213th ECS Meeting - Phoenix, AZ

May 18 - May 22, 2008

PROGRAM INFORMATION
 

B6 - Ionic and Mixed Conducting Ceramics 6

High Temperature Materials/Battery/Energy Technology
 

Monday, May 19, 2008

Room 211A, 200 Level, Phoenix Convention Center

SOFC Electrodes 1

Co-Chair(s): H. Yokokawa and M. Mogensen
TimeAbs#Title and Authors
10:30 Introductory Remarks (10 Minutes)
10:40   362   Oxygen Incorporation Kinetics into Dense, PLD-Deposited (Ba,Sr)(Co,Fe)O3-d. Microelectrodes R. Merkle (MPI for Solid State Reserach), L. Wang, G. Cristiani, B. Stuhlhofer, H. Habermeier (MPI for Solid State Research Stuttgart) and J. Maier (Max Planck Institute for Soild State Research)
11:00   363   Effect of Temperature and Electrical Field on Oxygen Transport Paths Around Gold / Ion Conducting Oxides Hetero-Interfaces H. Kishimoto (National Institute of Advanced Industrial Science and Technology (AIST)), H. Kishimoto, K. Yamaji, T. Horita, M. Brito and H. Yokokawa (National Institute of Advanced Industrial Science and Technology)
11:20   364   O2 Oxide Redox Chemistry at La1-xSrxCoO3-δ 0 {less than or equal to} x {less than or equal to} 0.6) and La1-xSrxFeO3-δ (0.2 {less than or equal to} x {less than or equal to} 0.6)SOFC Materials J. L. Fournier, V. Thangadurai and V. Birss (University of Calgary)
11:40   365   Effect of Minor Additions of CeO2 on Conductivity of Perovskites with Mixed Ionic-Electronic Conductivity E. Konysheva and J. Irvine (University of St Andrews)
 

SOFC Electrodes 2

Co-Chair(s): R. Merckle and T. M. Gur
TimeAbs#Title and Authors
14:00   366   Impact of Electrochemical Reaction Mechanisms on Overpotentials in the Solid Oxide Fuel Cell Anode K. N. Grew, J. R. Izzo Jr. and W. Chiu (University of Connecticut)
14:20   367   Effect of A-site Deficiency on Mixed Conducting Properties of (Ba,Sr)(Co,Fe)O3-δ Electrodes for Solid Oxide Fuel Cell Y. Kim (Korea Advanced Institute of Science and Technology) and J. Bae (Korea Advanced Institute of Science and Technology (KAIST))
14:40   368   Pd Promoted La0.8Sr0.2Cr0.5Mn0.5O3/YSZ Composite Anodes for Solid Oxide Fuel Cells S. Jiang and Y. Ye (Nanyang Technological University)
15:00   369   MIEC's Studied by the use of Cone-Shaped Electrodes K. Kammer Hansen (Technical University of Denmark) and M. Mogensen (Risø National Laboratory - DTU)
15:20 Intermission (20 Minutes)
15:40   370   Structural and Electronic Characterization of Nd1-xSrxMn0.5Cr0.5O3-d (x = 0.25, 0.5) as Cathode Materials for SOFC A. K. Azad and J. Irvine (University of St-Andrews)
16:00   371   Electronic and Local Structures of La1-xSrxCoO3-d Studied by In-Situ Micro XAFS Measurements K. Amezawa, A. Unemoto, M. Sase, T. Kawada (Tohoku University), Y. Orikasa, H. Aoki, T. Ina, T. Fukutsuka, Y. Uchimoto (Kyoto University) and Y. Terada (JASRI)
16:20   372   Electrochemical Investigation of LSGMC-Containing Composite Cathodes on LSGM-Supported Cells A. Do, X. Lu (National Fuel Cell Research Center, UC-Irvine), J. Bae (Korea Advanced Institute of Science and Technology (KAIST)) and J. Brouwer (National Fuel Cell Research Center, UC-Irvine)
16:40   373   Strontium Titanate-based Composite Electrodes for Solid Oxide Fuel Cells P. Blennow (Risø National Laboratory for Sustainable Energy, Technical University of Denmark), K. Kammer Hansen (Technical University of Denmark), L. Wallenberg (nCHREM, Polymer and Materials Chemistry, Kemicentrum, Lund University) and M. Mogensen (Risø National Laboratory - DTU)
17:00   374   Ba0.2Sr0.8Co0.8Fe0.2O3-d Phase Equilibrium, Bulk Conductivity and CO2 Sensitivity Z. Yang (Nonmetallic Inorganic Materials), A. Harvey (Nonmetallic Inorganic Materials, Department of Material) and L. Gauckler (ETH Zurich)
17:20   375   Mesoporus La0.6Sr0.4CoO3-δ, Pr0.6Sr0.4CoO3-δ and Gd0.6Sr0.4CoO3-δ as Mixed Conducting Cathode Materials for Intermediate Temperature SOFC I. Kivi, E. Lust and G. Nurk (University of Tartu)
17:40   376   Improving Sulfur-Tolerance of Ni-YSZ Anode in SOFC by Imprgnation of Doped Ceria M. Gong, X. Liu (West Virginia University) and R. Gemmen (National Energy Technology Laboratory)
 

