Clean Energy from Water

For most of history, fuel cells existed only as laboratory curiosities. As far back as 1839, the English scientist William Grove had the idea that the reactants of a battery could be gases fed into it from external tanks.

Since their humble beginnings, fuel cells have come a far to prove as a viable alternative to combustion. Currently, researchers at the University of Basel are studying how sunlight could split water into hydrogen and oxygen, creating a fuel cell that could produce clean energy from water.

(MORE: Read “Battery and Fuel Cell Technology.”)

Artificial photosynthesis has proven to be one of the most promising tools in producing clean, renewable resources. This process occurs when water is photo-electrochemically, with the aid of sunlight, separated into its H2 and O2 components.

Of the two reactions that occur, water oxidation typically provides researchers with the most hurdles to overcome. The new research works to develop an efficient, sustainable water oxidation catalyst.

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SOFC

New material could help SOFCs operate more efficiently and cheaply.
Image: Bloom Energy

Solid oxide fuel cells may be producing cleaner energy at a more efficient level soon, thanks to a development at the University of Cambridge.

A new thin-film electrolyte material, developed by a team including ECS member Sergei Kalinin, has the potential to propel portable power sources due to its ability to achieve high performance levels and very low temperatures.

Advancing fuel cells

With a huge scientific focus shift toward developing new energy technologies, fuel cells have emerged as a big contender. Transitioning from a simple laboratory curiosity in the 19th century to a main contender for powering electric vehicles, researchers have dedicated much energy to building an efficient, cost effective fuel cell.

(MORE: Read “Battery and Fuel Cell Technology“)

This from University of Cambridge:

By using thin-film electrolyte layers, micro solid oxide fuel cells offer a concentrated energy source, with potential applications in portable power sources for electronic consumer or medical devices, or those that need uninterruptable power supplies such as those used by the military or in recreational vehicles.

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Electrochemical Impedance Spectroscopy Workshop

On October 26th, 2015, the ECS British Columbia Student Chapter held its 1st Annual Academic Workshop.

The workshop was held at the Molecular Biology and Chemistry Building located at Simon Fraser University in British Columbia, Canada. It attracted nearly 40 attendees from all different departments and disciplines at The University of British Columbia, Simon Fraser University and Tsinghua University, China. Also in attendance was the Chair of ECS Canada Section, Dr. Michael Eickerling.

The attendees were given a detailed presentation from Dr. Andrei Kulikovsky on the topic of Physical Models of Impedance Spectroscopy for PEM fuel cells. Dr. Kulikovsky visited all the way from Germany for the workshop, where he is involved in modeling fuel cell components and stacks. Within the past fifteen years, Dr. Kulikovsky has published more than seventy research papers.

In 2012, he published a one-of-a-kind book called Analytical Modeling of Fuel Cells. This book is the first monograph on modeling of polymer electrolyte, direct methanol and solid oxide fuel cells performance. Dr. Kulikovsky’s current research interests include modeling of fuel cells and catalyst layers.

Dr. Andrei Kulikovsky beginning the workshop.

Dr. Andrei Kulikovsky beginning the workshop.

Attendees keenly listening to the talk and taking notes.

Attendees keenly listening to the talk and taking notes.

Congratulations on a successful workshop!

Technology Prospects for Future Mobility

review-paperWith the transportation sectors of industrialized countries on the rise and greenhouse gas emissions at an all-time high, many scientists and engineers are searching for the next-generation of transportation. From hybrid to electric to hydrogen, alternative energy sources for vehicles are being explored and tested throughout the scientific community. Now, many are wondering which technology will win in the race between battery- and hydrogen-powered cars.

A recent open access paper published in the Journal of The Electrochemical Society (JES) explores this topic. Authors Hubert A. Gasteiger, Jens-Peter Suchsland, and Oliver Gröger have outlined the technological barriers for next-generation vehicles in “Review—Electromobility: Batteries or Fuel Cells?” This paper comes as part of the recent JES Collection of Invited Battery Review Papers.

The majority of today’s vehicles depend on petroleum-based products in internal combustion engines to operate. The burning of these fuels results in the emission of greenhouse gasses. The majority of these transportation sector greenhouse gas emissions do not come from large modes of transportation such as aircrafts or ships—but are primarily produced by cars, trucks, and SUVs.

In the recently published review, the authors describe the possibilities of extended range electric vehicles, the challenges in hydrogen fuel cell vehicles, and the potential for new materials to be used in these applications.

Read this open access paper and read the rest of the JES Collection of Invited Battery Review Papers.

