214th ECS Meeting - Honolulu, HI

October 12 - October 17, 2008

PROGRAM INFORMATION
 

B4 - Intercalation Compounds for Energy Conversion and Storage Devices

Energy Technology/Battery/Physical and Analytical Electrochemistry
 

Monday, October 13, 2008

Honolulu 1; Tapa Conference Center, Hilton Hawaiian Village

Cathodes

Co-Chair(s): K. Zaghib and C. Julien
TimeAbs#Title and Authors
10:00   575   Preparation and Properties of Aluminum Substituted Lithium Nickel Manganese Cobalt Oxides J. Dahn, W. Luo, F. Zhou, X. Zhao (Dalhousie University), J. Jiang (3M Company), Z. Lu (3M Co.) and A. Van Bommel (Dalhousie University)
10:40   576   The Origins of the Rate Enhancement in LiNi0.4Co0.2-yAlyMn0.4O2 (0≤y≤0.2) Cathode Materials J. Wilcox (UC Berkeley/Lawrence Berkeley National Lab) and M. Doeff (Lawrence Berkeley National Laboratory)
11:00   577   High-Capacity Lithium Insertion Materials in the Phase Triangle of LiCoO2-LiNiO2-LiMnO2 T. Ohzuku, S. Kohno, K. Honoki, T. Izumoto (Graduate School of Engineering, Osaka City University) and K. Ariyoshi (Osaka City University)
11:20   578   The Role of Cation Ordering and Segrega-tion in LiNi0.5Mn0.5O2 on the Electrochemical Reactivity N. Yabuuchi (MIT) and Y. Shao-Horn (Massachusetts Institute of Technology)
11:40   579   Synthesis of LiNi1/3Mn1/3Co1/3O2 and Crystal Structure Studies by Electron Diffraction H. Gabrisch, D. Mohanty (University of New Orleans) and R. Yazami (CALTECH/CNRS)
 

Olivines

Co-Chair(s): Z. Ougumi and G. Ceder
TimeAbs#Title and Authors
14:00   580   New Insights In Oxyanions Electrode Materials N. Recham, M. Casas-Cabanas (LRCS/CNRS U. de Picardie Jules Verne), J. Cabana Jiménez, C. Grey (SUNY at Stony Brook), J. Tarascon (Universite de Picardie & CNRS) and M. B. Armand (LRCS/CNRS U. de Picardie Jules Verne)
14:40   581   Some Observations on the Effect of Nanoscale on the Properties of Li Battery Electrodes G. Ceder, L. Wang (Massachusetts Institute of Technology), A. Belcher, Y. Lee (MIT) and K. Kang (KAIST University)
15:00   582   LiFePO4- Molten State: from Ingot to Nano K. Zaghib (Hydro-Quebec), G. Liang (Phostech Lithium), J. Labrecque (Hydro-Quebec), A. Mauger, C. Julien (INSP-CNRS) and M. Gauthier (Phostech Lithium)
15:20   583   Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses J. Chen, M. Doeff and R. Wang (Lawrence Berkeley National Laboratory)
15:40   584   Phase Content, Diffusivity, and Rate Capability in the LiMnyFe1-yPO4 Cathode System A. M. Hashambhoy (Carnegie Mellon University), K. Zaghib (Hydro-Quebec) and J. Whitacre (Carnegie Mellon University)
16:00 Intermission (20 Minutes)
16:20   585   Three Experimental Verifications on LixFePO4: (i) Bulk Miscibility Gap, (ii) Air Exposure Effect, and (iii) Lithium Diffusion A. Yamada (Tokyo Institute of Technology)
17:00   586   Li-Fe-P-O2 Phase Diagram from First Principles Calculations S. Ong, L. Wang, B. Kang and G. Ceder (Massachusetts Institute of Technology)
17:20   587   Effects of Al3+ Doping on the Cycling Performance of LiFePO4 Cathode Materials S. Wu (Tatung University)
17:40   588   Improvement of the High Rate Performance of LiFePO4 B. Kang and G. Ceder (Massachusetts Institute of Technology)
 

