204th Meeting of The Electrochemical Society, Co-sponsored in Part by the Electronics Division of The American Ceramic Society

October 12-October 16, 2003


AA2 - Electrochemistry Symposium in Honor of Michael Weaver

Physical Electrochemistry/Organic and Biological Electrochemistry

Monday, October 13, 2003

Great Hall West, Ground Level

Electroanalytical Chemistry

Co-Chairs: C. Koval and R. Corn

2:00 Introductory Remarks
2:051395 Uses of Ionic Liquids in Electrochemical Processes - C. Koval, D. Camper, J. Kieft, R. Noble, M. Norman (University of Colorado at Boulder), and P. Scovazzo (University of Mississippi)
2:301396 Insights into Sorption at Carbon-Based Materials Using Electrochemically Modulated Liquid Chromatography - D.W. Keller, L.M. Ponton, and M.D. Porter (Iowa State University)
2:551397 Single Molecule Spectroscopy of Conjugated Polymer - P. Barbara, R. Lammi, and Z. Yu (University of Texas at Austin)
3:201398 Studies of the Oxidation of a Hydroxychromium(III)[hydrotrispyrazoylborate]pyarazole Complex - C. Van Kirk, K. Qin, K. Theopold, and D. Evans (University of Delaware)
3:45 Twenty-Five Minute Intermission
4:101399 Determination of the Basic Time Scale in Kinetic Monte Carlo Simulations by Comparison with CV Experiments - P.A. Rikvold, I. Abou Hamad, and G. Brown (Florida State University)
4:351400 Simulation of Electrochemically Activated Confined Chemical Patterning of Surfaces Using an Array of Microband Electrodes - R. Egeland (University of Oxford), F. Marken (Loughborough University), J. Elder, E. Southern, and S. Feldberg (University of Oxford)
5:001401 The Reversible Hydrogen Electrode: Potential-Dependent Activation Energies over Platinum from Quantum Theory - A. Anderson and Y. Cai (Case Western Reserve University)
5:251402 Determining the Surface Structure of Nanomaterials - M. Van Hove (Lawrence Berkeley National Laboratory)

Tuesday, October 14, 2003

Senate Room, Lobby Level


Co-Chairs: D. Scherson and J. Stickney

8:001403 Chiral Monolayer Adsorption: Two-Dimensional Chiral Crystals - S.L. Bernasek and Y. Cai (Princeton University)
8:251404 Interfacial Structures of Self-Assembled Monolayers of 2-Amino-6-purinethiol on Au(111) - T. Sawaguchi, Y. Sato, and F. Mizutani (National Institute of Advanced Industrial Science and Technology)
8:501405 Electrochemical Behavior of Pt(100) Vicinal Surfaces in Bromide Solutions. - N. Garcia-Araez, E. Herrero, and J.M. Feliu (Universidad de Alicante)
9:151406 Adlayers of S and SCN on Cu(111) in KOH Solution - J. Inukai and K. Itaya (Tohoku University)
9:40 Fifteen-Minute Intermission
9:551407 Studies of the Deposition of the First Few Monolayers of CdTe and CdSe on Au(111), via Electrochemical Atomic Layer Epitaxy (EC-ALE) - J. Stickney, M. Lay, and N. Srisook (The University of Georgia)
10:201408 Preparation of Metallic Platinum by Displacment of Copper on Aryl Modified Glassy Carbon Electrodes. - M. Van Brussel (Universite Libre de Bruxelles), M. D'Amours, J. Marwan (UQAM), C. Buess-Herman (Universite Libre de Bruxelles), and D. Belanger (UQAM)
10:451409 Al Underpotential Deposition from AlCl3 Based Melts on Electrodes of Known Composition in UHV - M. Johnston (Case Western Reserve University), K. Wheeler (Delaware State University), G. Chottiner, and D. Scherson (Case Western Reserve University)
11:101410 Electrochemistry, Spectrophotometry, and NMR Investigations of Chemisorption of Polyoxometalate on Silver Nanoparticle Surfaces - G.C. Lica, B.S. Zelakiewicz, L.B. Smeeding, and Y. Tong (Georgetown University)
11:351411 Nanoscale Dynamics of Molecular Self Assembly at Electrochemical Interfaces - E. Borguet, T. Ye, and Y. He (University of Pittsburgh)

