201st Meeting - Philadelphia, PA
May 12-17, 2002
PROGRAM INFORMATION
AG1 - Thirteenth International Symposium On Molten Salts
Physical Electrochemistry/High Temperature Materials/Electrodeposition
Monday, May 13, 2002
Salon D, Level 5
Power Applications of Molten Salts
Co-Chairs: H.C. De Long and P.C. Trulove
Power Applications of Molten Salts
Co-Chairs: H.C. De Long and P.C. Trulove
Time | Abs# | Title |
1:40 | 1387 |
Direct X-ray Evidence of Electrochemical Induced Intercalation of Substituted Alkylimidazolium and Lithium Cations into Graphite from Ambient-Temperature Ionic Liquids - P. Trulove (Air Force Office of Scientific Research), H.
DeLong, and T. Sutto (Naval Research Laboratory and U.S. Naval Academy Chemistry Department) |
2:00 | 1388 |
Ion Transport in Ionic-Liquid/Polymer Gel Electrolytes - R. Mantz
(AFRL/MLBT), T. Sutto (Naval Research Laboratory), H. De Long (US Naval Academy), and P. Trulove
(AFOSR/NL) |
2:20 | 1389 |
Electrochemistry of Nonporous Ni/NiCl2 Electrode in Chloroaluminate Melt - J. Prakash (Illinois Institute of Technology) |
2:40 | 1390 |
Ionic Liquids as Thermal Fluids - R. Vaughn, M.
Mutch, and J. Wilkes (USAF Academy) |
3:00 | 1391 |
Proton Conduction of RTMS - Acid System - S.
Mitsushima, K. Kudo, R. Sakamoto, A. Noda, Y. Takeoka, N. Kamiya, M. Watanabe, and K.-I. Ota (Yokohama National University) |
3:20 | 1392 |
Mechanisum of Electrowetting of Molten Carbonate - K. Asano (Central Research Institute of Electric Power Industry) |
3:40 | |
Twenty-Minute Intermission - |
Molten Salts in Synthesis, Catalysis, and Green Processes
Co-Chairs: P.C. Trulove and H.C. De Long
Tuesday, May 14, 2002
Molten Salts in Synthesis, Catalysis, and Green Processes
Co-Chairs: J. Fuller and T. Sutto
Time | Abs# | Title |
8:00 | 1398 |
Improved Thermal Stability of Imidazolium Treatments for Polymer Layered-Silicate Nanocomposites - J. Gilman, W.
Awad, R. Davis (National Institute of Standards and Technology), T. Sutto (Naval Research Laboratory), C. Davis (National Institute of Standards and Technology), P. Trulove (Air Force Office of Scientific Research), A. Morgan (National Institute of Standards and Technology), H. DeLong (US Naval Academy), L. Mathias (University of Southern Mississippi), and D. Schiraldi
(KOSA) |
8:20 | 1399 |
Thermal Degradation Studies of Trialkyl-Imidazolium Salts and Their Application in Nanocomposites - W.
Awad, J. Gilman, M. Nyden, R. Davis, R. Harris (National Institute of Standards and Technology), T.
Sutto, J. Callahan (Naval Research Laboratory), P. Trulove (Air Force Office of Scientific Research), and H. Delong (US Naval Academy) |
8:40 | 1400 |
Transition Metal Catalyzed CO/OLEF in Co-Polymerization in Room Temperature Ionic Liquids - J.
Holbrey, K. Shaughnessy, M. Klingshirn, G. Broker, and R. Rogers (The University of Alabama) |
9:00 | 1401 |
Catalytic Oxidations and Comparative Kinetics in Room-Temperature Ionic Liquids - M. Abu-Omar, G. Owens, and A. Durazo (University of California- Los Angeles) |
9:20 | 1402 |
Bioelectrocatalytic Reactions in Room Temperature Ionic Liquids - D. Compton and J. Laszlo (United States Department of Agriculture) |
9:40 | 1403 |
Humidity Effects on Facilitated Gas Separations Using Immobilized Ionic Liquid Membranes - P. Scovazzo (University of Colorado), D. DuBois (National Renewable Energy Laboratory), C.
