221st ECS Meeting - Seattle, Washington

May 6 - May 10, 2012



I7 - Recent Advances in Spectro-Electrochemistry


Monday, May 7, 2012

Room 613, Level 6, Washington State Convention Center

The Introduction and Raman Spectroscopy

Co-Chairs: S. Mukerjee and A. Wieckowski
TimeProgr#Title and Authors
08:30   1552   Progress in IR Spectroelectrochemistry S. Mukerjee (Northeastern University) and A. Wieckowski (University of Illinois)
09:00   1553   Uniform Arrays of SiO2@Au Core-Shell Particles for In-Situ Surface-enhanced Raman Spectroscopy: Application to Studies of Nafion Adsorption J. Zeng, D. Jean, and S. Zou (Miami University)
09:30 Intermission (30 Minutes)
10:00   1554   Polarization Characteristics of SERS Photons from Molecules at Liquid/Plasmonic Metal Interface K. Murakoshi (Hokkaido University)
10:30   1555   Gap-mode SERS Observation at Atomically Defined Catalytic Metal Surfaces K. Ikeda (Hokkaido University) and K. Uosaki (National Institute for Materials Science)
11:00   1556   Structure of Water and Other Molecules at the Electrified Solid Liquid Interface Using Raman Spectrosocopy A. Gewirth (University of Illinois Urbana Champaign) and D. Butcher Jr. (University of Illinois)
11:30 Discussion (30 Minutes)

Solid/Liquid Interfaces

Co-Chairs: N. Markovic and M. Fayer
TimeProgr#Title and Authors
14:00   1557   Dynamics of Interfaces Studied with Ultrafast 2D IR Vibrational Echo Spectroscopy M. D. Fayer (Stanford University)
14:30   1558   Tuning Hydrogen Oxidation and Oxygen Reduction Reaction in Alloy Electrocatalysts for Fuel Cells S. Yoo (Korea Institute of Science and Technology) and Y. Sung (Seoul National University)
15:00   1559   The Mechanism of the Direct and the Indirect Paths of the Electrocatalytic Oxidation of Formic Acid on Metals A. Cuesta, G. Cabello (CSIC), M. Osawa (Hokkaido University), and C. Gutiérrez (CSIC)
15:30   1560   Controlling Reactivity of Electrochemical Interfaces by Tuning Non-covalent Interactions D. Strmcnik, R. Subbaraman, D. Tripkovic, K. Chang, N. Danilovic, D. F. Van der Vliet, P. Lopes, A. Paulikas, V. R. Stamenkovic, and N. M. Markovic (Argonne National Laboratory)
16:00 Discussion (30 Minutes)

Tuesday, May 8, 2012

Room 613, Level 6, Washington State Convention Center

Vibrational SFG

Co-Chairs: B. Braunschweig and E. Borguet
TimeProgr#Title and Authors
08:30   1561   In Situ Studies of Lithium-Ion battery Solid-Electrolyte Interphase Formation Using Nonlinear Coherent Vibrational Spectroscopy P. Mukherjee, A. Lagutchev (University of Illinois at Urbana-Champaign), and D. D. Dlott (University of Illinois)
09:00   1562   Heterodyne-Detected 2D Sum Frequency Generation of Pt-CO: A Probe of Dynamics at Catalytic Interfaces J. Laaser (UW-Madison), W. Xiong, R. Mehlenbacher, and M. Zanni (UW-Madison Chemistry)
09:30 Intermission (30 Minutes)
10:00   1563   Molecular Structure of Charged α-Al2O3(0001) Surfaces in Aqueous Electrolytes Probed with Sum-Frequency Vibration Spectroscopy W. Daum (Clausthal University of Technology), A. Rumpel, and B. Braunschweig (University Erlangen-Nuremberg)
10:30   1564   Probing the Molecular Structure of Electrode−Electrolyte Interfaces with Broadband Sum-Frequency Generation B. Braunschweig (University Erlangen-Nuremberg), R. Kutz, P. Mukherjee (University of Illinois at Urbana-Champaign), D. D. Dlott, and A. Wieckowski (University of Illinois)
11:00   1565   Ultra-broadband Vibrational Sum-Frequency Spectroscopy of OH Groups at a Charged Mineral/Aqueous Interface O. Isaienko (Temple University), S. Nihonyanagi (Riken), D. Sil, and E. Borguet (Temple University)
11:30   1566   Comparative Study on the Reaction Intermediates of Ethanol Electro-Oxidation Over Pt Probed by FTIR and SFG Spectroscopies J. Fernandes Gomes, G. Tremiliosi-Filho (Universidade de São Paulo), K. Bergamaski (Universidade Federal de Sergipe), and P. Barbeitas Miranda (Universidade de São Paulo)
12:00 Discussion (30 Minutes)