Scotland C, Ground Level

Catalysis I

Co-Chairs: R. Adzic and P. Ross

2:001412 Oxidation of the Ag Single Crystal Electrodes in Alkaline Electrolytes: from Hydroxide Adsorption to the Oxide Formation - S. Horswell, M. Danckwerts, B. Pettinger, E. Savinova, and K. Doblhofer (Fritz-Haber-Institut der Max-Planck-Gesellschaft)
2:251413 Study of Growth and Properties of Thin Anodic Oxide Films on Platinum - A. Sun and D. Macdonald (Penn State University)
2:501414 Electrochemical and 195Pt NMR Studies of the Effects of Heat-Treatment on Pt-Ru Alloy Nanoparticles - H.S. Kim, P.K. Babu, E. Oldfield, and A. Wieckowski (University of Illinois at Urbana-Champaign)
3:151415 Surface Properties of Bimetallic Alloys: CO Oxidation on Pt-Sn and Pt-Mo Surfaces - V. Stamenkovic, M. Arenz, P. Ross, and N. Markovic (Lawrence Berkeley National Laboratory)
3:40 Fifteen-Minute Intermission
3:551416 DFT Study of the Water Activation and CO Oxidation on Nanoparticle Catalysts for Fuel Cell Applications - Y. Ishikawa and C. Cabrera (University of Puerto Rico)
4:201417 The Effects of Solvation and Potential on the Reactivity of Model Pt and PtRu Surfaces - M. Neurock, J.-S. Filhol, and S. Desai (University of Virginia)
4:451418 Effect of the Step Density on the Oxygen Reduction Reaction on Platinum Single Crystals - M.D. Macia, J.M. Campina, E. Herrero, and J.M. Feliu (Universidad de Alicante)
5:101419 In situ Infrared Reflectance Spectroscopic Study of the Intermediate Species involved in the Electrocatalytic Oxidation of Alcohols on Platinum-based Dispersed Electrodes - C. Lamy, S. Rousseau, F. Vigier, L. Dubau, F. Hahn, and J.-M. Leger (University of Poitiers)
5:351420 Could Anion Coadsorb with CO On Pt(111)- Reconcialiation of SXS, STM, IR, and Theoretical Studies - J. Wang and R. Adzic (Brookhaven National Loaboratory)

Wednesday, October 15, 2003


Co-Chairs: D. Buttry and A.R. Hillman

10:001421 Carl Wagner Memorial Award Address: Analytical Applications of Single-Pore Membranes Based on Carbon Nanotubes - R. Crooks, T. Ito, and L. Sun (Texas A and M University)
10:301422 Rates of Chemical Reactions in Monolayers - R. Martoglio and D. Buttry (University of Wyoming)
10:551423 Nanoparticle- Metallopolymer Composites: Electrochemical and Photonic Applications - R. Forster and L. Keane (Dublin City University)
11:201424 Reactivity of Single Supported Palladium Nano-Particles - M. Eikerling (Simon Fraser University), J. Meier, A.K. Pal, and U. Stimming (Technische Universität München)
11:451425 Spatial Distributions of Solvent and Salt in Polyvinylferrocene Films - A.R. Hillman, L. Bailey, A. Jackson (University of Leicester), A. Glidle, J. Cooper (Glasgow University), J. Webster (Rutherford Appleton Laboratory), and R. Cubitt (Institut Laue Langevin)

Catalysis II

Co-Chairs: C. Korzeniewski and A. Gewirth

2:001426 Mechanism of Peroxide Reduction On Metal Monolayer Modified Electrode Surfaces - X. Li and A. Gewirth (University of Illinois)
2:251427 The Electrochemical Reduction of Nitrite and Nitrate Ions followed by Mass Spectrometry and in situ IR spectroscopy - F. Nart (Univeristy of Sao Paulo) and F. Cunha (University of Sao Paulo)
2:501428 Methanol Oxidation Reaction: Strong Anion Effects on the Yields of Soluble Products - E. Batista, G. Malpass, A. Motheo, and T. Iwasita (University of Sao Paulo)
3:151429 Quantitative Approaches in the Study of Methanol Electrochemical Oxidation at Bulk and Nanometer-Scale Metals - C. Korzeniewski (Texas Tech University)
3:40 Fifteen-Minute Intermission
3:551430 Facilitation of CO Oxidation on Pt – Impact of Magnetic Fields - W.L. Gellett, J. Leddy (University of Iowa), S.D. Minteer, and K. Bahram-ahi (St. Louis University)
4:201431 Electrooxidation of Formaldehyde on Platinum Electrodes Studied by Surface-Enhanced Infrared Spectroscopy - A. Miki, S. Ye, and M. Osawa (Hokkaido University)
4:451432 Properties and Reactivities of Nanostructured Pt-Sn Alloys and SnOx Films on Pt - B.E. Koel (University of Southern California)
5:101433 Structure, Dynamics and Cooperativity for Ions in Water in Various Environments - D. Salahub (University of Calgary)
5:351434 DoubleLayer of the Au(111) Electrodes Modified by Self-assembled Monolayer of Thiol with Carboxy Terminal Group: 3-D Poisson Boltzmann Model and Monte Carlo Simulation - M. Yamamoto, T. Soda, H. Toyoda, D. Hobara, and T. Kakiuchi (Kyoto University)

