197th Meeting - Toronto, Ontario, Canada

May 14-18, 2000


U1 - Scale-Up in Organic and Pharmaceutical Electrosynthesis

Organic and Biological Electrochemistry Division/ Industrial Electrolysis and Electrochemical Engineering Division

Thursday, May 18, 2000

Simcoe/Dufferin Rooms, 2nd Floor

Co-Chairs: D.J. Mazur and H. Ohmori

8:001074 Effect of Heteroatoms on Intramolecular Cyclization of Non-Conjugated Enones by Electrochemical Reductions - I. Nishiguchi, S. Goda, and H. Maekawa (Nagaoka University) GIF
8:301075 Selective Alkene Hydrogenation with Atomic Hydrogen Permeating Through a Pd Sheet Electrode - S. Maki, Y. Harada, R. Matsui, T. Hirano, H. Niwa (The University of Electro-Communications), Y. Yoshida, S. Ogata, S. Nakamatsu (Permelec Electro de LTD. Endo), H. Inoue, and C. Iwakura (Osaka Prefecture University) GIF
9:001076 Electrochemical Carboxylation of Organic Compounds Using Fluidized Electrochemical Cell - H. Senboku, Y. Fujimura, D. Kuboshima, A. Sasaki, and M. Tokuda (Hokkaido University) GIF
9:151077 The Reduction of L-Cystine Hydrochloride: From Laboratory Kinetics to Process Modelling - F.C. Walsh (University of Portsmouth), T.R. Ralph (Johnson Matthey Technology Centre), M.L. Hitchman (University of Strathclyde), and J.P. Millington (UMIST) PDF

Co-Chairs: I. Nishiguchi and H. Tanaka

10:001078 The Electrocatalytic Role of Silver in Organic Halide Reactions - S.B. Rondinini, P.R. Mussini, F. Crippa, and G. Sello (The University of Milan) PDF
10:301079 Poly(p-phenylene Terephthalamide Film as a Matrix Film for Immobilization of Aminobenzenesulfonic Acids Oligomers - J. Yano, K. Furuya, M. Teraoka, C. Hata, and S. Yamasaki (University of East Asia) GIF
11:001080 Magnetoelectropolymerization of Pyrrole and Its Application to a Modified Electrode - I. Mogi, K. Watanabe, and M. Motokawa (Tohoku University) GIF
11:301081 Ultrasonic Effects on Electroorganic Processes. Part 42. Product Selectivity Control in Reductive Homo- and Cross-Coupling of Acrylonitrile - M. Atobe, M. Sasahira, and T. Nonaka (Tokyo Institute of Technology) PDF
11:451082 Synthetic Application of Acyl Phosphonium Ions - H. Ohmori and H. Maeda (Osaka University) PDF

Co-Chairs: P. Tatapudi and M. Tokuda

1:301083 Novel Catalytic System for One-Electron Reduction. Vanadium-Catalyzed Highly Diastereoselective Pinacol Coupling - T. Hirao, B. Hatano, M. Asahara, and A. Ogawa (Osaka University) GIF
2:001084 Lithium Perchlorate / Nitromethane as an Effective Electrochemical Reaction Medium for the Intermolecular C-C Bond Formations - K. Chiba (Tokyo University of Agriculture and Technology) PDF
2:301085 Electrosynthesis of Dicyan (Cyanogen and/or Oxalonitrile)for Manufacturing of Bistetrazole Inflating Agents - S. Torii (The Institute of Creative Chemistry Co. Ltd.), Y. Kubo, Y. Miyawaki (Masuda Chem. Ind. Co. Ltd.), and H. Tanaka (Okayama University) PDF
2:451086 Use of 2,2,2-Trifluoroethanol as a Substrate and a Solvent in Electrochemical Oxidation - Y. Matsumura, O. Onomura, T. Maki, and K. Shirai (Nagasaki University) GIF
3:00 Thirty-Minute Intermission
3:301087 N-Oxyl Mediated Oxidation of Alcohol in an Aqueous Silica Gel Disperse Electrolysis System - H. Tanaka, Y. Kawakami, K. Goto, and M. Kuroboshi (Okayama University) PDF

Co-Chairs: P.N. Pintauro and Y.M. Matsumura

4:001088 Oxidation of Phenol in an Electrochemical Flow Cell - W. O'Grady (Naval Research Laboratory), P. Hagans (NSWC Carderock), B. Stoner (University of North Carolina), and P. Natishan (Naval Research Laboratory) PDF
4:301089 Pilot Plant Scale-Up of a Pharmaceutical Intermediate - G.D. Zappi, N.L. Weinberg, D. Genders, D. Chai (The Electrosynthesis Company, Inc.), D. Walker, J. Lee (Schering-Plough Research Institute), E. Bernasconi, L. Sogli, J. Roletto (Antibi oticos S.A.), C. Martin, P. Zelenay, V. Menon, and H. Zhang (Colorado State University) PDF
5:001090 Electroorganic Synthesis in Low Ionic Strength Media at Zeolite-Supported Nanoelectrodes - V. Cepak and D. Rolison (Naval Research Laboratory) PDF
5:301091 An Efficient Preparation and Electrochemical Behavior of Azulenylquinodimethanes and Their Related Compounds - S.-I. Takekuma (Kinki University) GIF
5:451092 Stereospecific Ring Cleavage of 3-Chloro-2 Substituted Tetrahydrofurans by Electroreduction - I. Nishiguchi, H. Honma, H. Maekawa, and M. Wada (Nagaoka University of Technology) GIF