Koval, and R. Noble (University of Colorado) |
10:00 | 1404 |
Preferential Solvation within Binary and Ternary Solutions Containing Room-Temperature Ionic Liquids -
K.A. Fletcher, A.E. Hendricks, and S. Pandey (The New Mexico Institute of Mining and Technology) |
10:20 | 1405 |
A Corrosion Study of Stainless Steels in Ionic Liquids - A. Doherty and A. FitzGerald (Queen's University) |
10:40 | |
Thirty-Minute Intermission - |
High Temperature Molten Salts
Co-Chairs: A. Kiszra and G. Kaptay
Time | Abs# | Title |
1:40 | 1406 |
Molten Salt Oxidation: A Reassessment of its Supposed Catalytic Mechanism and hence its Development for the Disposal of Waste Automotive Tires - T. Griffiths (University of Leeds), V. Volkovich (University of Manchester), and E. Anghel (Institute of Physical Chemistry) |
2:00 | 1407 |
Molten Salt Electrolytes and Performance of Electrocatalytical Membrane Cells for Flue Gas Cleaning. -
S.B. Rasmussen, K.M. Eriksen (Technical University of Denmark), J. Winnick (Georgia Institute of Technology), and R. Fehrmann (Technical University of Denmark) |
2:20 | 1408 |
In situ Raman Spectroscopic Study of Supported Molten Salt Catalysts During SO_2 Oxidation - I. Giakoumelou
(Univeristy of Patras), R.M. Caraba, V. Parvulescu (University of Bucharest), and S. Boghosian
(Univeristy of Patras) |
2:40 | 1409 |
Molecular Dynamic Investigation of Three-dimensional Anionic Structures of Molten Al2O3-Na2O-SiO2 - Y. Sasaki, R. Asano, and K. Ishi (Hokkaido University) |
3:00 | 1410 |
Electrical Conductivity and Transference Number Measurements of FeO - CaO - MgO - SiO_2 Melts - A. Ducret and D. Sadoway (Massachusetts Institute of Technology) |
3:20 | 1411 |
Lewis Acid-based Equilibrium Effects on Volatility of Aluminum and Gallium Tetrachlorides in Molten NaCl-AlCl 3-GaCl 3 Mixtures and on Ga/Al Separation Factor -
A.B. Salyulev, N.T. Moskalenko, and A.L. Bovet (Institute of High-Temperature Electrochemistry) |
3:40 | |
Twenty-Minute Intermission - |
4:00 | 1412 |
Investigation of Melts Containing Na2CO3, Na2SO4, Na2S/Na2Sx and Na2O/Na2O2 for the Electrolytic Recycle of Pulping Chemicals - R. Wartena, J. Winnick (Georgia Institute of Technology), and P. Pfromm (Institute of Paper Science and Technology) |
4:20 | 1413 |
Thermodynamics of Gallium Chlorides Formation in the Low-Temperature Melts - A.L. Bovet, V.S. Mityaev, V.V. Smolenski, N.P. Borodina (Institute of High-Temperature Electrochemistry), A.G. Ossipenko, and A.V. Bychkov (Scientific Research of Atomic Reactors) |
4:40 | 1414 |
Low-Melting Salt Mixtures Data: Errors in Concentration Coordinates - V. Lutsyk (Buryat Scientific Center of the RAS) |
5:00 | 1415 |
The Influence of Passivation and Adsorption Phenomena on the Mechanism of Electrode Processes of Some Metals (Cu, Pt, Nb, Ta, Ti, W) in Low-temperature Carbamide-containing Melts - T. Nelly, V. Sergey, K. Svitlana, B. Nikolay, and B. Eugen (National Academy of Sciences of Ukraine) |
Franklin Hall, Level 4
Co-Chairs: R. Mantz and M. Matsunaga
Time | Abs# | Title |
o | 1416 |