Thursday, October 16, 2003

Electron Transfer and Spectroscopy

Co-Chairs: S. Wasileski and A. Wieckowski

8:001435 Coupled Electron-Transfer and Spin-Exchange Reactions. Insight from Electrochemical Activation Parameters - F.A. Schultz (Indiana University, Purdue University)
8:251436 Long-range Electron Transfer; Insights from Studies on Redox-active Self-assembled Monolayers - S. Creager, J. Atkins, and E. Hughes (Clemson University)
8:501437 Intramolecular Associative and Dissociative Electron-Transfer Reactions of Rhodium Complexes - W. Geiger, N. Camire-Ohrenberg, B. Yeomans (University of Vermont), and N. Connelly (University of Bristol)
9:151438 On the Theory of the Dissociation of Aromatic Radical Anions in Solution: a Ground Electronic State Conical Intersection Problem - D. Laage, I. Burghardt (Ecole Normale Superieure), T. Sommerfeld (Universitat Heidelberg), and J. Hynes (Ecole Normale Superieure)
9:40 Fifteen-Minute Intermission
9:551439 Mechanism of Charge Transfer at Film-modified Electrodes - M. Newton (Brookhaven National Laboratory)
10:201440 Electrochemistry of Mineral Surfaces and Chemical Evolution in the Pre-Biotic Era - M.R. Philpott, I.Y. Goliney (National University of Singapore), R. Jaffe (NASA), and T.T. Lin (Institute of Materials Research and Engineering)
10:451441 Synchrotron X-ray Studies of Electrode Surfaces: Techniques and Recent Results - H. You, A. Menzel, Y. Tolmachev, Z. Nagy (Argonne National Laboratory), and A. Wieckowski (University of Illinois)
11:101442 Vibrational Behavior of Molecules Chemisorbed at Electrochemical Interfaces from Density Functional Theory Calculations - S. Wasileski and M. Weaver (Purdue Universtiy)
11:351443 Electrical Properties and Chemical Stability of Alkylated Crystalline Silicon(111) Surfaces - L. Webb, E. Nemanick, and N. Lewis (California Institute of Technology)


Co-Chairs: J.T. Hupp and C. Takoudis

2:001444 Interface Properties of Ultra-Thin Dielectric Films on Silicon Substrates: In Situ and Real-Time? - C. Takoudis (University of Illinois at Chicago)
2:251445 The PZC of Physical vs. Chemical Mixtures of Oxides - L.A. De Faria (Federal University of Uberlandia) and S. Trasatti (University of Milan)
2:501446 Simulating the Electrode-Electrolyte Interface - J.W. Halley (University of Minnesota)
3:151447 Fundamental Aspects of Wet Electrochemical Emersion - J.E. Pemberton and A. Mudalige (University of Arizona)
3:40 Twenty-Five Minute Intermission
4:051448 IR Spectroscopy Helps to Understand the Results of SERS - M. Lust, M. Sinther, A. Pucci (Universitat Heidelberg), F. Bartolucci, and A. Otto (Universitat Dusseldorf)
4:301449 Surface NMR of Interest to Electrochemical Science - P. Babu, H. Imai, E. Oldfield, and A. Wieckowski (University of Illinois at Urbana-Champaign)
4:551450 Interfacial Molecular Structure at Solid/Liquid Interfaces by Sum Frequency Generation (SFG) Spectroscopy - K. Uosaki, S. Nihonyanagi, R. Yamamoto, and T. Yano (Hokkaido University)
5:201451 Modeling and Measuring Molecular Transport Through Nanoporous Materials - A. Massari and J. Hupp (Northwestern University)




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