204th Meeting of The Electrochemical Society, Co-sponsored in Part by the Electronics Division of The American Ceramic Society
October 12-October 16, 2003
PROGRAM INFORMATION
AA2 - Electrochemistry Symposium in Honor of Michael Weaver
Physical Electrochemistry/Organic and Biological Electrochemistry
Monday, October 13, 2003
Great Hall West, Ground Level
Electroanalytical Chemistry
Co-Chairs: C. Koval and R. Corn
| Time | Abs# | Title |
|---|
| 2:00 | |
Introductory Remarks |
| 2:05 | 1395 |
Uses of Ionic Liquids in Electrochemical Processes - C. Koval, D. Camper, J. Kieft, R. Noble, M. Norman (University of Colorado at Boulder), and P. Scovazzo (University of Mississippi) |
| 2:30 | 1396 |
Insights into Sorption at Carbon-Based Materials Using Electrochemically Modulated Liquid Chromatography - D.W. Keller, L.M. Ponton, and M.D. Porter (Iowa State University) |
| 2:55 | 1397 |
Single Molecule Spectroscopy of Conjugated Polymer - P. Barbara, R. Lammi, and Z. Yu (University of Texas at Austin) |
| 3:20 | 1398 |
Studies of the Oxidation of a Hydroxychromium(III)[hydrotrispyrazoylborate]pyarazole Complex - C. Van Kirk, K. Qin, K. Theopold, and D. Evans (University of Delaware) |
| 3:45 | |
Twenty-Five Minute Intermission |
| 4:10 | 1399 |
Determination of the Basic Time Scale in Kinetic Monte Carlo Simulations by Comparison with CV Experiments - P.A. Rikvold, I. Abou Hamad, and G. Brown (Florida State University) |
| 4:35 | 1400 |
Simulation of Electrochemically Activated Confined Chemical Patterning of Surfaces Using an Array of Microband Electrodes - R. Egeland (University of Oxford), F. Marken (Loughborough University), J. Elder, E. Southern, and S. Feldberg (University of Oxford) |
| 5:00 | 1401 |
The Reversible Hydrogen Electrode: Potential-Dependent Activation Energies over Platinum from Quantum Theory - A. Anderson and Y. Cai (Case Western Reserve University) |
| 5:25 | 1402 |
Determining the Surface Structure of Nanomaterials - M. Van Hove (Lawrence Berkeley National Laboratory) |
Tuesday, October 14, 2003
Senate Room, Lobby Level
Adsorption
Co-Chairs: D. Scherson and J. Stickney
| Time | Abs# | Title |
|---|
| 8:00 | 1403 |
Chiral Monolayer Adsorption: Two-Dimensional Chiral Crystals - S.L. Bernasek and Y. Cai (Princeton University) |
| 8:25 | 1404 |
Interfacial Structures of Self-Assembled Monolayers of 2-Amino-6-purinethiol on Au(111) - T. Sawaguchi, Y. Sato, and F. Mizutani (National Institute of Advanced Industrial Science and Technology) |
| 8:50 | 1405 |
Electrochemical Behavior of Pt(100) Vicinal Surfaces in Bromide Solutions. - N. Garcia-Araez, E. Herrero, and J.M. Feliu (Universidad de Alicante) |
| 9:15 | 1406 |
Adlayers of S and SCN on Cu(111) in KOH Solution - J. Inukai and K. Itaya (Tohoku University) |
| 9:40 | |
Fifteen-Minute Intermission |
| 9:55 | 1407 |
Studies of the Deposition of the First Few Monolayers of CdTe and CdSe on Au(111), via Electrochemical Atomic Layer Epitaxy (EC-ALE) - J. Stickney, M. Lay, and N. Srisook (The University of Georgia) |
| 10:20 | 1408 |
Preparation of Metallic Platinum by Displacment of Copper on Aryl Modified Glassy Carbon Electrodes. - M. Van Brussel (Universite Libre de Bruxelles), M. D'Amours, J. Marwan (UQAM), C. Buess-Herman (Universite Libre de Bruxelles), and D. Belanger (UQAM) |
| 10:45 | 1409 |
Al Underpotential Deposition from AlCl3 Based Melts on Electrodes of Known Composition in UHV - M. Johnston (Case Western Reserve University), K. Wheeler (Delaware State University), G. Chottiner, and D. Scherson (Case Western Reserve University) |
| 11:10 | 1410 |
Electrochemistry, Spectrophotometry, and NMR Investigations of Chemisorption of Polyoxometalate on Silver Nanoparticle Surfaces - G.C. Lica, B.S. Zelakiewicz, L.B. Smeeding, and Y. Tong (Georgetown University) |
| 11:35 | 1411 |
Nanoscale Dynamics of Molecular Self Assembly at Electrochemical Interfaces - E. Borguet, T. Ye, and Y. He (University of Pittsburgh) |
Scotland C, Ground Level
Catalysis I
Co-Chairs: R. Adzic and P. Ross