High-energy X-ray Diffraction Studies of Room Temperature Molten Salts at SPring-8 High-energy X-ray Diffraction Beamline BL04B2 - S. Kohara (Japan Synchrotron Radiation Research Institute), R. Hagiwara, K. Matsumoto, Y. Ito (Kyoto University), A. Kajinami (Kobe University), and K. Suzuya (Japan Atomic Energy Research Institute) |
o | 1417 |
Physical and Electrochemical Properties of Room Temperature Molten Salt Based on Aliphatic Onium Cations and Asymmetric Amide Anion - H. Matsumoto, H. Kageyama, and Y. Miyazaki (National Institute of Advanced Industrial Science and Technology) |
o | 1418 |
Comparative Electrochemical Behavior of 1,2-Dimethyl-3-n-Propylimidazoium Trifluoromethanesulfonyl-imide, 1,2-Dimethyl-3-n-Butylimidazoium Trifluoromethanesulfonyl-imide, and 1,2-Dimethyl-3-n-Butylimidazoium - T. S, H. DeLong (Naval Reserach Laboratory and U.S. Naval Academy), and P. Trulove (Air Force Office of Scientific Research) |
o | 1419 |
Model Structure of Alkali Metal Chloride Melts - V. Kremenetsky (Institute of Chemistry) |
o | 1420 |
Relationship between Electrical Conductivity and Thermodynamic Properties of Binary Molten Salt Mixtures - A. Redkin (Institute of High Temperature Electrochemistry) |
o | 1421 |
Interaction of Rare-Earth Fluorides with Zirconium and Lead-Sodium alloys in Molten Mixtures of Alkalyl Metal Fluorides - R. Savcuk, A. Omelchuk, N. Kompanichenko (The Ukrainian National Academy of Sciences), and P. Nagornyi (Taras Shevchenko National University of Kyiv) |
o | 1422 |
Electrochemical Behavior of Some Lanthanides in Imide Room Temperature Molten Salt Systems - M. Yamagata, Y. Katayama, and T. Miura (Keio University) |
o | 1423 |
Functionalized Ionic Liquids - S. Handy, M. Okello, G. Dickenson, and C. Egire (State University of New York) |
o | 1424 |
Study of the Morphology of TiB_2 Coatings on Molybdenum Substrates Electrodeposited from a NaCl-KCl-NaF-K2TiF6-NaBF4 Melt at 700°C - M.F. Souto (Austrian Research Center Seibersdorf), J. Sytchev (University of Miskolc), A. Koepf, G.E. Nauer (Austrian Research Center Seibersdorf), and G. Kaptay (University of Miskolc) |
o | 1425 |
Investigation of Kinetics of Electrode Processes in Halide Melts, Containing Berylllum, Vanadium, Niobium, and Hafnium - O. Rebrin, R. Scherbakov, I. Polovov, S. Mihalev, and V. Volkovich (Ural State Technical University) |
o | 1426 |
Electrodeposition of Zinc from Lewis Basic 1-Ethyl-3-Methylimidazolium Bromide - Zinc Bromide Molten Salt - H. Yamamoto, T. Iwagishi, K. Koyama, H. Shirai (Himeji Institute of Technology), and H. Kobayashi (Sanko Chemical Industry Co.) |
o | 1427 |
Joint Electrodeposition of Molybdenum and Tungsten and Molybdenum-tungsten Alloys Production from Oxihalide Melts - K. Kushkhov, L. Beroeva, and R. Karashaeva (Kabardino-Balkarian State University) |
o | 1428 |
Electrochemical Deposition of Aluminum at Vitreous Carbon in a Room-Temperature Molten Salt - G. Cheek (United States Naval Academy) |
o | 1429 |
Raman Spectra of Liquid Sulfur Around the Polymerization Transition - A. Kalampounias, G. Papatheodorou (University of Patras), and S. Yannopoulos (Foundation for Research and Technology Hellas) |
o | 1430 |
Raman Spectroscopic Measurements of Molten Ceramic Material at High Temperature - A. Kalampounias (University of Patras) and G. Papatheodorou (Foundation for Research and Technology Hellas) |
