214th ECS Meeting - Honolulu, HI

October 12 - October 17, 2008

PROGRAM INFORMATION
 

I3 - Electrocatalysis

Physical and Analytical Electrochemistry/Industrial Electrochemistry and Electrochemical Engineering/Energy Technology
 

Wednesday, October 15, 2008

Coral 2; Mid-Pacific Conference Center, Hilton Hawaiian Village

Oxygen reduction reaction

Co-Chair(s): G. Brisard and A. Wieckowski
TimeAbs#Title and Authors
08:00   2855   Ptmi/Pd/C Core-Shell Electrocatalysts for the ORR in PEMFCs B. C. Tessier (Jonhson Matthey Technology Centre), A. E. Russell (University of Southampton), B. R. Theobald and D. Thompsett (Jonhson Matthey Technology Centre, Sonning Common, UK)
08:20   2856   Oxygen Reduction Reaction on Carbon Supported Pt and Pd in Alkaline Solutions L. Jiang, A. Hsu (Indiana University Purdue University, Indianapolis), D. Chu (Army Research Laboratory) and R. Chen (Indiana University- Purdue University Indianapolis)
08:40   2857   Electrodeposited Pt1-x(Ni, Co, Fe)x ORR Catalyst T. Moffat and J. Mallett (NIST)
09:00   2858   Development of Bifunctional Electrocatalytic Systems for Oxygen Reduction P. J. Kulesza, B. Dembinska, M. Ratter, K. Miecznikowski (Warsaw University) and A. Lewera (University of Warsaw)
09:20   2859   Analyses of Oxygen Species Relating to Oxygen Reduction Reaction at Pt(111) and Polycrystalline Pt Electrodes by EC-XPS M. Wakisaka, H. Suzuki, H. Uchida and M. Watanabe (University of Yamanashi)
09:40 Intermission (20 Minutes)
10:00   2860   Platinum Monolayer Electrocatalysts: Tuning the Pt Monolayer-Supporting Core Interaction by a Pd Interlayer W. Chen, M. Vukmirovic, W. Zhou (Brookhaven National Laboratory) and R. Adzic (Brookhaven)
10:20   2861   X-ray Absorption Spectroscopy Study of Electrocatalytic Mechanism of Cobalt-based Chelate Catalyst for Oxygen Reduction Reaction H. Zhang (Shanghai Jiaotong University), W. Wen (Brookhaven National Laboratory), D. Zhang, X. Yuan and Z. Ma (Shanghai Jiaotong University)
10:40   2862   Fundamental Understanding of Co- and Fe-Phthalocyanines for Oxygen Reduction Reactions in Alkaline Solution M. J. Reed (Lugar Center for Renewable Energy), G. Wang (Indiana University- Purdue University Indianapolis), D. Chu (Army Research Laboratory) and R. Chen (Indiana University- Purdue University Indianapolis)
11:00   2863   Oxygen Reduction Reaction on Non-Noble Catalysts in Alkaline Media J. Spendelow (Los Alamos National Laboratory) and B. Pivovar (Los Alamos National Lab)
11:20   2864   Pyrolyzed Porphyrin Non-platinum Oxygen Reduction Catalysts: Structure-to-Properties Correlations T. Olson, S. Pylypenko and P. Atanassov (University of New Mexico)
11:40   2865   Development of PEFC Cathode Catalysts based on Metal-oxide Supports H. Notsu, T. Kitamura and I. Yagi (Advanced Institute of Science and Technology)
 