Tuesday, May 20, 2008

Room 211A, 200 Level, Phoenix Convention Center

SOFC Performance

Co-Chair(s): S. M. Haile and T. Armstrong
TimeAbs#Title and Authors
08:00   377   Performance and Electrochemical Characterisation of Thin Electrolyte SOFCs T. G. Ramos, J. Hjelm (Risø National Laboratory - DTU), M. Wandel (Risø National Laboratory), A. Hagen and M. Mogensen (Risø National Laboratory - DTU)
08:20   378   Effect of Anode Active Layer on Performance of Single Step Co-fired Solid Oxide Fuel Cells (SOFC's) at High Fuel Utilizations K. Yoon, S. Gopalan and U. Pal (Boston University)
08:40   379   In-Plane and Through-Plane Electrochemical Conductivity and Fuel Cell Performance of Thin-Film Yttria-Doped Zirconia Electrolytes A. C. Johnson and S. Ramanathan (Harvard University)
09:00   380   Intermediate-Temperature Solid Oxide Fuel Cell Based on Proton Conductors T. H. Lee, C. Park, S. E. Dorris and U. Balachandran (Argonne National Laboratory)
09:20   381   The Course of O2 Partial Pressure and Electric Poten-tial Across an Oxide Electrolyte Cell M. Mogensen (Risø National Laboratory - DTU) and T. Jacobsen (Department of Chemistry)
09:40 Intermission (20 Minutes)
10:00   382   Intermediate Temperature Solid Oxide Fuel Cells Based on Nano-Composite Cathodes with Multi-Layer Structure T. Kharlamova (Boreskov Institute of Catalysis), A. Smirnova (University of Connecticut) and V. Sadykov (Boreskov Institute of Catalysis)
10:20   383   Efficiency and Fuel Utilization of Methane-Powered Single-Chamber SOFCs Y. Hao and D. Goodwin (California Institute of Technology)
10:40   384   Electrochemical Characterization of Planar Anode Supported SOFC with Sr-Doped Lanthanum Cobalt Oxide Cathodes J. Hjelm, M. Soegaard, R. Knibbe, A. Hagen and M. Mogensen (Risø National Laboratory - DTU)
11:00   385   Structural and Electrochemial Properties of A1-ySryCo1-xFexO3 (A=Ba, La, Pr, Sm; y=0.2, 0.5; 0.0<x<1.0 Oxides for SOFCs E. Magnone (University of Rome Tor Vergata), M. Miyayama (RCAST- University of Tokyo) and E. Traversa (University of Rome Tor Vergata)
11:20   386   Energy Production from Coal Syngas Containing H2S via Solid Oxide Fuel Cells M. E. Cooper, C. DeSilva and D. Bayless (Ohio University)
11:40   387   Operation of Solid Oxide Fuel Cells on Gasified Coal O. A. Marina, L. Pederson, C. Coyle, E. Thomsen, G. Coffey, B. McCarthy and J. Templeton (Pacific Northwest National Laboratory)
 