o | 1431 |
Spectroscopy of Ni(II) and Pt(II) Complexes in Carbamide and Carbamide-halide Melts - T. Silinskaya, N. Buryak, N. Tumanova, and S. Volkov (National Academy of Sciences of Ukraine) |
o | 1432 |
Non-enzymatic Synthesis of Peptides in an Ionic Liquid - V.F. Smith, H.C. De Long (United States Naval Academy), P.C. Trulove, and T. Sutto (Air Force Office of Scientific Research) |
o | 1433 |
Corrosion of Magnesium, Aluminium, and Titanium in Alkaline-salt Melts - I. Skryptun and O. Zarubitskii (Institute of General & Inorganic Chemistry) |
o | 1434 |
Development of Methods for the Electropolishing of Refractory Metals in Environmentally Friendly Low-temperature Carbamide-containing Melts - K. Svitlana, B. Ludmila, and T. Nelly (National Academy of Sciences of Ukraine) |
o | 1435 |
Oxidation Catalysis in Ionic Liquids - V. Farmer and T. Welton (Imperial College) |
o | 1436 |
Ionic Liquid Mediated Palladium Catalysis - P. Smith and T. Welton (Imperial College) |
Maggiano's Little Italy Restaurant
Bredig Award Address
Co-Chairs: H.C. De Long and P.C. Trulove
Wednesday, May 15, 2002
Salon D, Level 5
High Temperature Molten Salts
Co-Chairs: T. Griffiths and R. Fehrmann
Lanthanide, Actinide, and Radioisotope Chem in Molten Salts
Co-Chairs: D. Costa and M. Gaune-Escard
Lanthanide, Actinide, and Radioisotope Chem in Molten Salts
Co-Chairs: D. Costa and M. Gaune-Escard
Time | Abs# | Title |
1:40 | 1446 |
Actinide Chemistry in Novel Solvent Media: Room Temperature Ionic Liquids - R. Rogers and A. Visser (The University of Alabama) |
2:00 | 1447 |
Molecular Recognition through Ionic Liquids - S. Dai (Chemical Sciences Division), H. Luo (Nuclear Science aand Technology Division), P.V. Bonnesen, and A.C. Buchanan, III (Chemical Sciences Division) |
2:20 | 1448 |
Electrotransport of U and Pu into Liquid Cadmium Cathodes in LiCl-KCl Eutectic Melts - K. Uozumi, M. IIzuka, T. Inoue (Central Research Inst. of Electric Power Industry), O. Shirai, T. Iwai, and Y. Arai (Japan Atomic Energy Research Inst.) |
2:40 | 1449 |
Anodic Process of Electrorefining Spent Nuclear Fuel in Molten LiCl-KCl-UCl3 - S. Li (Argonne National Laboratory) |
3:00 | 1450 |
Actinides Recycle by Pyrochemistry in Nuclear Fuel Cycle - T. Inoue, Y. Sakamura, M. Iizuka, K. Kinoshita, T. Usami, and M. Kurata (Central Research Institute of Electric Power Industry) |
3:20 | |
Twenty-Minute Intermission - |
3:40 | 1451 |
Separation of Uranium andMagnesium by Molten Salt Electrorefining - B. Mishra, I. Maroef (Colorado School of Mines), and D. Hebditch (Japan Nuclear Cycle Development Institute) |
4:00 | 1452 |
Influence of the First and Second Coordination Spheres on Electrochemical and Thermodynamical Properties of Europium in Alkali Chloride Melts - S. Kuznetsov (Russian Academy of Sciences) and M. Gaune-Escard (IUSTI) |
4:20 | 1453 |
Nano Materials From Molten Salts: Preparation of Nano-sized Lanthanide Phosphates from Chloride Melts - V.A. Volkovich (The University of Manchester), T.R. Griffiths (University of Leeds), and R.C. Thied (British Nuclear Fuels) |
4:40 | 1454 |
