203rd Meeting - Paris, France
April 27-May 2, 2003
PROGRAM INFORMATION
AC2 - Electron Transfer through Organic and Biological Bridges
Organic and Biological Electrochemistry
Monday, April 28, 2003
Room 242B, Level 2, Le Palais des Congres
Co-Chairs: F. Maran and R.W. Murray
Room 242B, Level 2, Le Palais des Congres
Co-Chairs: J. Jortner and F. Armstrong
| Time | Abs# | Title |
|---|
| 13:40 | 2488 |
From Energetic Control to Thermally Induced Hopping - J. Jortner (Tel Aviv University) |
| 14:15 | 2489 |
Unified Theory of Bridge Mediated Electron Transfer - V. May (Humboldt-University at Berlin) and E. Petrov (National Academy of Sciences of Ukraine) |
| 14:45 | 2490 |
Anomalous Distance Dependence of Electron Transfer across Aib Oligo-Peptide Bridges - S. Antonello, F. Formaggio, A. Moretto, C. Toniolo, F. Maran, and F. Polo (Universita di Padova) |
| 15:15 | 2491 |
Electrochemical Studies of Fc-labeled Peptide Monolayers on Gold - H.-B. Kraatz (University of Saskatchewan) |
| 15:45 | |
Twenty-Minute Intermission |
| 16:05 | 2492 |
Electron Transfer in Active Enzyme Molecules Adsorbed on Electrodes: Studies and Exploits of the Coupling to Proton Transfer and Catalysis - F. Armstrong (Oxford University) |
| 16:40 | 2493 |
Charge Injection Through Rigid Bridges At Molecule-Semiconductor Nanoparticle Interfaces - E. Galoppini, Q. Wei, D. Wang, W. Zhang, P. Piotrowiak, P. Wiewior, and G. Zordan (Rutgers University) |
| 17:10 | 2494 |
Photoinduced Electron and Energy Transfer Processes in Fullerene-Based Donor-Bridge-Acceptor Systems - M. Marcaccio, D. Paolucci, F. Paolucci, S. Roffia (Dipartimento di Chimica "G. Ciamician", Università di Bologna), M. Prato (Universita di Trieste), M. Maggini (Universita di Padova), D.M. Guldi (University of Notre Dame), G. Burley, and R. Taylor (University of Sussex) |
| 17:35 | 2495 |
Electron Transfer Through Organic Tunneling Barriers Between Monolayer Protected Clusters Assembled into Conductive Networks. - R. Donkers and R. Murray (The University of North Carolina) |
Tuesday, April 29, 2003
Co-Chairs: D.D.M. Wayner and J.M. Saveant
| Time | Abs# | Title |
|---|
| 8:20 | 2496 |
Electronic Transport Through Benzene Molecule and DNA Base Pairs - A.A. Farajian, T.M. Briere, R.V. Belosludov, H. Mizuseki, and Y. Kawazoe (Tohoku University) |
| 8:40 | 2497 |
Formation and Characterization of Self-assembled Monolayers of 2’-fluoro-4,4’-di(phenylethynyl)-1-Benzenethiolate on Gold - C.A. Hacker, C.A. Richter, L.J. Richter, J.D. Batteas, R.D. van Zee (National Institute of Standards and Technology), and M. Marquez (Los Alamos National Laboratory) |
| 9:00 | 2498 |
Investigations on the Oxidation and Reduction of Ferrocenthiols - N. Krings, H.-H. Strehblow (Heinrich-Heine Universitat Dusseldorf), B. Zeysing, and A. Terfort (Universitat Hamburg) |
| 9:20 | 2499 |
Study of Electron Transfer Kinetics on Self-Assembled Monolayers of Alkanethiols in Non-Aqueous Solvents - U.K. Sur (Raman Research Institute) and V. Lakshminarayanan (Raman Reseach Institute) |
| 9:40 | |
Twenty-Minute Intermission |
| 10:00 | 2500 |
Electron Transfer Through Self-assembled Alkyl Monolayers on Si(111) - D.D.M. Wayner, B. Fabre, D. Colman, and R. Voicu (National Research Council of Canada) |
| 10:35 | 2501 |
Electron Beam Induced Modification of Organic Monolayers on Si(111) - E. Balaur, T. Djenizian (University of Erlangen-Nuremberg), R. Boukherroub (Ecole Polytechnique), and P. Schmuki (University of Erlangen-Nuremberg) |
| 10:55 | 2502 |
Electrochemistry Within Molecules using Ultrafast Cyclic Voltammetry - C. Amatore, Y. Bouret, and E. Maisonhaute (Ecole Normale Superieure) |
| 11:20 | 2503 |
Electronic Communication Through Tetrazole-Based Bridging Ligands in Bimetallic Ruthenium Systems - A.J. Bard (The University of Texas at Austin), C. Bruno (Universita di Bologna), M. Carano (The University of Texas at Austin), M. Marcaccio, A. Palazzi, D. Paolucci, F. Paolucci, S. Roffia, and S. Stagni (Universita di Bologna) |
| 11:40 | 2504 |
Electronic Interactions in Copper(I)- and Silver(I)-Complexes between the Ligands and Metals as Evidenced with Cyclic Voltammetry - M. Leschke, H. Lang, and R. Holze (Technische Universitat Chemnitz) |
Co-Chairs: D.H. Evans and B. Speiser
| Time | Abs# | Title |
|---|
| 13:50 | 2505 |
Do Standard Potential Differences Measure the 'Communication' Between Identical Redox Centers Separated by a Conjugated Chain? Application to Carotenoids - V. Konovalov (University of Alabama at Birmingham), P. Hapiot (Universite de Paris 7 - Denis Diderot), L. Kispert (University of Alabama), and J.-M. Saveant (Universite de Paris 7 - Denis Diderot) |