Dense Separation Membranes

Co-Chair(s): H-I. Yoo and O. Marina
TimeAbs#Title and Authors
14:00   388   ITM Ceramic Membrane Technology to Produce Synthesis Gas C. Miller, M. Carolan, C. Chen, E. Minford, W. Waldron (Air Products and Chemicals, Inc.) and J. Chen (Ceramatec, Inc.)
14:20   389   High Temperature, Dual-Ion Conducting Membrane for CO2 Separation J. L. Wade (Columbia University), A. West (Department of Chemical Engineering, Columbia University) and K. Lackner (Earth and Environmental Engineering, Columbia University)
14:40   390   Onsager Transport Coefficients of CeO2-d W. Park (Seoul National University), I. Yang (Division of Physical Metrology, Korea Research Institute of Standards and Science) and H. Yoo (Seoul National University)
15:00   391   Effects of Excess Ga on the Oxygen Permeation and Electrical Conducting Property of Pr2Ni0.75Cu0.25O4 Based Oxide T. Ishihara, K. Tominaga, S. Okada (Kyushu University) and H. Matsumoto (Kushu University)
15:20   392   Proton-Electron Mixed Conduction Properties in (Ce,Sr)PO4 A. Unemoto (Tohoku University), N. Kitamura (Tokyo University of Science), K. Amezawa and T. Kawada (Tohoku University)
15:40 Intermission (20 Minutes)
16:00   393   Characteristics of Oxygen Reduction on Nanocrystalline YSZ H. Huang (Wright State University), J. Shim, C. Chao (Stanford University), R. Pornprasertsuk (Chulalongkorn University), M. Sugawara, T. M. Gür and F. Prinz (Stanford University)
16:20   394   Determination of Oxygen Exchange and Diffusion Coefficients of MIEC Perovskites by Asymptotic Analysis of Relaxation Data E. Rudberg (Norwegian University of Science and Technology), A. Svensson (SINTEF), K. Wiik (Norwegian University of Science and Technology), M. Thomassen (SINTEF) and K. Nisancioglu (Norwegian University of Science and Technology)
16:40   395   Transport, Thermal Expansion and Redox Properties of Ce0,80RE0,20O2-δ (RE=Pr, Tb) Solid Solutions C. Chatzichristodoulou (Risø DTU, National Laboratory for Sustainable Energy), J. Grivel (Risø National Laboratory, DTU), A. Hagen (Risø National Laboratory - DTU) and P. V. Hendriksen (Risø National Laboratory for Sustainable Energy, Technical University of Denmark)
17:00   396   Cation Migration in Oxygen Permeable Membranes during Methane Reforming H. Takamura, H. Takahashi, T. Kikuchi and Y. Aizumi (Tohoku University)
17:20   397   Finite-Element Modeling of SOFC Electrodes Containing Ionically Conducting Nanoparticles J. D. Nicholas and S. A. Barnett (Northwestern University)
17:40   398   Hydrogen Production by Water Dissociation using Oxygen Transport Membranes T. H. Lee, C. Park, S. E. Dorris and U. Balachandran (Argonne National Laboratory)
 