Mixing Enthalapies of TbBr3 - MBr Liquid Mixtures(M=Li, Na, K, Rb, Cs) - M. Gaune-Escard (IUSTI) and L. Rycerz (Wroclaw University of Technology) |
5:00 | 1455 |
Infrared Radiation Spectra of Oxyhydril Groups in MCl (M = Na, K, Cs) and UO_2Cl2 - Cs Cl mixed Melts - A.A. Khokhryakov and A.M. Khokhlova (Institute of High-Temperature Electrochemistry) |
5:20 | 1456 |
Joint Electroreduction of Lanthanum, Gadolinium, and Boron in Chloride Melts - K. Kushkhov, A. Uzdenova, and M. Vindizheva (Kabardino-Balkarian State University) |
Thursday, May 16, 2002
Electrodeposition in Molten Salts
Co-Chairs: G. Stafford and S. Kuznetsov
Salon D, Level 5
Electrodeposition in Molten Salts
Co-Chairs: C. Hussey and F. Endres
Time | Abs# | Title |
1:40 | 1466 |
Production of Reactive Metals by Molten Salt Processing - B. Mishra and D.L. Olson (Colorado School of Mines) |
2:00 | 1467 |
Cathode Wear During Aluminum Electrolysis - H.A. Oye (Norwegian University of Science and Technology) and X. Liao (Elkem Metals Canada) |
2:20 | 1468 |
Electrowinning of Metallic Lithium from Molten Salts - Y. Sato, Y. Qin, Z. Zheng, T. Kobayashi, and T. Yamamura (Tohoku University) |
2:40 | 1469 |
The Cathodic Process in Magnesium Chloride-Alkali Chloride Melts - J. Kazmierczak, A. Kisza (University of Wroclaw), G.M. Haarberg, and R. Tunold (NTNU) |
3:00 | 1470 |
Electrorefining of Magnesium in Chloride Melt - T. Takenaka, S. Isazawa, Y. Naka, and M. Kawakami (Toyohashi University of Technology) |
3:20 | 1471 |
Formation of Metal Fog and Dissolved Metals during Electrodeposition from Molten Salts - G.M. Haarberg (Norwegian University of Science and Technology) |
3:40 | |
Twenty-Minute Intermission - |
4:00 | 1472 |
Electrodeposition of Refractory Metals from Molten Salts - E. Boland, R. Lanam, A. Shchetkovskiy, and A. Smirnov (Engelhard) |
4:20 | 1473 |
Electrochemical Reduction of Solutions of ReF_6 in the Fused LiF-NaF-KF Eutectic Mixture - A.M. Affoune (Universite de Guelma), J. Bouteillon, and J.C. Poignet (ENSEEG) |
4:40 | 1474 |
Hafnium in Molten Salts: Electrochemistry, Chemistry, Electrodeposition - S. Kuznetsov and S. Kuznetsova (Russian Academy of Sciences) |
5:00 | 1475 |
Electroless Cocating of Non-Conducting Surfaces and Particles with Metallic Titanium in Molten Salts - I. Sytchev, Z.H. Gondor, and G. Kaptay (University of Miskolc) |
5:20 | 1476 |
A New Concept of Sponge Titanium Production by Calciothermic Reduction of Titanium Oxide in the Molten CaCl2 - R. Suzuki and K. Ono (Kyoto University) |
5:40 | 1477 |
Investigation of the Mechanism of the Joint Electrodeposition of Molybdenum, Tungsten, and Carbon in Oxide and Oxihalide Melts - K. Kushkhov, L. Beroeva, and M. Adamokova (Kabardino-Balkarian State University) |
Friday, May 17, 2002
Electrochemistry and Properties of Room-Temp Molten Salts
Co-Chairs: P.C. Trulove and M. Matsunaga
Time | Abs# | Title |
8:00 | 1478 |
Electrochemical Investigations in the Ionic Liquid 1-Butyl-3-Methylimidazolium Hexafluorophosphate - D. Boxall and R. Osteryoung (North Carolina State University) |
8:20 | 1479 |
Electrochemistry in Neoteric Ionic Liquids - C. Brooks and A. Doherty (The Queen's University of Belfast) |
8:40 | 1480 |
The Electrochemistry of 1-Butyl-3-methyl-1H-imidazolium Tetrafluoroborate - L. Xiao and K. Johnson (University of Regina) |
