Light-Driven Reactions Now More Efficient

The new process uses light to do photochemistry instead of the traditional method of using heat to do chemistry.Image: Emory University

The new process uses light to do photochemistry instead of the traditional method of using heat to do chemistry.
Image: Emory University

Scientists from Emory University are opening yet another door to renewable energy efforts. Their new way of performing light-driven reactions based on plasmon—the motion of free electrons that strongly absorb and scatter light—is said to be much more effective than previous processes.

“We’ve discovered a new and unexpected way to use plasmonic metal that holds potential for use in solar energy conversion,” says Tim Lian, professor of physical chemistry at Emory University and the lead author of the research. “We’ve shown that we can harvest the high energy electrons excited by light in plasmon and then use this energy to do chemistry.”

To get a better understanding of surface plasmonic, just think of how a cathedral’s stained glass windows absorb and shatter light.

Researchers involved in this study believe their plasmonic centered process could apply to efforts in electronics and renewable energy. Using plasmon could potentially make light-driven charge transfer for solar energy conversion much more efficient.

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The laboratory-created chemical garden exhibits battery-like properties that may have helped start life on Earth.Image: JEt Propulsion Laboratory/Caltech

The laboratory-created chemical garden exhibits battery-like properties that may have helped start life on Earth.
Image: Jet Propulsion Laboratory/Caltech

Energy is everywhere. As long as there has been a universe, there has been energy. In fact, some researchers believe that Earth’s very first life forms got a little electrical energy boost from chemical seafloor gardens.

Of course this was only a theory, so scientists at the Jet Propulsion Laboratory have grown their on chemical gardens in-house. The have proven strong enough to power a lightbulb, suggesting that the first cell-like organisms may indeed have used seafloor, chimney-shaped structures to channel electricity.

“These chimneys can act like electrical wires on the seafloor,” said Laurie Barge of NASA’s Jet Propulsion Laboratory. “We’re harnessing energy as the first life on Earth might have.”

These findings help researchers explore more definitive answers to the question of life on earth and how it all started. The idea of the seafloor chemical garden agrees with an already established scientific theory—alkaline vent hypothesis—that leans toward the idea that life started underwater due to warm, alkaline chimneys.

“Life doesn’t want to get electrocuted, but needs just the right amount of electricity,” said Michael Russell of Jet Propulsion Laboratory. “This new experiment confirms what that amount of electricity is – just under a volt.”

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es-2015-008758_0004The cleaning of industrial wastewater is a persistent issue across the globe. If left untreated, these harmful waters could enter open watercourses, dispersing contaminants such as mercury and lead. Not only is this an immediate health risk, but it also threatens the entire ecosystem.

Modern wastewater treatment plants have been able to treat the water, but have not been very environmentally conscious. The typical plant produces CO2 by burning fossil fuels for power and the general decomposition of the materials in the wastewater. Not to mention, these things require a lot of power. About 12 trillion gallons of wastewater gets treated each year in the United States along, consuming an alarmingly high 3 percent of the nation’s energy grid.

Researchers have already produced power from pee and made poop potable; so why not develop a new type of wastewater treatment device that significantly lessens the severity of CO2 emissions and simultaneously captures greenhouse gases?

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The new hybrid sol-gel material provides an electrical energy storage capacity rivaling some batteries.Image: John Toon/Georgia Tech

The new hybrid sol-gel material provides an electrical energy storage capacity rivaling some batteries.
Image: John Toon/Georgia Tech

The future of electric vehicle and defibrillator technologies depend largely on new, innovative energy storage research and improving device power densities. With the high demand for more powerful, efficient energy devices, the researchers from Georgia Tech believe they may have developed what could be the answer to powering large-scale devices.

The team has developed a new capacitor dielectric material. This capacitor—developed from a hybrid silica sol-gel material and self-assembled monolayers of common fatty acid—has the potential to surpass some of today’s conventional batteries in the field of energy and power density.

If the researchers can scale up their current laboratory sample, the new capacitors will be able to provide large amounts of current quickly to large-scale applications.

This from Georgia Tech:

The new material is composed of a silica sol-gel thin film containing polar groups linked to the silicon atoms and a nanoscale self-assembled monolayer of an octylphosphonic acid, which provides insulating properties. The bilayer structure blocks the injection of electrons into the sol-gel material, providing low leakage current, high breakdown strength and high energy extraction efficiency.

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First Hydrogen Fuel Cell Ferry

The high-speed hydrogen fuel cell ferry boat is set to hit the waters of the San Francisco Bay Area.Image: Green Car Reports

The high-speed hydrogen fuel cell ferry boat is set to hit the waters of the San Francisco Bay Area.
Image: Green Car Reports

Diesel burning vehicles in the U.S. alone emit pollutants that lead to 21,000 premature deaths each year and act as one of the largest drivers of climate change. The traditional ferry typically burns around one million liters of diesel fuel each year—producing 570 tons of carbon dioxide. In order to help combat this issue, Sandia National Laboratories and the Red and White Fleet ferry company are joining forces to create the first hydrogen fuel cell ferry boat to hit the waters of the San Francisco Bay Area.