Hall 2, Lower Level, Phoenix Convention Center

Poster Session

TimeAbs#Title and Authors
o   399   Study on Conductivity Properties of Calcium and Magnesium Doped GdAlO3 A. Sinha (Bhabha Atomic Research Centre), H. Näfe (Max-Planck-Institut fuer Metallforschung, Stuttgart, Germany) and B. Sharma (Bhabha Atomic Research Centre, INDIA)
o   400   Relationship between Defect Structures and Electrochemical Properties of (La,Sr)2NiO4{plus minus}d T. Ina, H. Aoki, Y. Orikasa, T. Fukutsuka, Y. Uchimoto (Kyoto University), K. Amezawa and T. Kawada (Tohoku University)
o   401   X-Ray Absorption Spectroscopic Studies on Electronic and Local Structures in La0.6Sr0.4Co0.8Fe0.2O3-d Perovskite-Type Oxides Y. Orikasa, H. Aoki, T. Ina, T. Fukutsuka, Y. Uchimoto (Kyoto University), K. Amezawa and T. Kawada (Tohoku University)
o   402   Ionic and Electronic Conductivities for Ln9.33+xSi6O26+1.5x under Various Conditions T. Nakao, A. Mineshige, Y. Ohnishi, M. Kobune, T. Yazawa (University of Hyogo) and H. Yoshioka (Hyogo Prefectural Institute of Technology)
o   403   Electrical Performance of Calcium Doped Lanthanum Ferrite for use in Single-Step Co-Fired Solid Oxide Fuel Cells (SOFCs) P. A. Zink, U. Pal and S. Gopalan (Boston University)
o   404   Effect of Co-substitution on the Structure Characterization and Electrical Properties of Sr2FeNbO6 Double Perovskite T. Xia (Heilongjiang University), J. Wang (Harbin Engineering University), N. Lin, H. Zhao and L. Huo (Heilongjiang University)
o   405   Densification and Electrical Conductivity of Yttria-Stabilized Zirconia Containing NiO Additions R. M. Batista and E. N. Muccillo (Energy and Nuclear Research Institute)
o   406   Effects of Substrate Cooling on the Ionic Conductivity of Ta2O5 Solid-Electrolyte Thin Films Prepared by Reactive Sputtering Using H2O Gas Y. Abe, F. Peng, Y. Takiguchi, M. Kawamura, K. Sasaki, H. Itoh and T. Suzuki (Kitami Insitute of Technology)
o   407   Molecular Beam Synthesis and Electrochemical Transport Properties of Highly Textured Ceria Thin Films M. Tsuchiya (Harvard University), N. Bojarczuk (IBM T. J. Watson Research Center) and S. Ramanathan (Harvard University)
o   408   Oxygen Permeation and Electrical Transport Properties of 70 vol. % Bi1.6Y0.4O3 and 30 vol. % Ag Composite K. Kobayashi, M. Nishimura (National Institute for Materials Science) and S. Yamaguchi (The University of Tokyo)
o   409   A New Method for Indicating Oxygen Penetrability of MIECs F. Li, Y. Kang (University of Science and Technology Beijing), X. Lu (Shanghai University) and L. Li (University of Science and Technology Beijing)
o   410   La0.7Sr0.3Cu0.2Fe0.8O3-x as Oxygen Transport Membrane for Producing Hydrogen via Water Splitting C. Park, T. H. Lee, S. E. Dorris and U. Balachandran (Argonne National Laboratory)
o   411   Impedance Spectroscopy Measurement of Ni-SDC Composite Anode S. Baek and J. Bae (Korea Advanced Institute of Science and Technology (KAIST))
o   412   An Oxide Ion and Proton Co-Ion Conducting Sn0.9In0.1P2O7 Electrolyte for Intermediate-Temperature Fuel Cells C. Wang, X. Chen (University of Maryland), E. Payzant (ORNL) and C. Xia (University of Science and Technology of China)
o   413   Enhanced Interfacial Lithium Storage in Nanocomposites of Transition Metals with LiF or Li2O: Experimental Studies and Theoretical Simulations E. A. Kotomin, Y. Zhukovskii (Max Planck Institute) and J. Maier (Max Planck Institute for Soild State Research)
o   414   Electrochemical Studies of Anode-Supported SOFC Unit Cell Prepared by Tape-Casting and Co-Sintering Y. Kim, S. Park, Y. Shin (Chonnam National University), H. Kim, J. Kim (Korea Institute of Industrial Technology), Y. Lee and M. Lee (Chonnam National University)
o   415   Synthesis Characteristics of Nanocrystalline YSZ by Chemical Co-Precipiation and its Electrochemical Study by SOFC Unit Cell Y. Shin, Y. Kim, S. Park (Chonnam National University), H. Kim, H. Lee (Korea Institute of Industrial Technology), Y. Lee and M. Lee (Chonnam National University)
o   416   The Effect of Electrolyte Doping on Chromium Deposition at SOFC Electrode/Electrolyte Interface K. Wang and J. Fergus (Auburn University)
o   417   Impedance Spectroscopy Analysis of Zirconia:10 mol% Scandia Solid Electrolytes During and After Sintering G. Costa and R. Muccillo (IPEN-USP)
 

Wednesday, May 21, 2008

Room 211A, 200 Level, Phoenix Convention Center

Electrolytes

Co-Chair(s): T. Ishihara and E. Traversa
TimeAbs#Title and Authors
08:00   418   Oxidation and Hydration Kinetics of Proton Conductor Oxides H. Yoo, J. Kim and C. Lee (Seoul National University)
08:20   419   Equilibrium Constants for Water Incorporation and Oxidation Reactions in Yttrium-Doped Barium Zirconates Y. Yamazaki, P. Babilo and S. Haile (California Institute of Technology)
08:40   420   Effect of Water on the Bulk & Electrode Properties of Ceria W. C. Chueh, W. Lai and S. Haile (California Institute of Technology)
09:00   421   Conductivity Studies of Inorganic Proton Conductors for Composite Membranes in PEM Fuel Cells C. Wang, E. Chalkova (Energy Institute), C. Lute (Electrical Engineering), M. Fedkin, S. Komarneni, M. Chung and S. N. Lvov (Penn State University)
09:20   422   Electric Transport Property and Defect Structure of BaPr1-xYbxO3 S. Miyoshi, S. Mimuro (The University of Tokyo), T. Higuchi (Tokyo University of Science), K. Kobayashi (National Institute for Materials Science), Y. Oyama, S. Shin and S. Yamaguchi (The University of Tokyo)
09:40 Intermission (20 Minutes)
10:00   423   Synthesis and High Temperature Electrochemical Properties of Y-Doped Zirconia Thin Films Synthesized under Photon Irradiation: A Route to Ultra-Thin Electrolyte Membranes M. Tsuchiya and S. Ramanathan (Harvard University)
10:20   424   Ionic Conducting Ceramics as Alternative Catalyst Supports P. Vernoux (CNRS), M. Guth (Université Lyon 1) and X. Li (Tianjin University)
10:40   425   Unusual Conductivity of Nanostructured Scandia Stabilized Zirconia Ceramics V. V. Zyryanov, N. F. Uvarov and A. S. Ulihin (Institute of Solid State Chemistry)
11:00   426   Effect of Electrode Polarisation on the Determination of Electronic Conduction Properties of Calcium Doped GdAlO3 by Permeation and Simultaneous Cell Voltage Measurements A. Sinha (Bhabha Atomic Research Centre), H. Näfe (Max-Planck-Institut fuer Metallforschung, Stuttgart, Germany), B. Sharma (Bhabha Atomic Research Centre, Mumbai, India) and P. Gopalan (Indian Institute of Technology)
11:20   427   Dehydration Behavior and Electrical Conductivity of Ceria Nanoparticles Prepared by Wet Processing N. Takahashi, M. Watanabe, M. Okada and H. Takamura (Tohoku University)
11:40   428   Electrical and Interfacial Properties for a New Class of Oxide Ionic Conductors, La9.33+xSi6O26+1.5x A. Mineshige, T. Nakao, M. Kobune, T. Yazawa (University of Hyogo) and H. Yoshioka (Hyogo Prefectural Institute of Technology)
 