Wednesday, May 9, 2012

Room 613, Level 6, Washington State Convention Center

Infrared measurements

Co-Chairs: D. Scherson and J. Lipkowski
TimeProgr#Title and Authors
08:00   1567   A Combined In Situ Spectroelectrochemical NMR and IR Investigations of Ru@Pt and Au@Pt Nanoparticles D. Atienza, D. Chen, A. Hofstead-Duffy, I. Park, and Y. J. Tong (Georgetown University)
08:30   1568   Infrared Studies of the Potential Controlled Adsorption of Sodium Dodecyl Sulfate at the Au(111) Electrode Surface J. Leitch (University of Guelph), K. Friedrich (cGerman Aerospace Center Institute of Technical Thermodynamics), U. Stimming (Technical University Munich), J. Dutcher, and J. Lipkowski (University of Guelph)
09:00   1569   IR Analysis of Polymer Electrolytes Using a "Color-coded" Coordinate Subset Representation of Functional Groups E. Smotkin (Northeastern University), N. Dimakis (University of Texas-Pan American), I. Kendrick (Northeastern University), T. Mion (University of Texas-Pan American), and A. Yakaboski (Northeastern University)
09:30 Intermission (30 Minutes)
10:00   1570   In-situ Infrared Spectroscopy at Solid-Liquid Interfaces as a Tool for Evaluation of Nanoscale Surface Morphology D. Tripkovic, D. Strmcnik, D. F. Van der Vliet, C. Wang, N. M. Markovic, and V. R. Stamenkovic (Argonne National Laboratory)
10:30   1571   Interfacial Water Structure at the Aqueous Salt-Fused Silica Interface P. A. Covert, K. Jena, and D. K. Hore (University of Victoria)
11:00   1572   The Electrochemistry of Hydroxylamine on Au and Pd@Au Surfaces: Electrochemical and In Situ Spectroscopic Studies A. Jacob Jebaraj, D. Godoi, and D. Scherson (Case western Reserve University)
11:30   1573   Competitive and Co-Adsorption of Additives for Cu Electrodeposition Investigated by SEIRAS G. Liu, S. Zou, L. Richter, and T. Moffat (NIST)
12:00 Discussion (30 Minutes)

XAS (and X-ray Scattering)

Co-Chairs: H. You and S. Mukerjee
TimeProgr#Title and Authors
14:00   1574   In Situ XAS and IRRAS of Platinum Monolayer Fuel Cell Electrocatalysts M. Li, K. Sasaki, M. B. Vukmirovic, and R. R. Adzic (Brookhaven National Laboratory)
14:30   1575   In-operando study of PEM Fuel Cells using Ambient Pressure Photoemission H. G. Sanchez Casalongue (Stanford University), S. Kaya, H. Ogasawara, S. Cho (SSRL), D. Miller (Stanford University), D. Friebel, and A. Nilsson (SSRL)
15:00   1576   Study of Electrode Surface Dynamics Using Coherent Surface X-ray Scattering M. Pierce, V. Komanicky, A. Barbour (Argonne National Laboratory), C. Zhu (Argonne National Laboratoroy), and H. You (Argonne National Laboratory)
15:30   1577   In Situ and Operando Site Specific Surface Probe Using Synchrotron XANES for Investigating Ensemble and Morphology Effects in Electrocatalysis S. Mukerjee (Northeastern University), D. Ramaker (George Washington University), N. Ramaswamy (Northeastern University), B. Shyam (George Washington University), and Q. Jia (Northeastern University)
16:00 Discussion (30 Minutes)