| Time | Abs# | Title |
|---|
| 2:00 | 1412 |
Oxidation of the Ag Single Crystal Electrodes in Alkaline Electrolytes: from Hydroxide Adsorption to the Oxide Formation - S. Horswell, M. Danckwerts, B. Pettinger, E. Savinova, and K. Doblhofer (Fritz-Haber-Institut der Max-Planck-Gesellschaft) |
| 2:25 | 1413 |
Study of Growth and Properties of Thin Anodic Oxide Films on Platinum - A. Sun and D. Macdonald (Penn State University) |
| 2:50 | 1414 |
Electrochemical and 195Pt NMR Studies of the Effects of Heat-Treatment on Pt-Ru Alloy Nanoparticles - H.S. Kim, P.K. Babu, E. Oldfield, and A. Wieckowski (University of Illinois at Urbana-Champaign) |
| 3:15 | 1415 |
Surface Properties of Bimetallic Alloys: CO Oxidation on Pt-Sn and Pt-Mo Surfaces - V. Stamenkovic, M. Arenz, P. Ross, and N. Markovic (Lawrence Berkeley National Laboratory) |
| 3:40 | |
Fifteen-Minute Intermission |
| 3:55 | 1416 |
DFT Study of the Water Activation and CO Oxidation on Nanoparticle Catalysts for Fuel Cell Applications - Y. Ishikawa and C. Cabrera (University of Puerto Rico) |
| 4:20 | 1417 |
The Effects of Solvation and Potential on the Reactivity of Model Pt and PtRu Surfaces - M. Neurock, J.-S. Filhol, and S. Desai (University of Virginia) |
| 4:45 | 1418 |
Effect of the Step Density on the Oxygen Reduction Reaction on Platinum Single Crystals - M.D. Macia, J.M. Campina, E. Herrero, and J.M. Feliu (Universidad de Alicante) |
| 5:10 | 1419 |
In situ Infrared Reflectance Spectroscopic Study of the Intermediate Species involved in the Electrocatalytic Oxidation of Alcohols on Platinum-based Dispersed Electrodes - C. Lamy, S. Rousseau, F. Vigier, L. Dubau, F. Hahn, and J.-M. Leger (University of Poitiers) |
| 5:35 | 1420 |
Could Anion Coadsorb with CO On Pt(111)- Reconcialiation of SXS, STM, IR, and Theoretical Studies - J. Wang and R. Adzic (Brookhaven National Loaboratory) |
Wednesday, October 15, 2003
Nanostructures
Co-Chairs: D. Buttry and A.R. Hillman
| Time | Abs# | Title |
|---|
| 10:00 | 1421 |
Carl Wagner Memorial Award Address: Analytical Applications of Single-Pore Membranes Based on Carbon Nanotubes - R. Crooks, T. Ito, and L. Sun (Texas A and M University) |
| 10:30 | 1422 |
Rates of Chemical Reactions in Monolayers - R. Martoglio and D. Buttry (University of Wyoming) |
| 10:55 | 1423 |
Nanoparticle- Metallopolymer Composites: Electrochemical and Photonic Applications - R. Forster and L. Keane (Dublin City University) |
| 11:20 | 1424 |
Reactivity of Single Supported Palladium Nano-Particles - M. Eikerling (Simon Fraser University), J. Meier, A.K. Pal, and U. Stimming (Technische Universität München) |
| 11:45 | 1425 |
Spatial Distributions of Solvent and Salt in Polyvinylferrocene Films - A.R. Hillman, L. Bailey, A. Jackson (University of Leicester), A. Glidle, J. Cooper (Glasgow University), J. Webster (Rutherford Appleton Laboratory), and R. Cubitt (Institut Laue Langevin) |
Catalysis II
Co-Chairs: C. Korzeniewski and A. Gewirth
| Time | Abs# | Title |
|---|
| 2:00 | 1426 |
Mechanism of Peroxide Reduction On Metal Monolayer Modified Electrode Surfaces - X. Li and A. Gewirth (University of Illinois) |
| 2:25 | 1427 |
The Electrochemical Reduction of Nitrite and Nitrate Ions followed by Mass Spectrometry and in situ IR spectroscopy - F. Nart (Univeristy of Sao Paulo) and F. Cunha (University of Sao Paulo) |
| 2:50 | 1428 |
Methanol Oxidation Reaction: Strong Anion Effects on the Yields of Soluble Products - E. Batista, G. Malpass, A. Motheo, and T. Iwasita (University of Sao Paulo) |
| 3:15 | 1429 |
Quantitative Approaches in the Study of Methanol Electrochemical Oxidation at Bulk and Nanometer-Scale Metals - C. Korzeniewski (Texas Tech University) |
| 3:40 | |
Fifteen-Minute Intermission |
| 3:55 | 1430 |
Facilitation of CO Oxidation on Pt – Impact of Magnetic Fields - W.L. Gellett, J. Leddy (University of Iowa), S.D. Minteer, and K. Bahram-ahi (St. Louis University) |
| 4:20 | 1431 |
Electrooxidation of Formaldehyde on Platinum Electrodes Studied by Surface-Enhanced Infrared Spectroscopy - A. Miki, S. Ye, and M. Osawa (Hokkaido University) |
