatiev, P. Sartori (Gerhard-Mercator-University Duisburg), U. Heider, and V. Hilarius (Merck KGaA) PDF
10:10 Fifteen-Minute Intermission
10:251017 Nickel-Catalyzed Electrochemical Carbon Dioxide Incorporation into Perfluoroalkyl Derivatives - E. Dunach (Universite de Nice) PDF
10:501018 Selective Electrosynthesis and Reactivity of New Fluorosilyl Synthons: Conditions for a Scale Extension - M. Bordeau, P. Clavel, C. Biran (Universite Bordeaux 1), N. Roques (Rhodia), S. Trevin (EDF), and D. de Montauzon (CNRS) PDF
11:151019 An Electrochemical Approach for the Synthesis of Fluorinated Heterocycles - M. Medebielle (Universite Paris) PDF
11:401020 Syntezis Perfluorophenylalkyl Ethers by the Crossed Anodic Condensation of Perfluorocarboxylic Acids With Perfluorophenols - V.V. Berenblit (State S.V.Lebedev Synthetic Rubber Research Institute) and E.S. Panitkova (Jerusalem University) PDF