205th Meeting of The Electrochemical Society

May 9-May 14, 2004


S3 - Sixth International M. Baizer Award Symposium on Organic Electrochemistry

Organic and Biological Electrochemistry

Monday, May 10, 2004

Salon H, Level 3

Co-Chairs: J. Lessard and K. Chiba

10:00747 Recent Efforts to Achieve Electrocatalysis Using Ytterbium(III); and Electrochemically Mediated Rearrangements of Housanes - D. Little (UCSB) and B. Frontana-Uribe (UNAM)
10:20748 Biomimetic Oxygenation using Electrochemical Method - S. Maki (The University of Electro-Communications)
10:40749 Synthesis of 2,3-Dihydrobenzofuran Derivatives via Electron Transfer Reaction Catalyzed by Iron(III)-Salt in an Ionic Liquid Solvent System - T. Itoh, K. Kawai, H. Uehara, S. Hayase, H. Ohara (Tottori University), and M. Oyama (Kyoto University)
11:00750 Electrochemical Dehalogenation Reaction of DDT Mediated by Hydrophobic Vitamin B12 - Y. Hisaeda, H. Shimakoshi, and M. Tokunaga (Kyushu University)
11:20 Electron Transfer Discussion by M. Workentin (University of Western Ontario)
11:40751 Kinetics of Native and Cross Linked Hemoglobins at Thin Layer and Modified Planar Waveguide Electrodes - A. Fitch, A. Wagdy, F. Amoake (Loyola University Chicago), S. Dragan (Northwestern University), and K. Olsen (Loyola University Chicago)

Co-Chairs: J. Simonet and H. Tanaka

14:00752 M.M. Baizer Award Addresss: Mechanistic Organic Electrochemistry: Some Reflections on its Past, Present and Future - D. Evans (University of Arizona)
15:00753 Evidence for an Inverted Region Behavior in Proton Transfer to Carbanions. A Laser Flash Electron Photoinjection Study - C. Andrieux, J. Gamby (Universite de Paris 7 - Denis Diderot), P. Hapiot (Universite de Rennes 1), and J.-M. Saveant (Universite de Paris 7 - Denis Diderot)
15:20754 Electron Transfer to and Conformational Preferences of Aib Oligo-Peptides - V. Barone (Universita di Napoli), F. Formaggio (Universita di Padova), R. Improta (Universita di Napoli), F. Polo, and F. Maran (Universita di Padova)
15:40 Twenty-Minute Intermission
16:00755 Kinetics and Mechanism of the Formation of Organometallic Compounds from Organic Halides at Metal Surfaces - W.J. Bowyer and B. Beckingham (Hobart and William Smith Colleges)
16:20756 Catalytic Reduction of 1,6-Dihaloalkanes with Electrogenerated Nickel(I) Salen in Dimethylformamide - P. Vanalabhpatana and D. Peters (Indiana University)
16:40757 Dissociative Electron Transfer to Organic Polychloride Pollutants. From Electrochemical Induced Cleavage to Enzymatic Dechlorination. - J.E. Arguello, C. Costentin, B. Limoges, M. Robert, and J.-M. Saveant (UniversiteParis 7)
17:00758 Linear and Cyclic Vinylogous TTF: Molecular Movement Induced by Electron Transfer - M. Guerro, R. Carlier, D. Lorcy, and P. Hapiot (Universite de Rennes 1)
17:20759 Electrochemistry of Terephthalaldehyde - P. Zuman, W. Bover, M. Baymak, and H. Celik (Clarkson University)