9:00 | 1481 |
Electrochemical Studies of the Fries Rearrangement of Phenyl Benzoate in a Room-Temperature Molten Salt - G. Cheek (United States Naval Academy) |
9:20 | 1482 |
Electrochemistry of Ta(V) in Lewis Basic TaCl_5-EMIC Low Temperature Molten Salts - M. Matsunaga, T. Matsuo, and M. Morimitsu (Kyushu Institute of Technology) |
9:40 | |
Forty-Minute Intermission - |
10:20 | 1483 |
Electrolytic Synthesis of Perfluorotrimethylamine with Alkali Metal Fluoride Contained Carbon Anode - A. Tasaka, A. Miyasaka, T. Miyazaki (Doshisha University), H. Takebayashi, T. Tojo (Toyo Tanso Co., Ltd.), and K. Momota (Morita Chemical Industries Co., Ltd.) |
10:40 | 1484 |
Anlysis of the Species in the (CH3)4NFNmHF Melt and Electrolysis of Its Melt with LiNiO2 Coated Ni Anode - Y. Shodai (Doshisha University), K. Momota (Morita Chemical Industries Co., Ltd.), and A. Tasaka (Doshisha University) |
11:00 | 1485 |
Electrical Conductivity of Coexisting System Containing Inorganic Powder and Ambient Temperature Molten Salts - S. Deki, K. Yaso, M. Mizuhata, and A. Kajinami (Kobe University) |
11:20 | 1486 |
The Molarities of Ionic Liquid Species-Densities Are not Boring - L. Xiao (University of Regina), J.S. Wilkes (US Air Force Academy), and K.E. Johnson (University of Regina) |
11:40 | 1487 |
NMR Relaxation Studies and Molecular Modeling of 1-butyl-3-methyl Imidazolium PF6 [BMIM][PF6] and Related Ionic Liquids - R. Carper, Z. Meng (Wichita State University), and A. Dolle (Rheinisch-Westfalische Technische Hochschule) |
Electrochemistry and Properties of Room-Temp Molten Salts
Co-Chairs: R. Mantz and G.T. Cheek
Time | Abs# | Title |
1:40 | 1488 |
Coordination Chemistry and Speciation of Metal Complexes in Room Temperature Ionic Liquids - W. Oldham and B. Williams (Nuclear Materials Technology Division) |
2:00 | 1489 |
Quantitative Study by Raman Spectroscopy of the Stability of 1-methyl-3-butylimidazolium Chloride/AlCl_3/EthylAlCl2 Mixed Molten Salts in Presence of an Aliphatic Hydrocarbon - S. Dechamps, B. Gilbert (University of Liege), and H. Olivier (Institut Francais du Petrole) |
2:20 | 1490 |
The HNMR Spectra of Molten Asymetric Pyridinium Salts - D. Newman, D.Y. Chen (Bowling Green State University), V. Oliveira, A. Elias, and M.E. Elias (University of Portugal) |
2:40 | 1491 |
Alkylimidazolium Fluorohydrogenates Room Temperature Molten Salts - R. Hagiwara, K. Matsumoto, Y. Nakamori, T. Tsuda, and Y. Ito (Kyoto University) |
3:00 | 1492 |
Physicochemical Properties of Pyrazolium Based Ionic Liquid: 1-Ethyl-2-Methylpyrazolium Tetrafluoroborate - J. Caja, D. Dunstan (Electrochemical Systems, Inc.), and V. Katovic (Wright State University) |
3:20 | 1493 |
Conductivities of Room Temperature Molten Salts Containing ZnCl2, Measured by a Computerized Direct Current Method - H. Hsin-Yi and Y. Chao-Chen (National Yunlin University of Science and Technology) |
3:40 | 1494 |
Investigation of Physical properties for a New Type Molten ZnCl2-DMSO2 Electrolytes - S. Min-Fong and Y. Chao-Chen (National Yunlin University of Science and Technology) |
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