214th ECS Meeting - Honolulu, HI

October 12 - October 17, 2008

PROGRAM INFORMATION
 

B7 - Non-Aqueous Electrolytes for Lithium Batteries

Battery/Physical and Analytical Electrochemistry
 

Monday, October 13, 2008

South Pacific 1; Mid-Pacific Conference Center, Hilton Hawaiian Village

Solid/Polymer Electrolytes

Co-Chair(s): Michel Armand and Michael Ding
TimeAbs#Title and Authors
14:00   707   Crystalline Small Molecule Lithium-Ion Electrolytes D. A. Ainsworth, C. Zhang, S. Lilley (University of St Andrews), Y. Andreev (Unversity of St Andrews) and P. G. Bruce (University of St Andrews)
14:20   708   Synthesis of an Ethylene Oxide-Acrylate Functionalized Hydrophobic-hydrophilic Viscid Copolymer Electrolyte based on Polysiloxane, and its Conductivity Properties F. Wang, C. Cheng (Industrial Technology Research Institute), C. Wan and Y. Wang (National Tsing Hua University)
14:40   709   Si-Based Electrolyte - From Polysiloxane to Monosilane Z. Zhang (Argonne National Laboratory), R. West (Organosilicon Research Center, University of Wisconsin-Madison) and K. Amine (Argonne National Laboratory)
15:00   710   Detailed Studies on the Composite, PEO-based Polymeric Electrolytes J. S. Syzdek (Warsaw University of Technology), M. Armand (Universite de Picardie Jules Verne), M. Szafran and W. Wieczorek (Warsaw University of Technology)
15:20   711   Ion Assosiation in Liquid Olygoether Systems Observed from the Cation and 19F NMR Spectroscopy A. Plewa-Marczewska (Warsaw University of Technology) and M. S. Siekierski (Warsaw Univesity of Technology)
15:40 Intermission (20 Minutes)
16:00   712   Development of Solid Electrolytes for High-Performance Lithium Batteries R. Murugan (Chr.-Albrechts University) and W. J. Weppner (Chr.-Albrechts-University)
16:20   713   Ion Conduction in Non-aqueous Liquid Electrolytes Containing Ceramic Inclusions S. Das and A. J. Bhattacharyya (Indian Institute of Science)
16:40   714   Investigation on the Anion Complexation Ability of Boroorganic Acids and Esters in Polymer Electrolytes. Spectroscopical Approach Z. Zukowska, M. Szczechura (Warsaw University of Technology), M. Marcinek (Warsaw Univeristy of Technology), A. Zubrowska, A. Sporzyński and W. Wieczorek (Warsaw University of Technology)
 

Tuesday, October 14, 2008

Tapa 3; Tapa Conference Center, Hilton Hawaiian Village

Ionic Liquid Electrolytes

Co-Chair(s): Wesley A. Henderson and Yukio Sasaki
TimeAbs#Title and Authors
08:00   715   Mixtures of Ionic Liquid in Combination with Graphite Electrodes: the Role of Electrolyte Additives and Li-salt A. Balducci (Westfälische Wilhelms University of Münster), G. Appetecchi (Italian National Agency for New Technologies, Energy and the Environment), S. F. Lux (Institute for Chemistry and Technology of Materials, Graz University of Technology), M. Schmuck (Institute for Chemical Technology of Inorganic Materials, Graz University of Technology), M. Winter (Institute of Physical Chemistry, Westfälische Wilhelms University of Münster) and S. Passerini (Italian National Agency for New Technologies, Energy, and the Environment (ENEA), Casaccia Research Center, Rome, Italy; Institute of Physical Chemistry, University of Muenster, Germany)
08:40   716   Electrochemical and Physicochemical Properties of PYR14-FSI Based Electrolytes with LiFSI E. E. Paillard, Q. Zhou, W. Henderson (North Carolina State University), G. Appetecchi (Italian National Agency for New Technologies, Energy and the Environment), M. Montanino (Italian National Agency for New Technologies, Energy, and the Environment (ENEA), Casaccia Research Center, Rome, Italy) and S. Passerini (Italian National Agency for New Technologies, Energy, and the Environment (ENEA), Casaccia Research Center, Rome, Italy; Institute of Physical Chemistry, University of Muenster, Germany)
09:00   717   LiTFSI-Py24TFSI: A Novel Electrolyte for Rechargeable Lithium Batteries A. Fernicola, C. Sirisopanaporn and B. Scrosati (University of Rome)
09:20   718   Spectroscopic Investigation of the Surface of LixMnO2 and LixTi0.11Mn0.89O2 Composite Electrodes in Pyrrolidinium-based Ionic Liquid Electrolyte Systems L. J. Hardwick, J. Saint, M. Doeff and R. Kostecki (Lawrence Berkeley National Laboratory)
09:40 Intermission (20 Minutes)
10:00   719   Dependence of Anionic Species on Li/LiCoO2 Cell Performance Using Ionic Liquids composed of N,N-Diethyl-N-methyl-N-(2-methoxyethyl)ammonium H. Matsumoto, H. Sakaebe (National Institute of Advanced Industrial Science and Technology (AIST)) and K. Tatsumi (National Institute of Advanced Industrial Science and Technology)
10:40   720   Thermal Stability of Room Temperature Ionic Liquids (RTILs) with Asymmetric Cations in Li Battery System H. Sakaebe, H. Matsumoto (National Institute of Advanced Industrial Science and Technology (AIST)), S. Tsuzuki and K. Tatsumi (National Institute of Advanced Industrial Science and Technology)
11:00   721   Electrochemical Lithium Insertion/Extraction for Carbon Electrodes in FSI-based Ionic Liquids M. Ishikawa (Kansai University), T. Sugimoto (Dai-ichi Kogyo Seiyaku Co., Ltd.), Y. Atsumi, M. Yamagata (Kansai University), M. Kikuta, E. Ishiko and M. Kono (Dai-ichi Kogyo Seiyaku Co., Ltd.)
11:40   722   Properties of BMIBF4-LiBF4 Electrolytes for Lithium Ion Batteries N. Giroud, H. Rouault (CEA), E. Chainet and J. Poignet (CNRS)
 