Tuesday, October 14, 2008

Honolulu 1; Tapa Conference Center, Hilton Hawaiian Village

Silicates and Olivines

Co-Chair(s): V. Venkat and A. M. Sastry
TimeAbs#Title and Authors
08:00   589   LiFePO4 Surface Reactivity K. Zaghib (Hydro-Quebec), A. Guerfi, P. Charest, M. Dontigny, J. Labrecque (IREQ), A. Mauger (Université Paris6), M. Kopec (Université Paris 6), F. Gendron (Université Paris6) and C. M. Julien (University Paris6)
08:40   590   Neutron Diffraction Study on Lithium Diffusion in LixFePO4 S. Nishimura, G. Kobayashi, R. Kanno (Tokyo Institute of Technology), K. Ohoyama (Tohoku University), M. Yashima and A. Yamada (Tokyo Institute of Technology)
09:00   591   Towards Optimization of Silicate Compounds as Potential Cathodes for Li Ion Batteries R. Dominko (National Institute of Chemistry), I. Arcon (Univeristy of Nova Gorica, Slovenia), G. Mali (National Institute of Chemistry, Ljubljana), A. Kokalj, D. Hanzel (Jozef Stefan Institute, Slovenia), J. Jamnik (National Institute of Chemirstry, Ljubljana) and M. Gaberscek (National Institute of Chemistry)
09:20   592   Combinatorial Study of LiF:M and LiF:M:C (M = Fe, Co or Ni) Nanocomposites as Positive Electrode Materials in Li-ion Batteries P. Liao, R. Dunlap and J. Dahn (Dalhousie University)
09:40 Intermission (20 Minutes)
10:00   593   Phase Transitions, Interfaces, and Stability Relationships in Phosphate Cathodes T. J. Richardson (Lawrence Berkeley National Laboratory)
10:40   594   Novel Synthesis and Electrochemical Behaviour vs. Li of the First Ever Reported Lamellar FeOF Phase N. Recham (LRCS/CNRS U. de Picardie Jules Verne), L. Laffont-Dantras (CNRS/:LRCS université de picardie jules verne), M. B. Armand (LRCS/CNRS U. de Picardie Jules Verne) and J. Tarascon (Universite de Picardie & CNRS)
11:00   595   The Role of Conductive and Ceramic (non-conductive) Coatings in Cathode Materials fot Li Ion Batteries M. Gaberscek (National Institute of Chemistry), B. Erjavec (national Institute of Chemistry, Ljubljana), R. Dominko (National Institute of Chemistry) and J. Jamnik (National Institute of Chemirstry, Ljubljana)
11:20   596   New Synthesis Approaches Towards Polyanionic Compounds Displaying a Li Electrochemical Activity N. Recham, L. Dupont, M. B. Armand (LRCS/CNRS U. de Picardie Jules Verne) and J. Tarascon (Universite de Picardie & CNRS)
11:40   597   Fading MEchanism of Li2MnSiO4 as Cathode Material in Lithium Ion Batteries Y. Li (State Key Laboratory for Physical Chemistry of Solid Surfaces), J. Shen, Z. Gong (State Key Lab for Physical Chemistry of Solid Surfaces and Department of Chemistry, Xiamen University) and Y. Yang (Xiamen University)
 