SOFC general

Co-Chair(s): V. Birss and D. Goodwin
TimeAbs#Title and Authors
14:00   429   First Principles Modeling of SOFC Cathode E. A. Kotomin, Y. Mastrikov, E. Heifets (Max Planck Institute), R. Merkle (MPI for Solid State Reserach), J. Fleig (Vienna Institute of Technology), J. Maier (Max Planck Institute for Soild State Research), A. Gordon (Dept. Physics, Haifa University, Israel) and J. Felsteiner (Dept. Physics, Technion, Israel)
14:20   430   Computation of Polarization Resistance in Samaria Doped Ceria F. Ciucci, W. C. Chueh, S. Ben Hadj Hassine, S. Haile and D. Goodwin (California Institute of Technology)
14:40   431   Gas Concentration Impedance in an SOFC Plug Flow Setup S. H. Jensen (Risø National Laboratory for Sustainable Energy, Technical University of Denmark), M. Mogensen (Risø National Laboratory - DTU) and T. Jacobsen (Department of Chemistry)
15:00   432   Fabrication of Multi-Layered Electrolyte for Micro Tubular SOFCs T. Suzuki (AIST), Y. Funahashi (FCRA), T. Yamaguchi, Y. Fujishiro and M. Awano (AIST)
15:20   433   Fabrication and Characterization of Micro-Electrodes for the Electrochemical Investigation of Thin Film SOFC Cathodes T. M. Ryll, H. Galinski, B. Scherrer, R. Tolke, J. Rupp, A. Bieberle-Hutter and L. Gauckler (ETH Zurich)
15:40   434   Reactions at a Porous Ni Electrode Concurrent with Hydrogen evolution M. Villa, P. Salvi, E. Verardi (Universita' di Bergamo) and G. Zangari (University of Virginia)
 

Lithium Batteries

Co-Chair(s): J. Hjelm and K. Kammer Hansen
TimeAbs#Title and Authors
16:20   435   Li ion Migration in Li3PO4 Electrolytes: Effects of O Vacancies and N Substitutions Y. A. Du and N. A. Holzwarth (Wake Forest University)
17:20   436   Transport Properties and Defect Chemistry of Undoped and Doped Single Crystalline LiFePO4 R. Amin, C. Lin (Max Planck Institute for Soild State Research), W. Sigle (Max Planck Institute for Metal Research) and J. Maier (Max Planck Institute for Soild State Research)
17:40   437   Deposition and Properties of Lithium Phosphorous Oxynitride (Lipon) Thin Films N. Dudney and F. Xu (Oak Ridge National Laboratory)
 

Thursday, May 22, 2008

Room 211A, 200 Level, Phoenix Convention Center

Metal Oxidation and Coatings

Co-Chair(s): K. Nisancioglu and M. Mogensen
TimeAbs#Title and Authors
08:00   438   Evaluation of Electrophoretically Deposited CuMn1.8O4 Spinel )Oxide Coating on Metallic Interconnect for SOFCs W. Huang, S. Gopalan, U. Pal and S. Basu (Boston University)
08:20   439   Investigation of Oxide Conductivity for Study of SOFC Interconnect Degradation M. Edelen and D. Lewis (Rensselaer Polytechnic Institute)
08:40   440   Mixed Conductive Coatings on Ferritic Stainless Steels for SOFC Interconnect Applications Z. Yang, G. Xia and J. Stevenson (Pacific Northwest National Laboratory)