Currently in the early stages of development, the boat is set to be named SF BREEZE—an acronym for “San Francisco Bay Renewable Energy Electric vessel with Zero Emissions.” As far as consumption goes, the researchers believe it will take about 1,000 kilograms (2,204 pounds) of hydrogen per day to power the ship.

ICYMI: Listen to Subhash Singhal, a world-leader in the study of fuel cells, talk about the future of energy and climate change.

To satisfy this demand, the construction of the world’s largest hydrogen fueling station will begin off shore and will have the ability to service both sea and land vehicles.

But this isn’t Siemens first take on zero emission ferries. Earlier this year, the lab developed the technology for the world’s first electrically-powered ferry in Norway. This ship has already hit the water successfully, causing no carbon dioxide emissions.

PS: We’re currently accepting abstracts for the 229th ECS Meeting in San Diego! Submit today!

Japan Turns Golf Courses into Solar Farms

It’s all about repurposing. At least, that looks to be the case for Japan’s energy grid.

Beth Schademann, ECS’s Publications Specialist, recently came across a Business Insider article detailing Japan’s initiative to turn abandoned golf courses into solar power plants.

Japan’s Kyocera Corporation is taking the unused green space and making clean, renewable solar farms. They’re starting off big with a 23 megawatt solar plant that will produce enough energy to power around 8,100 households.

And they’re not stopping there. After their first project goes live in 2017, the company will go full force into their 92 megawatt solar plant project that is expected to power over 30,000 households.

Japan’s abandoned golf courses are prime real estate for solar farms, and there’s no shortage of potential here.

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The development of ultralight, ultrathin solar cells is on the horizon due to a new semiconductor call phosphorene.

A team of researchers from Australian National University have developed an atom-thick layer of black phosphorus crystals through a process that utilizes sticky tape.

“Because phosphorene is so thin and light, it creates possibilities for making lots of interesting devices, such as LEDs or solar cells,” said lead researcher Dr. Yuerui (Larry) Lu.

The fabrication of this phosphorene is similar to that of graphene, bringing the new material to a thickness of just 0.5 nanometers. With phosphorene’s novel properties, doors are opening for a new generation of solar cells and LEDs.

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viswanathan-news-brief-chart_500x429-minLithium-air batteries are—in theory—an extremely attractive alternative for affordable, efficient energy storage for electric vehicles. However, as researchers explore this technology, they are met with many critical challenges. If researchers can overcome these challenges, there is a great likelihood that the lithium-air battery will surpass the energy density of today’s lithium-ion battery.

Researchers from Carnegie Mellon University and the University of California, Berkley feel like they may have part of the answer to this critical challenge, which could propel the practicality of the lithium-air battery. The team, which included researchers from Bryan McCloskey and Venkat Viswanathan‘s laboratories, has found a way to both increase the capacity while preserving the recharge ability of the lithium-air battery by blending different types within the battery’s electrolytes.

“The electrolytes used in batteries are just like Gatorade electrolytes,” says Venkat Viswanathan, assistant professor of mechanical engineering at Carnegie Mellon. “Every electrolyte has a solvent and a salt. So if you take Gatorade, the solvent would be water and the salt would be something like sodium chloride, for instance. However, in a lithium air battery, the solvent is dimethoxyethane and the salt is something like lithium hexafluorophosphate.”

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The Future of Solar Fuels

solar-fuelsThere is currently a strong incentive among the scientific community to research clean, renewable energy sources to address challenges in sustainable global development. Through solar fuels, scientists can convert solar energy to chemical energy stored in chemical fuels such as clean-burning hydrogen.

Solar fuels started to really accelerate in 1972 when Akira Fujishima and Kenichi Honda developed a titanium dioxide-based photoelectrochemical cell to split water to generate hydrogen.

Now, researchers from Eindhoven University of Technology have discovered a new way to improve upon this process through the novel way of processing the material gallium phosphide (GaP).

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FCLabs and manufacturers across the globe are pushing forward in an effort to develop a completely clean hydrogen-powered car. Whether it’s through the plotting of more fueling stations or new vehicle prototypes, many manufactures are hoping to bring this concept into reality soon.

However, there is still one very important aspect missing – the science and technology to produce the best and most efficient hydrogen fuel cell.

In ACS Central Science, two teams have independently reported developments in this field that may be able to get us one step closer to a practical hydrogen-powered car.

ICYMI: Listen to our podcast with Subhash C. Singhal, a world-leader in fuel cell research.

The catalysts currently used to produce the proper chemical reaction for hydrogen and oxygen to create energy is currently too expensive or just demands too much energy to be efficient. For this reason, these two teams – led by Yi Cui at Sanford University, and combining the scientific prowess of James Gerken and Shannon Stahl at the University of Wisconsin, Madison – are seeking a new material that could cause the same reaction at a lower price point and higher efficiency.

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