Intercalation Compounds for Batteries

Co-Chair(s): E. Takeuchi and B. Y . Liaw
TimeAbs#Title and Authors
14:00   598   Electronic and Crystal Structural change Studies of LiMPO4 (M=Fe, Mn. Co Ni) Cathode Materials during Lithium Intercalation and De-intercalation X. Yang (Brookhaven National Lab.), X. Wang (Institute of Physics, Chinese Academy of Sciences), W. Yoon, K. Nam (Brookhaven National Lab.), H. Li (Chinese Academy of Sciences), X. Huang, L. Chen (Institute of Physics, Chinese Academy of Sciences), H. Lee and J. McBreen (Brookhaven National Laboratory)
14:40   599   Understanding the Synthesis of Li[Co1-zAlz]O2 W. Luo and J. Dahn (Dalhousie University)
15:00   600   Synthesis and Characterization of LiNi1/3Mn1/3Co1/3O2 by Wet-Chemical Method X. Zhang, F. Gendron, A. Mauger (Université Paris6), L. Qi (University of Beijing) and C. M. Julien (University Paris6)
15:20   601   Surface Structure Changes of Intercalation Cathodes during the Initial Electrochemical Process M. Hirayama, S. Kazuyuki, T. Takeshi, S. Kouta, C. Woosuk, Y. Atsuo (Tokyo Institute of Technology), T. Kazuhisa, M. Jun'ichiro (Japan Atomic Energy Agency) and K. Ryoji (Tokyo Institute of Technology)
15:40   602   Sputtered LiCoO2 Thin Films: Investigation of Structure-Electrochemistry Relationships as a Function of the Deposition Parameters S. Tintignac, R. Baddour-Hadjean, J. Pereira-Ramos and R. Salot (CNRS)
16:00 Intermission (20 Minutes)
16:20   603   Development of High-Capacity Intercalation Compounds for Lithium-Ion Batteries H. Nakamura, K. Masahara (SANYO Electric Co., Ltd.), M. Saito (SANYO electric Co.,Ltd.), D. Yu, K. Yanagida, M. Fujimoto, Y. Kato, S. Matsuta and S. Fujitani (SANYO Electric Co., Ltd.)
17:00   604   Solid-state Redox Mechanism of Li2MnO3 by First-Principles Calculation Y. Koyama, I. Tanaka (Kyoto University), M. Nagao and R. Kanno (Tokyo Institute of Technology)
17:20   605   Layered Lithium Cobalt and Nickel Nitrides: A New Class of Lithium Intercalation Compounds J. Pereira-Ramos (CNRS), S. Bach (ICMPE, CNRS), J. Ducros (CNRS) and P. Willmann (CNES)
17:40   606   Relationship between Local Structure using PDF Method, Thermodynamic Stability, and Cathode Performance Depend on Different Synthetic Process of LiMn1/3Co1/3Ni1/3O2 as a Cathode Active Material for Li Ion Battery Y. Idemoto, K. Ueki, N. Kitamura and T. Matsui (Tokyo University of Science)
 

Wednesday, October 15, 2008

Honolulu 1; Tapa Conference Center, Hilton Hawaiian Village

Negative, Electrolyte and Modeling

Co-Chair(s): M. Doeff and J. Whitacre
TimeAbs#Title and Authors
08:00   607   Analysis of the Charge/Discharge Behavior of Silicon Anodes V. Srinivasan, V. A. Sethuraman (Lawrence Berkeley National Laboratory) and J. Newman (Univ. of California, Berkeley)
08:40   608   Electrochemical Performances of Si/Cu/Graphite Composite Anode with Different Polymer Binders H. Kim (KIST), K. Chung (Korea Institute of Science and Technology) and B. Cho (KIST)
09:00   609   Phase Diagram and Li Diffusion in Graphitic Carbon K. A. Persson, Y. Hinuma (MIT), S. Meng (University of Florida), A. Van der Ven (University of Michigan) and G. Ceder (Massachusetts Institute of Technology)
09:20   610   Study of Sn30(Co1-xFex)30C40 Alloy Negative Electrode Materials Prepared by Mechanical Attriting P. P. Ferguson, R. Dunlap (Dalhousie) and J. Dahn (Dalhousie University)
09:40 Intermission (20 Minutes)
10:00   611   Design of Li-ion Cells Using Multiscale Modeling C. Wang (Sakti3 Inc., Ann Arbor, Michigan), Y. Chen, X. Zhang and A. Sastry (University of Michigan)
10:40   612   Electrochemical Anion Intercalation into Multiwall Carbon Nanotubes R. Yazami and R. Yazami (CALTECH/CNRS)
11:00   613   Enhanced Li-ion Diffusion via Surface Effect on Nanocrystalline LiCoO2 M. Okubo (Chuo University), T. Kudo and I. Honma (national Institute of Advanced Industrial Science and Technology)
11:20   614   Electrochemical Profile of Lithium Intercalation Compounds in the Aqueous Electrolyte Y. Xia, C. Wang, J. Luo and Y. Wang (Fudan University)
11:40   615   Possibility of Ionic liquid based on Bis(fluorosulfonyl)imide (FSI) for Lithium ion Battery Application M. Kikuta, M. Kono (Dai-ichi Kogyo Seiyaku Co., Ltd.) and M. Ishikawa (Kansai University)
 