Tuesday, May 11, 2004

Co-Chairs: P. Hapiot and J. Yoshida

08:00760 Towards Molecular-Level Understanding of Electrocatalytic Hydrogenation. Part 2. Behavior of Benzene at Pt(hkl) - M. DeBlois (Universite de Sherbrooke), F. Perreault, G. Jerkiewicz (Queen's University), and J. Lessard (Universite de Sherbrooke)
08:20761 Electocatalytic Carbonylation of Methanol by Gold Anode - I. Yamanaka, A. Funakawa, S. Takenaka, and K. Otsuka (Tokyo Institute of Technology)
08:40762 Studies Toward Understanding the Role of Interfacial Molecular Structure on Adhesion and Corrosion - M. Anderson (Virginia Tech)
09:00763 Enhanced Rates of Styrene Epoxidation Catalyzed by Myoglobin-Polyion Films in Bicontinuous Microemulsions - J. Rusling and A. Vaze (University of Connecticut)
09:20764 Electrochemistry of Adsorbed Nitrofluorenone Monolayers and their Use in Bioelectrocatalysis - S. Ben-Ali (ENSCPB University Bordeaux), N. Mano (The University of Texas at Austin), and A. Kuhn (ENSCPB University Bordeaux)
09:40 Twenty-Minute Intermission
10:00765 Bio-Sensitization of Boron-Doped Diamond - D. Delabouglise, B. Marcus, M. Mermoux, P. Bouvier, J. Chane-Tune, J.-P. Petit (Institut National Polytechnique de Grenoble), P. Mailley, and T. Livache (CEA-Grenoble)
10:20766 Electrogenerated Affinity Polymers for the Immobilization of Biomolecules : From Microbiosensors to Bioreactors - S. Cosnier (Universite Joseph Fourier Grenoble)
10:40767 In Situ ESR UV Vis NIR Spectroelectrochemical Studies of End-Capped Oligothiophenes - D. Rohde (IFW Dresden), A. Tabet, H. Hartmann (FH Merseburg), and L. Dunsch (IFW Dresden)
11:00768 Spectroelectrochemical Studies of Functionalised Organic Polymeric Layers - J. Tarabek (IFW Dresden), P. Rapta (Slovak University of Technology), D. Ferse, H.-J. Adler (Technische Universitat Dresden), and L. Dunsch (IFW Dresden)
11:20769 One Dimensional Metal-metal Bond Based Molecular Wires. Electrosynthesis, Spectroscopic Features and Catalytic Activities - S. Chardon noblat and A. Deronzier (Universite Joseph Fourier - Grenoble 1)
11:40770 Synthesis and Characteristics of Polyacetylene Chloride - M.-H. Chen and T.-C. Chou (National Cheng Kung University)

Co-Chairs: H. Schaefer and I. Nishiguchi

14:00771 M.M. Baizer Award Address: Environmentally Benign Organic Syntheses by Utilizing Organic Electrochemistry - M. Tokuda (Hokkaido University)
15:00772 Cathodic Intramolecular Cyclisation of N-(Oxoalkyl)pyridinium-salt.- A Short Entry to Indolizidine Alkaloids - J. Heimann and H.J. Schafer (Universitat Munster)
15:20773 Electrochemical Conversion of Primary Alkyl Halides to Alkenes at Platinum Cathodes - J. Simonet (University of Rennes 1) and D. Peters (Indiana University)
15:40 Twenty-Minute Intermission
16:00774 Reductive Cyclization of Tethered Bis-Enones - S. Handy and D. Omune (SUNY-Binghamton)
16:20775 Electrolyzed CH3CN-Et4NClO4 Solutions: an Alternative Strategy to C-N Bond Formation - L. Rossi (Universita degli Studi), M. Feroci, M. Orsini (Dip. Ingegneria Chimica, Materiali, Materie Prime e Metallurgia, Universita), L. Palombi, and A. Inesi (Universita degli Studi)
16:40776 Synthesis of Medium-ring Lactones via an Electrochemical Arylation of Olefins - J.-Y. Nedelec, E. Leonel, and E. Metay (University of Paris 12)
17:00777 Electrohydrogenation of Alpha-functionalized Carboxylic Acids - T. Datta, J. Jackson, and D. Miller (Michigan State University)
17:20778 Electroreductive One-Pot Double Carboalkoxylation with N-Carboalkoxyimidazole - I. Nishiguchi, T. Uchida, U. Yamamoto, and H. Maekawa (Nagaoka University of Technology)

