Lithium-air batteries are viewed by many as a potential next-generation technology in energy storage. With the highest theoretical energy density of all battery devices, Li-air could revolutionize everything from electric vehicles to large-scale grid storage. However, the relatively young technology has a few barriers to overcome before it can be applied. A new study published in the Journal of The Electrochemical Society (JES) is taking a fundamental step forward in advancing Li-air through the development of mixed metal catalyst that could lead to more efficient electrode reactions in the battery.

The paper, entitled “In Situ Formed Layered-Layered Metal Oxide as Bifunctional Catalyst for Li-Air Batteries,” details a cathode catalyst composed of three transition metals (manganese, nickel, and cobalt), which can create the right oxidation state during the battery cycling to enable both the catalysis of the charge and the discharge reaction.

Future opportunities

According to K.M. Abraham, co-author of the paper, the manganese allows for the catalysis of the oxygen reduction reaction while the cobalt catalyzes the charge reaction of the battery.

“This offers opportunities for future research to develop similar materials to optimize the catalysis of the Li-air battery using one material that will combine the functions of these mixed metal oxides,” Abraham says.

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In late 2015, a team of Cambridge University researchers led by ECS member Clare Grey, detailed research in the journal Science on the path to the “ultimate” battery. According to the study, the researchers stated they had successfully demonstrated how to overcome many of the problems preventing the theoretically promising lithium-air battery from being commercially viable.

The key component to this research relies on a highly porous, “fluffy” carbon electrode made from graphene. The researchers cautioned that although the preliminary results were very promising, much work was yet to be done to take lithium-air batteries from the lab to the marketplace.

However, the research got many scientists in energy science and technology talking. Like all groundbreaking results, there has been much discussion and some controversy over the research published by Grey and her team.

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While you may be unfamiliar with Khalil Amine, he has made an immense impact in your life if you happen to use batteries in any way.

As a researcher with a vision of where the science can be applied in the market, Amine has been monumental in developing and moving some of the biggest breakthroughs in battery technology from the lab to the marketplace.

Amine is currently head of the Technology Development Group in the Battery Technology Department at Argonne National Laboratory. From 1998-2008 he was the most cited scientist in the world in the field of battery technology.

He is the chair of the organizing committee for the 18th International Meeting on Lithium Batteries being held this June in Chicago.

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