Surface Characterization

Co-Chair(s): M. Osawa and I.T. Bae
TimeAbs#Title and Authors
13:40   2866   X-ray Studies of Ordered Intermetallic Phases for Fuel Cell Applications Y. Liu and H. Abruña (Cornell University)
14:00   2867   Atomic-Level Structural Dynamics during Dealloying of Bimetallic Nanoparticle Catalysts - a Combined Synchrotron in-situ SAXS and in situ XRD Study C. Yu, S. Koh (University of Houston), M. Toney (SLAC) and P. Strasser (University of Houston)
14:20   2868   Electronic Interactions Between Components and Adsorbates on Fuel Cell Catalysts - Combined XPS and Electrochemical Studies A. Lewera, P. J. Barczuk (University of Warsaw), K. Miecznikowski (Warsaw University), R. Hunger, W. Jaegermann (Technische Universität Darmstadt), P. Bagus (University of North Texas), N. Alonso-Vante (Universite de Poitiers), A. Wieckowski (University of Illinois) and P. J. Kulesza (Warsaw University)
14:40   2869   Small Angle X-ray Scattering (SAXS) for detection of Particle Size Distribution dynamics of PEM Fuel Cell Electrocatalysts S. Koh, C. Yu (University of Houston), M. Toney (SLAC) and P. Strasser (University of Houston)
15:00   2870   In situ XAS Studies on PVP Stabilized and Specifically Shaped Pt Nanoparticles in 1M HClO4 B. Shyam (George Washington University), C. Susut (Georgetown University), T. Arruda, S. Mukerjee (Northeastern University), Y. Tong (Georgetown University) and D. Ramaker (George Washington University)
15:20   2871   Evaluation of Atomic Processes in Electro-chemical reactions: Site-selective Anodic Dissolution of Metals and Semiconductors K. Itaya, T. Minato (Tohoku University) and A. Kuzume (Tohoku Univ.)
15:40   2872   Video Rate AFM for Investigation of Dynamical Processes of Electrochemical Reactions T. Minato (Tohoku University), K. Yoshida (Tohoku Univ.), R. Mizuno, T. Morii, T. Okada (RIBM), A. Kuzume (Tohoku Univ.) and K. Itaya (Tohoku University)
16:00   2873   Electrochemical Investigation of Cu Deposition Reaction on Corronene Adsorbed Au(111) T. Sawaguchi (National Institute of Advanced Industrial Science and Technology) and S. Yoshimoto (Kumamoto University)
16:20   2874   Enhanced Hydrogen Evolution Reaction on an Ag Electrode Catalyzed by Proton-coupled Redox of 4,4'-Bipyridine Adsorbed on the Surface T. Uchida (Hokkaido University), A. Yamakata (Hokkaido Univ.), Y. Sasaki and M. Osawa (Hokkaido University)
16:40   2875   Structure of Oxygenated Cobalt Porphyrin as Probed by X-ray Absorption Spectroscopy I. Bae (Needham Technical Center), J. Nelson (Needham Technical Center, Procter and Gamble) and W. Yoon (Brookhaven National Lab.)
17:00   2876   In Situ FTIR Spectroscopic Studies of Electrooxidation of Small Organic Molecules Z. Zhou (Department of Chemistry, Xiamen University), D. Chen, H. Li (College of Chemistry and Chemical Engineering, Xiamen University) and S. Sun (Xiamen University)
17:20   2877   Direct Monitoring of the Bond Strength of CO on Pt electrodes in a Thin Layer Flow Cell by in‐situ Electrochemical Surface‐enhanced Infrared /Raman Spectroscopy Y. Chen (University of Science and Technology of China)
 