Electrode Materials and Safety

Co-Chair(s): X.Q. Yang and T. Ohzuku
TimeAbs#Title and Authors
14:00   616   Overcharge Tolerance of Intercalation Compounds in Lithium-ion Batteries P. Onnerud (Boston-Power Inc.), R. V. Chamberlain (Boston-Power), Y. Song, P. Partin, W. Howard and C. Lampe-Onnerud (Boston-Power Inc.)
14:40   617   Preparation and Electrochemistry of Silver Vanadium Phosphorous Oxide E. S. Takeuchi, K. Takeuchi and A. Marschilok (University at Buffalo)
15:00   618   Effect of Li Addition into NayLixMn1-zCozO2 Cathode Materials M. Saito, S. Tsuruta, M. Fujimoto, K. Masahara, D. Yu, K. Yanagida, Y. Kato, S. Matsuta, R. Matsuoka, H. Nakamura and S. Fujitani (SANYO Electric Co., Ltd.)
15:20   619   EIS Study of Sub-Fluorinated Carbon Fluoride (CFx) in Lithium Batteries Q. Shi (California Institute of Technology) and R. Yazami (CALTECH/CNRS)
15:40   620   Characterization of VO2 (B) Nanorods for Li Battery V. Channu, E. Walker, S. Wicker (Southern University and A&M College), Q. Williams and R. Kalluru (Jackson State University)
16:00 Intermission (20 Minutes)
16:20   621   Lithium Ion Insertion Reaction into Layered Materials Z. Ogumi, T. Abe (Kyoto University) and Y. Iriyama (Shizuoka University)
17:00   622   Comparative Study for Electrochemical Lithiation of Ramsdellite like MnO2 and b-MnO2 H. Noguchi, S. Ennouji, K. Kawaguchi (Saga University) and K. Isono (Saga Univ.)
17:20   623   First-Principles Study of Lithium Intercalation into Doped Crystalline MoO3 and MoS2 Y. Kim, J. Kang (National Renewable Energy Laboratory), S. Lee (University of Colorado at Boulder) and A. Dillon (National Renewable Energy Laboratory)
17:40   624   'Core-shell' Cathode Materials for Lithium-ion Batteries Prepared via Mechanochemical Route N. V. Kosova (Institute of Solid State Chemistry), E. Devyatkina (Institute of Solid State Chemistry SB RAS), V. Kaichev (Boreskov Institute of Catalysis SB RAS) and A. Slobodyuk (Institute of Chemistry FEB RAS)
 

Coral Exhibit Hall, Mid-Pacific Conference Center, Hilton Hawaiian Village

Intercalation Compounds

Co-Chair(s): K. Zaghib, R. Mantz, T. Ohzuku, S. Whittingham and Y-Y. Xia
TimeAbs#Title and Authors
o   625   Nanoparticles Materials Prepared by New Process for Battery Application A. Watanabe (Hosokawa Micron Corporation), A. Guerfi (Hydro-Quebec), M. Fujii (Hosokawa Micron Corporation), A. Vijh (Hydro-Quebec), M. Sadakane (Hosokawa Micron Corporation) and K. Zaghib (Hydro-Quebec)
o   626   Synthesis and Characterization of LiFePO4 Nano-materials Prepared by Wet Chemistry K. Zaghib (Hydro-Quebec), F. Brochu, A. Guerfi (IREQ), M. Kopec (Université Paris 6), A. Mauger, F. Gendron (Université Paris6) and C. M. Julien (University Paris6)
o   627   Studies of the Surface Effect on the Electrochemical Properties of LiFePO4 Nanoparticles K. Zaghib (Hydro-Quebec), A. Mauger, F. Gendron (Université Paris6) and C. M. Julien (University Paris6)
o   628   Isolation of Solid-Solution Phase in LixFePO4 at Room Temperature G. Kobayashi, S. Nishimura, M. Park, R. Kanno, M. Yashima (Tokyo Institute of Technology), T. Ida (Nagoya Institute of Technology) and A. Yamada (Tokyo Institute of Technology)
o   629   Effects of Ti4+ Doping on the Cycling Performance of LiFe1-xTixPO4 Cathode Materials S. Wu (Tatung University)
o   630   Electrochemical Sodium Intercalation of Layered Na(Ni0.5Mn0.5)O2 and NaCrO2 S. Komaba, A. Ogata, T. Shimizu, C. Takei and T. Nakayama (Tokyo University of Science)
o   631   Electrochemical Behavior of Li3-xM1xV2-yM2y(PO4)3 (M1=K, M2=Sc)/C Composite Cathode Material for Lithium-Ion Batteries Y. Mateyshina, A. S. Ulihin and N. Uvarov (Institute of Solid State Chemistry and Mechanochemistry)
o   632   Synthesis and Characterization of LiFePO4 Nanoparticle/Mesoporous Carbon Composites as High-Power Cathode Materials for Lithium-Ion Batteries C. Liang, J. Howe, S. Dai and N. Dudney (Oak Ridge National Laboratory)
o   633   Relating Quench Rate with Performance for Sol-gel Derived Na(Ni1/2Mn1/2)O2 Cathode Materials Y. Zhang and J. Whitacre (Carnegie Mellon University)
o   634   Fabrication of Layered Manganese Oxide Intercalated with Cobalt(II) Ions for Redox Capacitor R. Inoue, K. Suzuki and M. Nakayama (Yamaguchi University)
o   635   In Situ Monitoring of Silicon Negative Electrode for Lithium-Ion Batteries by an Acoustic Emission Technique M. Alias (CEA - LITEN), M. Boinet (Euro Physical Acoustics SA), F. Le Cras (CEA) and T. Brousse (Université de Nantes)
o   636   A High Potential Negative Electrode TiO2(B) Prepared by Solid-State Reaction for Lithium Ion Batteries Y. Murota, Y. Oba, A. Tasaka, K. Hirota and M. Inaba (Doshisha University)
o   637   Photoelectrochemical Properties of TiO2 Electrodes Prepared using Functionalized Plant Oil Binders K. Park, E. Jin and H. Gu (Chonnam National University)
o   638   Electrochemical Properties of Dye-Sensitized TiO2 Solar Cells included Glass Powders E. Jin, H. Li, K. Park and H. Gu (Chonnam National University)
o   639   Efficiency Enhancement of poly(3-hexylthiophene):[6,6]-phenyl-C61-Butyric Acid Methyl Ester Polymer Solar Cell by Blending Palladium Nanoparticles Y. Chen, Y. Tsai, M. Chang, W. Huang (National Sun Yat-Sen University), Y. Han (National Kaohsiung University of Applied Sciences) and K. Chi (National Chung Cheng University)
 