Interface/Kinetics

Co-Chair(s): Brett Lucht and Masashi Ishikawa
TimeAbs#Title and Authors
14:00   723   Ionic Liquids and their Analogs―Electrochemical Behaviors at Electrode/Electrolyte Interface T. Matsui (Panasonic Corporation, Energy Company), M. Deguchi and H. Yoshizawa (Matsushita Battery Industry Co., Ltd.)
14:40   724   Molecular Dynamics Simulations of LiFePO4/Electrolyte Interfaces G. D. Smith and O. Borodin (University of Utah)
15:00   725   Ethylene and Vinylene Carbonate Reduction Mechanisms in Condensed Phase and At Interfaces. A Molecular Dynamics Simulation Study using ReaxFF. D. Bedrov (University of Utah), A. Van Duin (California Institute of Technology) and G. Smith (University of Utah)
15:20   726   Transport Modeling of Electrolyte Speciation at Electrode-Electrolyte Interfaces for Li-ion Systems K. L. Gering (Idaho National Laboratory)
15:40 Intermission (20 Minutes)
16:00   727   Lithium-ion and Anion transfers at Graphite Electrode in Various Electrolytes T. Abe and Z. Ogumi (Kyoto University)
16:40   728   The Film-Forming Properties of Propylene Carbonate (pc) on Graphite Anodes H. Zheng, Q. Qu (Henan Normal University), Z. Ogumi (Kyoto University), G. Liu and V. Battaglia (Lawrence Berkeley National Lab)
17:00   729   Examination of the Solid Electrolyte Interphase on Binder-free Graphite Electrodes in Advanced Electrolytes B. Lucht, A. Xiao (University of Rhode Island), S. Kang and D. Abraham (Argonne National Laboratory)
17:20   730   Reactive Metal Surfaces in Ionic Liquids P. C. Howlett, J. Sun, M. Forsyth and D. MacFarlane (Monash University)
17:40   731   Impact of Electrolyte on SEI and Charge Transfer Kinetics in Lithium-ion Batteries T. Jow and J. Allen (U.S. Army Research Laboratory)
 

Coral Exhibit Hall, Mid-Pacific Conference Center, Hilton Hawaiian Village

Nonaqueous Electrolytes for Lithium Batteries

Co-Chair(s): T. Richard Jow, Wesley A. Henderson, Brett Lucht, Makoto Ue
TimeAbs#Title and Authors
o   732   Poly(acrylonitrile-methyl methacrylate-methoxy polyethylene glycol monoacrylate) Microporous Gel Polymer Electrolyte for Lithium Ion Batteries W. Pu (Tsinghua University), S. Zhang, L. Zhang (Beihang University), X. He, C. Wan and C. Jiang (Tsinghua University)
o   733   Suppression of Dendritic Lithium Formation by Using Concentrated Electrolyte Solutions S. Jeong (Soonchunhyang University), H. Seo (EIG Ltd.), Y. Iriyama (Shizuoka University), T. Abe and Z. Ogumi (Kyoto University)
o   734   Ionic Liquids Based on the Sulfide and Polysulfide Anions A. T. Yeates and D. Dudis (Air Force Research Laboratory)
o   735   Formation and Properties of the Interface Layer at Lithium Electrodes N. J. Dudney (Oak Ridge National Lab), S. Park, K. More and N. De Jonge (Oak Ridge National Laboratory)
o   736   Imidazole-Modified RTILs as Electrolytes for Rechargeable Lithium Batteries O. E. Geiculescu, R. Rajagopal, J. Oh, C. Lu, S. Creager and D. DesMarteau (Clemson University)
 