Coral Exhibit Hall, Mid-Pacific Conference Center, Hilton Hawaiian Village

Electrocatalysis

Co-Chair(s): G. Brisard and I. T. Bae
TimeAbs#Title and Authors
o Intermission (20 Minutes)
o   2878   Activating Pd by Morphology Tailoring for Oxygen Reduction L. Xiao, L. Zhuang, J. Lu (Wuhan University) and H. Abruña (Cornell University)
o   2879   PtRh/C Electrocatalysts for Dehydrogenative Oxidation of Cyclohexane over Polymer Electrolyte Membrane Fuel Cell H. Kim, S. Choi (Gwangju Institute of Science and Technology (GIST)), S. Nam (Gwangju Institute of Science and Engineering), M. Seo (Gwangju Institute of Science and Technology (GIST)) and W. Kim (Gwangju Institute of Science and Technology)
o   2880   Structural Effects on Electrochemical Reduction of Nitrate at Pt(S)[n(111)×(111)] and Pt(S)[n(111)×(100)] Electrodes in Acidic Medium S. Taguchi (Hokkadio University of Education Sapporo) and J. Feliu (Universidad de Alicante)
o   2881   Infrared Spectroscopy of Formic Acid Oxidation on Low-index Pt Surfaces M. Nakamura, S. Saiki and N. Hoshi (Chiba University)
o   2882   Electrochemical Reductions of Carbon Dioxides with Gas Diffusion Electrodes Catalyzed by Cuprous Oxide R. Liang, T. Chang (National Chiao Tung University), P. Wu (National Chiao-Tung University) and P. Lin (National Chiao Tung University)
o   2883   Molecular Structures of Organic Single Crystals Investigated by New Scanning Probe Microscopes T. Minato, H. Aoki (Tohoku University), T. Wagner (Universität Duisburg-Essen), K. Sato and K. Itaya (Tohoku University)
o   2884   Comparison of the Efficiencies of Different Carbons to Produce Hydrogen by Carbon-assisted Water Electrolysis at Room Temperature M. S. Seehra and S. Bollineni (West Virginia University)
o   2885   Peroxynitrite Activation By Inducible Nitric Oxide Synthase (iNOS). J. A. Boutros, K. Benmerzouga and M. Bayachou (Cleveland State University)
o   2886   Effect of Conserved Arg 375 On The Tetrahydrobiopterin (H4B) Binding to Inducible Nitric Oxide Synthase (iNOS): A Thermodynamic And Kinetic Study Of Electron Transfer. M. Bayachou and J. A. Boutros (Cleveland State University)
o   2887   Fast Screening of Durable Catalysts/supports for PEM Fuel Cells with SECM and Multi-channel Disk Electrodes Y. Shao (Pacific Northwest National Lab), J. Wang (Pacific Northwest National Laboratory), S. Towne, V. Viswanathan (Pacific Northwest National Lab), R. Kou (Pacific Northwest National Laboratory), J. Kwak (Pacific Northwest National Lab), J. Liu (Pacific Northwest National Laboratory), Y. Wang (Pacific Northwest National Lab) and Y. Lin (Pacific Northwest National Laboratory)
o   2888   Methanol Electrooxidation on Bulk and Carbon Supported Nanoparticle Pt and PtRu Catalysts: a DEMS Study H. Wang (Cornell University)
o   2889   Non-noble Metal Catalyst Based on CoTETA/C for Oxygen Reduction Reaction H. Zhang, X. Xia, X. Yuan, D. Zhang and Z. Ma (Shanghai Jiaotong University)
o   2890   Effects of Electrodeposited Co-P Catalysts on the Hydrogen Generation Properties by Methanolysis of NaBH4 K. Cho (KAIST, KOREA), K. Karan (Department of Chemical Engineering, Queen's University, Kingston, Ontario, Canada), K. Eom (KAIST) and H. Kwon (Korea Advanced Institute of Science and Technology)
o   2891   Direct Electrochemistry of Chloroperoxidase Pyrolytic Graphite Electrode Modified with DDAB and its Application X. Wu, W. Hou, Z. Lu, R. Wang and H. Li (Shanghai Normal University)
o   2892   The Matrix Effect of Conducting Polyaniline on the Anodic Catalyst of Pem Fuel Cells M. Dagdevren (Istanbul Technical University Science and Letters Faculty) and F. Kadirgan (Istanbul Technical University Science and letters Faculty Chemistry Department)
o   2893   An Electrochemical STM in-situ Study of PtCo Films Q. Xu (Honda Research Institute), E. Kreidler (Honda Research Institute USA), K. Sieradzki (Arizona State University) and T. He (Honda Research Institute USA)
o   2894   Porous Nickel Electrocatalyts through Electroplating for Hydrogen Production W. B. Ingler Jr., M. Adiga, S. Bhandari, N. Adiga and X. Deng (University of Toledo)
o   2895   Palladium-Cobalt Precursor for Catalyst Formation on Carbon Surfaces L. Arroyo-Ramírez, D. Raptis (University of Puerto Rico, Río Piedras Campus) and C. R. Cabrera (University of Puerto Rico)
o   2896   Evaluation of the Catalytic Electrodes to Generate Oxygen Bubbles for the Electroflotation Process R. Pérez, M. Oropeza (Centro de Graduados e Investigación del Instituto Tecnológico de Tijuana), L. Oscar (Universidad Autonoma Metropolitana-Iztapalapa) and I. Gradilla (Centro de Nanotecnología y Nanociencia, UNAM)
o   2897   Preparation of Porous Ni-BaZr(Y)O3 Anode Cermet for High Temperature Proton-conducting Oxide Fuel Cell D. Seo, S. Park, J. Kim and Y. Shul (Yonsei university)
o   2898   Evaluation of the Catalytic Electrodes to Generate Oxygen Bubbles for the Electroflotation Process. R. Pérez, M. Oropeza (Centro de Graduados e Investigación del Instituto Tecnológico de Tijuana), L. Oscar (Universidad Autonoma Metropolitana-Iztapalapa) and I. Gradilla (Centro de Nanotecnología y Nanociencia, UNAM)
 