Salons E and F, Level 3

Poster Session

Co-Chairs: J. Lessard and P. Hapiot

o779 Electrochemistry of 4-Aminothiophenol on Glassy Carbon Electrodes - J. Marwan and D. Belanger (Universite de Quebec a Montreal)
o780 Reactivity of Electrogenerated Organic Radicals in Room-Temperature Ionic Liquids. Kinetics Studies in Unconventional Media - C. Lagrost, D. Carrie, S. Gmouth, M. Vaultier, and P. Hapiot (Universite de Rennes 1)
o781 In situ EC-AFM Imaging of Cathodic Modifications of Platinum Surfaces Performed in Dimethylformamide - J.F. Bergamini, J. Ghilane, M. Guilloux-Viry, C. Lagrost, J. Simonet, and P. Hapiot (Universite de Rennes 1)
o782 Electro-Polymerization of Aminoquinoxalines and Their Characteristics as Electrochemical Capacitors - M. Morita, N. Yoshimoto, Y. Mukai (Yamaguchi University), M. Kasai, and H. Furusho (Nissan Chemical Industries, Ltd.)
o783 Electrosynthesis of new hydroxylamines – stability and evolution - C. Cristea (University of Medicine and Pharmacy), C. Moinet (University of Rennes 1), and M. Jitaru (Babes Bolyai University)

Wednesday, May 12, 2004

Salon H, Level 3

Co-Chairs: J.M. Saveant and Y. Matsumura

10:00784 Anodic Electrochemistry: New Umpolung Reactions for Organic Synthesis - K. Moeller (Washington University)
10:20785 Reactivity and Stability of Electrochemically Generated “Alkoxycarbeniun Ion Pools” - S. Suga, S. Suzuki, Y. Tsutsui, A. Yamamoto, and J.-I. Yoshida (Kyoto University)
10:40786 Nickel-catalyzed Electrochemical Cyclization of Halogenated Allyl Aryl Sulfides: Synthesis of Benzothiophene Derivatives - E. Dunach and S. Olivero (CNRS)
11:00787 Mediated Electrosyntheses - D. Pletcher (University of Southampton)
11:20788 Highly Diastereoselective Anodic Fluorination of Sulfides Having Oxygen- Containing Heterocyclic Groups - T. Fuchigami and K. Suzuki (Tokyo Institute of Technology)
11:40789 Unprecedented and Unique Electroreductive Rearrangement of 4-(2-Nitrophenyl)-3-5-dicarblalkoxy-1,4-dihydro-pyridines to 3-Carboalkoxyquinolines - I. Nishiguchi, M. Maseguchi, M. Matsunami, and H. Maekawa (Nagaoka University of Technology)

Co-Chairs: K. Moeller and T. Fuchigami

14:00790 Highly Selective Friedel-Crafts Reaction of Electrochemically Generated “Cation Pool” Using Micromixing - J.-I. Yoshida, A. Nagaki, and S. Suga (Kyoto University)
14:20791 Electrochemical Transformation of Activated Olefins and CH-acids into Functionally Substituted Cyclopropanes. - A. Vereshchagin, M. Elinson, S. Feducovich, and G. Nikishin (N.D. Zelinsky Institute of Organic Chemistry RAS.)
14:40792 Anodic Oxidation of Mono- and Disubstituted 1,4-Dimethoxybenzenes: Basic vs. Neutral and Constant Current vs. Controlled Potential Conditions - J.Y. Becker and C.-C. Zeng (Ben-Gurion University of the Negev)
15:00793 Stereoselective Synthesis of Azasugars by Electrochemical Oxidation - Y. Matsumura, O. Onomura, and N. Moriyama (Nagasaki University)
15:20794 Electrochemical Oxidation of Deoxy Derivatives of Some Purine Nucleosides and Nucleotides - R.N. Goyal (Indian Institute of Technology)
15:40 Twenty-Minute Intermission
16:00795 Anodic Modification of Proline Residues of Peptides Using a Lithium Perchlorate / Nitromethane Electrolyte Solution - K. Chiba, T. Suzuki, F. Tanaka, Y. Kitano, and M. Tada (Tokyo University of Agriculture and Technology)
16:20796 Scope and Limitation of Electrochemical Phenolic Oxidation: Synthesis of Verbenachalcone - T. Tanabe, F. Doi, T. Ogamino, and S. Nishiyama (Keio University)
16:40797 Electro-oxidation of Alcohols in N-Oxyl-Immobilized Ionic Liquids -Approach to a Toatlly Closed System - M. Kuroboshi, J. Fujisawa, and H. Tanaka (Okayama University)
17:00798 Influence of Acidity Level Change in Aprotic Media on the Voltammetric Behavior of Nitrogabacinamamides - J.A. Bautista-Martinez (Universidad Nacional Autonoma de Mexico), I. Gonzalez (Universidad Autonoma Metropolitana-Iztapalapa), and M. Aguilar-Martínez (Universidad Nacional Autonoma de Mexico)
17:20799 Experimental Proof of Formation of Imines as Intermediates in the Reduction of Hydrazones - M. Baymak (Clarkson University), H. Lund (Aarhus University), and P. Zuman (Clarkson University)
17:40800 Contributions to Electroreduction of Oximes - H. Celik (Clarkson University), J. Ludvik (J.Heyrovsky Institute of Physical Chemistry), and P. Zuman (Clarkson University)