Thursday, October 16, 2008

Honolulu 1; Tapa Conference Center, Hilton Hawaiian Village

Lithium and Metal Hydride Batteries

Co-Chair(s): S. Okada and G. Sakai
TimeAbs#Title and Authors
08:00   640   Methodology for Battery Life Prediction M. Dubarry (Hawaii Natural energy Insitute) and B. Liaw (University of Hawaii)
08:40   641   Mechanism of Lithium Intercalation in TiO2-brookite M. V. Koudriachova and M. Matar (University college London)
09:00   642   Cycling-Induced Crystallographic and Morphological Changes in Na4Mn9O18 A. D. Tevar (Carnegie Mellon University), M. De Graef (Dept. of Materials Science & Engineering, Carnegie Mellon University) and J. Whitacre (Carnegie Mellon University)
09:20   643   Electronic Mechanism of Lithium Insertion in Li0.5TiO2-Spinel M. V. Koudriachova (University College London)
09:40 Intermission (20 Minutes)
10:00   644   Ab Initio Study of Lithium Insertion in TiO2-Ramsdellite M. V. Koudriachova (University College London)
10:20   645   Electrochromic and Pseudocapacitive Properties of Anodically-Grown 2D Manganese Oxide Nanocomposites M. Nakayama, Y. Kashiwa and C. Iida (Yamaguchi University)
10:40   646   Layered Transition Metal Compounds as Cathodes for Sodium Secondary Battery S. Okada, S. Hara, M. Nishijima, T. Doi and J. Yamaki (Kyushu University)
11:00   647   Structure and Electrochemical Hydrogen Storage Properties of Mg-Ti Based Materials Prepared by Mechanical Alloying S. Rousselot, M. Bichat (INRS), D. Guay (INRS-ÉMT) and L. Roué (INRS)
11:20   648   Preparation of High-Surface-Area b-Ni(OH)2 and its Transformation into Nanosheets by Hydrothermal Treatment G. Sakai (University of Miyazaki), M. Miyazaki (Unicersity of Miyazaki) and T. Kijima (University of Miyazaki)
11:40   649   Refined Structural Analysis Using Synchrotron XRD and XAFS for Cobalt Oxyhydroxides as Additive for Nickel Hydroxide Electrode M. Morishita (Collaborative Reserch Team of Secondary Battery System), S. Ochiai, T. Kakeya, T. Ozaki, Y. Kawabe, M. Watada (GS Yuasa Corporation), S. Tanase and T. Sakai (Collaborative Reserch Team of Secondary Battery System)