Thursday, October 16, 2008

Coral 2; Mid-Pacific Conference Center, Hilton Hawaiian Village

Theory and modeling

Co-Chair(s): A. Wieckowski and M. Osawa
TimeAbs#Title and Authors
08:20   2899   Adlayer Structure on Pt(111): A First-Principles Study of the Water Discharge Mechanism V. Rai (Stanford University), M. Aryanpour (Cornell University) and H. Pitsch (Stanford University)
08:40   2900   Theoretical Studies on the Elementary Catalytic Reactions on Pt(111) Surface: First-principles Calculation for Potential Dependence of the Reaction M. Yamamoto (Kyoto University)
09:00   2901   Water Diffusion on Pt(111) Terrace, Kink and Steps: Density Functional Theory Study of Water Interaction and Diffusion. L. Arnadottir, E. Stuve (University of Washington) and H. Jónsson (University of Iceland)
09:20   2902   A First-Principles Simulation of the Electrochemical Interface: Electrooxidation of Molecular Hydrogen and UPD States of Hydrogen at Pt-Electrode/Water Interface Y. Ishikawa (University of Puerto Rico)
09:40 Intermission (20 Minutes)
10:00   2903   Theoretical Study of the Adsorption and Dissociation of Oxygen on Pt3Ni Alloy Nano-particles for Fuel Cell Applications P. Shirvanian (Ford Motor Company)
10:20   2904   Quantitative Property-Activity Relationship (QPAS) of PtRu/C for Methanol oxidation J. Lu, D. Wang, L. Zhuang and P. Liu (Wuhan University)
10:40   2905   First-Principles Studies of Surface Oxide Formation on Pt Electrode L. Qi and J. Li (University of Pennsylvania)
11:00   2906   Adatom Diffusion on Pt Surface at Variant Electrode Potential Y. Fujiwara (Honda Research Institute), L. Qi (University of Pennsylvania), T. He (Honda Research Institute USA) and J. Li (University of Pennsylvania)
11:20   2907   Accelerating Electrocatalysts Design by Structure-to-Property Modeling between X-ray Photoelectron Data and Electrochemical Performance K. Artyushkova, S. Pylypenko, T. Olson, M. Dowlapalli and P. Atanassov (University of New Mexico)
11:40   2908   Models for Magnetic Effects on Electron Transfer Processes S. Minteer (Saint Louis University) and J. Leddy (University of Iowa)
 

Nanoparticules Catalysts for Oxidation

Co-Chair(s): I.T. Bae and G. Brisard
TimeAbs#Title and Authors
14:00   2909   In situ Characterization of Pt/Rh/SnO2 Catalysts for Ethanol Oxidation N. Marinkovic (University of Delaware), M. Li, K. Sasaki (Brookhaven National Laboratory), A. Frenkel (Yeshiva University, New York), A. Kowal (Institute for Catalysis, Krakow, Poland) and R. Adzic (Brookhaven)
14:20   2910   Nanoparticle Arrays on Glassy Carbon as Model Fuel Cell Electrocatalysts R. S. Goeke (Sandia National Laboratories), A. Datye, P. Atanassov (University of New Mexico), J. St-Pierre (University of South Carolina), K. Artyushkova (University of New Mexico) and Y. Gu (University of South Carolina)
14:40   2911   Electrooxidation of Methanol on Electrodeposited Nanoparticles of Pt on Conductive Polymer PEDOT S. Patra and M. Nookala (Indian Institute of Science)
15:00   2912   Enhancement of Oxidation of Ethanol at Polyoxometallate-Modified Multi-Metallic Electrocatalysts P. J. Barczuk (University of Warsaw), G. Garczynski (Warsaw University), A. Lewera (University of Warsaw) and P. J. Kulesza (Warsaw University)
15:20   2913   Correlation of Size-Dependent Activity of Pt Nanoparticles for Carbon Monoxide and Methanol Oxidation to Surface Atomic and Electronic Structures S. Lee, S. Chen, N. Yabuuchi (MIT), W. Sheng (Massachusetts Institute of Technology), Y. Kim (Pusan National University), T. Mitani (JAIST) and Y. Shao-Horn (Massachusetts Institute of Technology)
15:40   2914   Particle Size Effect: Comparing Amorphous and Crystalline Structured Nanocatalysts R. J. Gilliam, D. W. Kirk and S. Thorpe (University of Toronto)
16:00   2915   Characterization of Pt/C and Ru/Pt/C Nanocatalysts Prepared by the RoDSE Technique D. Santiago (University of Puerto Rico), D. López-Salcedo (University of Puerto Rico, Rio Piedras Campus), G. Rodrígiez-Calero and C. R. Cabrera (University of Puerto Rico)
16:20   2916   Hydrogen Spillover-reverse Spillover Phenomena at Ta2O5-coated Pt Electrodes in Acidic Media T. Ohsaka, S. Sata, M. Awad, M. El-Deab, F. Kitamura and T. Okajima (Tokyo Institute of Technology)
16:40   2917   Carbon Nanotubes Supported Bimetallic Gold-Palladium Electrocatalysts for Formic Acid Electrooxidation C. Chen, D. Chen, S. Wu, W. Liou, H. Lin (Tatung University), L. Stobinski, A. Borodzinski and P. Kedzierzawski (Polish Academy of Sciences)
17:00   2918   Electrochemically Shape-controlled Synthesis of Pt Group Metal Nanocatalysts with High-index Facets N. Tian (College of Chemistry and Chemical Engineering, Xiamen University), Z. Zhou (Department of Chemistry, Xiamen University), Z. Huang, D. Chen (College of Chemistry and Chemical Engineering, Xiamen University) and S. Sun (Xiamen University)
 