Wednesday, October 15, 2008

Tapa 3; Tapa Conference Center, Hilton Hawaiian Village

New Salts/Solvents

Co-Chair(s): Makoto Ue and Marshall Smart
TimeAbs#Title and Authors
08:00   737   New Covalent Salts Of The 4+ Volt Class S. Laruelle, S. Grugeon (LRCS), P. Johansson (Chalmers U. of technology , Sweden), L. Niedzicki, M. Bukowska, P. Szczecinski, W. Wieczorek (Warsaw University of Technology Poland) and M. B. Armand (LRCS/CNRS U. de Picardie Jules Verne)
08:40   738   Novel Electrolyte for Lithium Ion Batteries: Lithum Tetrafluorooxalatophosphate (LiPF4C2O4) B. Lucht, A. Xiao, M. Xu and L. Yang (University of Rhode Island)
09:00   739   Ion Diffusion and Lithium Jump of Li2B12F12 dissolved in Propylene Carbonate (PC) studied by NMR Spectroscopy K. Hayamizu, M. Hattori (National Institute of Advanced Industrial Science and Technology), J. Arai and A. Matsuo (Air Products Japan)
09:20   740   LiBOB as Conductive Salt or Additive for Li-Ion Batteries C. E. Taeubert, M. Wohlfahrt-Mehrens (ZSW-Zentrum für Sonnenenergie- und Wasserstoff-Forschung), U. Wietelmann and T. Buhrmester (Chemetall GmbH, Frankfurt a.M., Germany)
09:40 Intermission (20 Minutes)
10:00   741   Physical and Electrolytic Properties of Partially Fluorinated Organic Solvents and Its Application to Secondary Lithium Batteries Y. Sasaki (Tokyo Polytechnic University)
10:40   742   Glyme-LiTFSI Complex as Electrolytes for Lithium Secondary Batteries M. Nakamura, Y. Kazue (Yokohama National University), S. Seki (Central Research Institute of Electric Power Industry), K. Dokko and M. Watanabe (Yokohama National University)
11:00   743   New Electrolytes for Lithium Ion Batteries Using LiF or Li2O Together with Boron Based Anion Receptors B. Xie, L. Li (Institute of Physics, Chinese Academy of Sciences), H. Lee (Brookhaven National Laboratory), H. Li (Chinese Academy of Sciences), X. Huang, L. Chen (Institute of Physics, Chinese Academy of Sciences), J. McBreen (Brookhaven National Laboratory) and X. Yang (Brookhaven National Lab.)
11:20   744   GBL Based Electrolyte and Different Types of Electrode: Safety and Performance Aspects D. Belov, D. Shieh and M. Yang (Industrial Technology Research Institute (ITRI))
11:40   745   Lithium-Ion Electrolytes Containing Flame-Retardant Additives for Increased Safety Characteristics K. A. Smith (Jet Propulsion Laboratory), M. C. Smart (Jet Propulsion Laboratory, California Institute of Technology), R. Bugga (Jet Propulsion Laboratory) and G. Prakash (University of Southern California)
 

Properties/Performance

Co-Chair(s): T. Richard Jow and Tooru Matsui
TimeAbs#Title and Authors
14:00   746   Thermal Behavior of Nonaqueous Electrolytes in Lithium-ion Cells M. Ue (Mitsubishi Chemical Corporation)
14:40   747   Combustion Studies of Electrolyte Solvents S. J. Harris, A. Timmons (General Motors R&D) and W. Pitz (Lawrence Livermore National Laboratory)
15:00   748   Novel SEI Formation of Maleimide Based Additives and its Improvement of Capability and Cyclicability in Lithium Ion Batteries F. Wang, C. Yang and C. Cheng (Industrial Technology Research Institute)
15:20   749   The Impact of Li-ion Battery Electrolyte Impurities on Performance Decline and Self-discharge P. Basak, L. Beer and J. B. Kerr (LBNL)
15:40 Intermission (20 Minutes)
16:00   750   Improved Low Temperature Performance of High Rate Nano-Lithium Iron Phosphate-Based Li-Ion Cells with Advanced Electrolytes M. C. Smart, B. Ratnakumar (Jet Propulsion Laboratory, California Institute of Technology), A. Gozdz (A123Systems, Inc.) and S. Mani (A123 Systems' Advanced Research and Government Solutions Division)
16:40   751   Physicochemical Properties of Non-Aqueous Solvents and Electrolytes for Lithium Battery Applications M. Ding and T. Jow (U.S. Army Research Laboratory)
17:20   752   An Organic Electrolyte Mixed with a Quaternary Phosphonium Salt for Lithium Secondary Batteries K. Tsunashima, F. Yonekawa, M. Kikuchi and M. Sugiya (Nippon Chemical Industrial Co., Ltd.)
17:40   753   A New Concept for Lithium Primary Cells using Poly(carbon Monofluoride) Cathode -The Effect of Quinone Compounds as an Electrolyte Additive- D. Noda (Mitsubishi Chemical Group. Science And Technology Research Center, Inc.), M. Takeda (Mitsubishi Chemical Corporation), S. Kinoshita (Mitsubishi Chemical Group. Science And Technology Research Center, Inc.) and M. Ue (Mitsubishi Chemical Corporation)