Thursday, May 13, 2004

Co-Chairs: F. Maran and A. Fry

08:00801 Kinetics of Anodic Oxidation of Sodium Gluconate by Using Graphite Electrode - C.-F. Chou and T.-C. Chou (Departemet of Chemical Engineering, National Cheng Kung University)
08:20802 The Influence of Hydrogen Bond Strength on the Redox Properties of Different a-NH-Quinones - M. Aguilar-Martinez, N. Macías-Ruvalcaba (Universidad Nacional Autonoma de Mexico), and I. Gonzalez (Universidad Autonoma Metropolitana-Iztapalapa)
08:40803 Intra and Intermolecular Hydrogen Bonding in Hydroxy-Naphthoquinones - M. Gomez, I. Gonzalez (Universidad Autonoma Metropolitana-Iztapalapa), and F. Gonzalez (Centro de Investigacion y Estudios Avanzados del IPN)
09:00804 Molecular and Electronic Structural Properties of the Hydrogen-Bonded Complexes of P-Quinone and O-Quinone Dianions - N. Okumura and B. Uno (Gifu Pharmaceutical Univercity)
09:20805 A New Approach to Substituent Effects in Organic Electrochemistry - A. Fry and L. Hicks (Wesleyan University)
09:40 Twenty-Minute Intermission
10:00806 Electrochemical Studies and Semiempirical Calculations on pi-Conjugated Dienones - S. Vatsadze (M. V. Lomonosov Moscow State University), M. Al-Anber, R. Holze, W.R. Thiel, and H. Lang (Technische Universitat Chemnitz)
10:20807 Computational Studies of Decomposition Reactions of 1,4-Diphenyl-2,3-dioxabicyclo[2.2.2]octane Radical Cation Generated by Photoinduced Electron Transfer - R. Akaba, Y. Kiyota, S. Nishimoto (Gunma College of Technology), and M. Kamata (Niigata University)
10:40808 Synchronization of Photoisomerization and Redox Reaction in Azo-conjugated Transition Metal Complexes - S. Kume, K. Yamaguchi, M. Murata, and H. Nishihara (The University of Tokyo)
11:00809 Spectroscopic Study on the Reactivity of N,N-Dimethyl-p-Substituted Aniline Cation Radicals in Acetonitrile - J. Zhang and M. Oyama (Kyoto University)
11:20810 Electrolytes for Lithium Batteries Based on Polysiloxane Hosts - L. Lyons (Grinnell College), Z. Zhang, R. West (Organosilicon Research Center), and K. Amine (Argonne National Laboratory)
11:40811 The Effect of Room Temperature Molten Thiocyanate Salts in CuI on the Performance of Solid-state Dye-sensitized Photovoltaic Cells Using CuI as a Hole Collector - A. Konno, T. Kitagawa, D. Sugiura, G.R.A. Kumara (Shizuoka University), and K. Tennakone (Institute of Fundamental Studies)