Friday, October 17, 2008

Coral 2; Mid-Pacific Conference Center, Hilton Hawaiian Village

Various applications of electrocatalysts

Co-Chair(s): G. Brisard and A. Wieckowski
TimeAbs#Title and Authors
08:20   2919   Solar-Powered Electrochemical Oxidation of Organic Compounds Coupled with the Cathodic Production of Molecular Hydrogen H. Park, C. Vecitis and M. Hoffmann (California Institute of Technology)
08:40   2920   Structural Effects on the Oxidation of Ascorbic Acid on Single Crystal Electrodes of Palladium N. Hoshi, M. Nakamura (Chiba University), T. Urada (Chiba Univesity) and N. Miura (Chiba University)
09:00   2921   Optimized Photocatalytic Degradation of Pesticides in Water with TiO2 N. Li (Graduate School of Engineering, Mie University), S. Kaneco, H. Katsumata, T. Suzuki (Mie University), S. Nakaguchi, K. Okano (Graduate School of Engineering, Mie University) and K. Ohta (Mie University)
09:20   2922   Electrodeposition of Platinum-iridium Alloys and its Application as Electrocatalysts in Ammonia Oxidation T. Jiang and G. Botte (Ohio University)
09:40 Intermission (20 Minutes)
10:00   2923   Spectral Studies of Formic Acid Oxidation Using Broad-Band Sum Frequency Generation R. L. Behrens, A. Lagutchev, D. Dlott and A. Wieckowski (University of Illinois)
10:20   2924   Electro-oxidation of Dimethyl Ether (DME) on Platinum Single Crystal Electrode Surfaces L. Lu, Y. Tong (Hokkaido University), Y. Zhang, G. Yin, Y. Gao (Harbin Inst. of Tech.), M. Osawa and S. Ye (Hokkaido University)
10:40   2925   Multipurpose Spectroscopic Fuel Cell for Evaluation of In Operando Membrane Electrode Assemblies E. A. Lewis, A. Rivera (Northeastern University), Q. Jia (Illinios Institute of Technology), S. Stoupin (Northeastern University), H. Rivera (University of Puerto Rico at Rio Peidras), C. R. Grice (NuVant Systems, Inc.), C. Segre (Illinios Institute of Technology) and E. Smotkin (Northeastern University)
11:00   2926   Thermal Annealing Effects on the Water Uptake and Interfacial Structural Changes of Sub- micron Films of Nafion Measured by Neutron Reflectivity V. Murthi (UMD/NIST), J. Dura, S. Satija and C. Majkrzak (NIST Center for Neutron Research)
11:20   2927   Synthesis and Characterization of Stoichiometric La0.6Ca0.4CoxRu1-xO3 as Bifunctional Electrocatalysts in Alkaline Electrolyte Y. Chang (National Chiao Tung University), P. Wu (National Chiao-Tung University) and Y. Chang (National Chiao Tung University)