| 14:25 | 2506 |
Mutual Interaction of Two Redox Active Centres in a Single Molecule- An Electrochemical Approach - J. Ludvik (Academy of Sciences of the Czech Republic) |
| 14:50 | 2507 |
Chemical Communication Induced by Intermolecular Electron Transfer in Heterobimetallic Ferrocenyl-Indenyl-Cr(CO)_3 Complexes - S. Santi, A. Ceccon, A. Bisello (Universita Di Padova), L. Crociani (CNR), and C. Durante (Universita Di Padova) |
| 15:15 | 2508 |
Two-Electron Stepwise Redox Processes in the Boron Subhalide Cluster Series - B. Speiser, T. Wizemann, and M. Wuerde (Institut fuer Organische Chemie) |
| 15:40 | |
Twenty-Minute Intermission |
| 16:00 | 2509 |
Intrinsic Electron Transfer Reactions - S. Nelsen (University of Wisconsin) |
| 16:30 | 2510 |
Driving-Force Dependence of Intramolecular Dissociative Electron Transfers - S. Antonello (Universita di Padova), F. Taddei (Universitadi Modena e Reggio Emilia), and F. Maran (Universita di Padova) |
| 16:55 | 2511 |
Homolytic Cleavage of Radicals and Ion-Radicals as Intramolecular Dissociative Electron Transfer - C. Costentin, M. Robert, and J.-M. Saveant (Universite de Paris 7 - Denis Diderot) |
| 17:20 | 2512 |
Sorting Out the Effects of Electron-Transfer Distance, the Electrical Double Layer and the Inner Reorganization Energy in Heterogeneous Electron-Transfer Reactions of Organic Compounds - D. Evans (University of Delaware) |
Hall Maillot, Level 2, Le Palais des Congres
Technical Exhibit and Tuesday Evening Poster Session
Co-Chairs: D.H. Evans and F. Maran
| Time | Abs# | Title |
|---|
| o | 2513 |
Evidence for a 'Hydrophobic Shield ' between the Alkanethiol SAM and Aqueous Electrolyte - U.K. Sur and V. Lakshminarayanan (Raman Research Institute) |
| o | 2514 |
Electrode Surface Structures for Studying Long-range Electron Transfer in Biological Systems - N. Barlow, K. Hoke (Oxford University), C. Moser, L. Dutton (University of Pennsylvania), and F. Armstrong (Oxford University) |
| o | 2515 |
Modulation of Heterogeneous Electron Transfer Dynamics: Osmium Bis-Bipyridyl Triazole Monolayers - D. Walsh, T. Keyes, and R. Forster (Dublin City University) |
| o | 2516 |
Electron Transfers and Bond Weakening in Excited and Ground States Based on Bent Metallocenes - G. Loukova and E. Karabanchuk (Russian Academy of Sciences) |
| o | 2517 |
Novel Experimental Approach to Probing Frontier Orbitals and HOMO-LUMO Gap in Pi-organometallics - G. Loukova and E. Karabanchuk (Russian Academy of Sciences) |
| o | 2518 |
Biomimetic Electrochemical Synthesis of Quinol-Thioether Conjugates: Their Implication in the Serotonergic Neurotoxicity of Amphetamine - A. Neudorffer, J.-P. Gramond, C. Slim, M.-B. Fleury, and M. Largeron (Universite Rene Descartes) |
| o | 2519 |
The Regularities of Dissociation of Weak Dibasic Organic Acids with the Close Ka' and Ka" Values - E. Kvaratskhelia and R. Kvaratskhelia (Georgian Academy of Sciences) |
| o | 2520 |
Electrochemical Studies of DL-Leucine, L-Proline, and L-Tryptophan and their Interaction with Copper and Iron - M.A. Jabbar, R.J. Mannan, S. Salauddin, and B. Rashid (University of Dhaka) |
| o | 2521 |
Electrochemical Features of Prussian Blue/Conducting Polymer Bilayer Films - S. Lupu (Ecole Normale Superieure) |
| o | 2522 |
Thin Liquid Films Voltammetry For The Thermodynamics Of Interfacial Ions Transfer - M.Y. Vagin (M.V. Lomonosov Moscow State University), S.Z. Ozkan, G.P. Karpachova (Russian Academy of Science), and A.A. Karyakin (M.V. Lomonosov Moscow State University) |
| o | 2523 |
Selective Reduction and Sonoassisted Electrodimerization of Substituted Benzothiophenes - M. Rejnak, J. Klima (Academy of Sciences of the Czech Republic), J. Svoboda (Department of Organic Chemistry, , Prague Institute of Chemical Technology,), and J. Ludvik (Academy of Sciences of the Czech Republic) |
| o | 2524 |
Composite Solid Electrolytes Materials for the Measurement of Bioelectric Signals - P. Romagnoli, M.L. Di Vona, E. Traversa, L. Narici (Universita di Roma “Tor Vergata”), W.G. Sannita (Universita’ di Genova), and S. Licoccia (Universita di Roma “Tor Vergata”) |
| o | 2525 |
Mechanism of the Palladium-Catalyzed Electrocarbonylation of Ethanol to Diethylcarbonate - C. Amatore, S. Bensalem, A. Jutand (Ecole Normale Superieure), and G. Silvestri (Universita di Palermo) |
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