| 4:45 | 1432 |
Properties and Reactivities of Nanostructured Pt-Sn Alloys and SnOx Films on Pt - B.E. Koel (University of Southern California) |
| 5:10 | 1433 |
Structure, Dynamics and Cooperativity for Ions in Water in Various Environments - D. Salahub (University of Calgary) |
| 5:35 | 1434 |
DoubleLayer of the Au(111) Electrodes Modified by Self-assembled Monolayer of Thiol with Carboxy Terminal Group: 3-D Poisson Boltzmann Model and Monte Carlo Simulation - M. Yamamoto, T. Soda, H. Toyoda, D. Hobara, and T. Kakiuchi (Kyoto University) |
Thursday, October 16, 2003
Electron Transfer and Spectroscopy
Co-Chairs: S. Wasileski and A. Wieckowski
| Time | Abs# | Title |
|---|
| 8:00 | 1435 |
Coupled Electron-Transfer and Spin-Exchange Reactions. Insight from Electrochemical Activation Parameters - F.A. Schultz (Indiana University, Purdue University) |
| 8:25 | 1436 |
Long-range Electron Transfer; Insights from Studies on Redox-active Self-assembled Monolayers - S. Creager, J. Atkins, and E. Hughes (Clemson University) |
| 8:50 | 1437 |
Intramolecular Associative and Dissociative Electron-Transfer Reactions of Rhodium Complexes - W. Geiger, N. Camire-Ohrenberg, B. Yeomans (University of Vermont), and N. Connelly (University of Bristol) |
| 9:15 | 1438 |
On the Theory of the Dissociation of Aromatic Radical Anions in Solution: a Ground Electronic State Conical Intersection Problem - D. Laage, I. Burghardt (Ecole Normale Superieure), T. Sommerfeld (Universitat Heidelberg), and J. Hynes (Ecole Normale Superieure) |
| 9:40 | |
Fifteen-Minute Intermission |
| 9:55 | 1439 |
Mechanism of Charge Transfer at Film-modified Electrodes - M. Newton (Brookhaven National Laboratory) |
| 10:20 | 1440 |
Electrochemistry of Mineral Surfaces and Chemical Evolution in the Pre-Biotic Era - M.R. Philpott, I.Y. Goliney (National University of Singapore), R. Jaffe (NASA), and T.T. Lin (Institute of Materials Research and Engineering) |
| 10:45 | 1441 |
Synchrotron X-ray Studies of Electrode Surfaces: Techniques and Recent Results - H. You, A. Menzel, Y. Tolmachev, Z. Nagy (Argonne National Laboratory), and A. Wieckowski (University of Illinois) |
| 11:10 | 1442 |
Vibrational Behavior of Molecules Chemisorbed at Electrochemical Interfaces from Density Functional Theory Calculations - S. Wasileski and M. Weaver (Purdue Universtiy) |
| 11:35 | 1443 |
Electrical Properties and Chemical Stability of Alkylated Crystalline Silicon(111) Surfaces - L. Webb, E. Nemanick, and N. Lewis (California Institute of Technology) |
Interfaces
Co-Chairs: J.T. Hupp and C. Takoudis
| Time | Abs# | Title |
|---|
| 2:00 | 1444 |
Interface Properties of Ultra-Thin Dielectric Films on Silicon Substrates: In Situ and Real-Time? - C. Takoudis (University of Illinois at Chicago) |
| 2:25 | 1445 |
The PZC of Physical vs. Chemical Mixtures of Oxides - L.A. De Faria (Federal University of Uberlandia) and S. Trasatti (University of Milan) |
| 2:50 | 1446 |
Simulating the Electrode-Electrolyte Interface - J.W. Halley (University of Minnesota) |
| 3:15 | 1447 |
Fundamental Aspects of Wet Electrochemical Emersion - J.E. Pemberton and A. Mudalige (University of Arizona) |
| 3:40 | |
Twenty-Five Minute Intermission |
| 4:05 | 1448 |
IR Spectroscopy Helps to Understand the Results of SERS - M. Lust, M. Sinther, A. Pucci (Universitat Heidelberg), F. Bartolucci, and A. Otto (Universitat Dusseldorf) |
| 4:30 | 1449 |
Surface NMR of Interest to Electrochemical Science - P. Babu, H. Imai, E. Oldfield, and A. Wieckowski (University of Illinois at Urbana-Champaign) |
| 4:55 | 1450 |
Interfacial Molecular Structure at Solid/Liquid Interfaces by Sum Frequency Generation (SFG) Spectroscopy - K. Uosaki, S. Nihonyanagi, R. Yamamoto, and T. Yano (Hokkaido University) |
| 5:20 | 1451 |
Modeling and Measuring Molecular Transport Through Nanoporous Materials - A. Massari and J. Hupp (Northwestern University) |
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