Fuel Cell Research Shows Promising Potential

When it comes to alternative energy solutions, many researchers are looking to fuel cells as a promising solution. With high theoretical efficiency levels and their environmentally friendly qualities, fuel cells could be an answer to both the energy crisis and climate issues. However, researchers are still looking at how to build a fuel cell so that it is not only efficient, but also cost effective.


Sadia Kabir, ECS student member and PhD student at the University of New Mexico, recently published a paper in the Journal of The Electrochemical Society detailing her novel work on graphene-supported catalysts for fuel cells. Kabir is moving from theory to proof with her new research, showcasing an efficient and economically viable fuel cell.

The research was compiled by an interdisciplinary team with representatives from the University of New Mexico, University of Portiers, and Franunhofer Institute for Chemical Technology.

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Fuel cells have been receiving a lot of attention in the scientific domain as one of the most promising alternative energy sources. When applying fuel cell technology to both the grid and automobiles, one issue is persistent: cost. Researchers at Argonne National Laboratory (ANNL) have been looking for a way to combat the price issues. Now, a team of researchers led by ECS member Di-Jia Liu have found a potential way to utilize fuel cells without the high cost of development and commercialization.

A New Catalyst

The team’s development revolves around the notion of using naturally abundant materials without sacrificing efficiency. Current, fuel cells work off a platinum catalyst, which is both expensive and scarce. The new catalyst eliminates the need for the precious material, all while demonstrating performance rates comparable to that of a platinum catalyst.

The scientists developed the new catalyst via the synthesis of a highly efficient, nanofibrous non-precious metal catalyst. If this technique proves to be commercially viable, it transition into automotive technology and extend the range of electric vehicles and potentially eliminate the need for charging.

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FCLabs and manufacturers across the globe are pushing forward in an effort to develop a completely clean hydrogen-powered car. Whether it’s through the plotting of more fueling stations or new vehicle prototypes, many manufactures are hoping to bring this concept into reality soon.

However, there is still one very important aspect missing – the science and technology to produce the best and most efficient hydrogen fuel cell.

In ACS Central Science, two teams have independently reported developments in this field that may be able to get us one step closer to a practical hydrogen-powered car.

ICYMI: Listen to our podcast with Subhash C. Singhal, a world-leader in fuel cell research.

The catalysts currently used to produce the proper chemical reaction for hydrogen and oxygen to create energy is currently too expensive or just demands too much energy to be efficient. For this reason, these two teams – led by Yi Cui at Sanford University, and combining the scientific prowess of James Gerken and Shannon Stahl at the University of Wisconsin, Madison – are seeking a new material that could cause the same reaction at a lower price point and higher efficiency.

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Printable Functional Materials

Potential technical applications of printable functional inks.

The videos and information in this post relate to an ECS Journal of Solid State Science and Technology focus issue called: Printable Functional Materials for Electronics and Energy Applications.

(Read/download the focus issue now. It’s entirely free.)

Printing technologies in an atmospheric environment offer the potential for low-cost and materials-efficient alternatives for manufacturing electronics and energy devices such as luminescent displays, thin-film transistors, sensors, thin-film photovoltaics, fuel cells, capacitors, and batteries. Significant progress has been made in the area of printable functional organic and inorganic materials including conductors, semiconductors, and dielectric and luminescent materials.

These new printable functional materials have and will continue to enable exciting advances in printed electronics and energy devices. Some examples are printed amorphous oxide semiconductors, organic conductors and semiconductors, inorganic semiconductor nanomaterials, silicon, chalcogenide semiconductors, ceramics, metals, intercalation compounds, and carbon-based materials.

A special focus issue of the ECS Journal of Solid State Science and Technology was created about the publication of state-of-the-art efforts that address a variety of approaches to printable functional materials and device. This focus issue, consisting of a total of 15 papers, includes both invited and contributed papers reflecting recent achievements in printable functional materials and devices.

The topics of these papers span several key ECS technical areas, including batteries, sensors, fuel cells, carbon nanostructures and devices, electronic and photonic devices, and display materials, devices, and processing. The overall collection of this focus issue covers an impressive scope from fundamental science and engineering of printing process, ink chemistry and ink conversion processes, printed devices, and characterizations to the future outlook for printable functional materials and devices.

The video below demonstrates Printed Metal Oxide Thin-Film Transistors by J. Gorecki, K. Eyerly, C.-H. Choi, and C.-H. Chang, School of Chemical, Biological and Environmental Engineering, Oregon State University.

Step-by-step explanation of the video:

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Printable Functional Materials

Potential technical applications of printable functional inks.

The video and information in this post relate to an ECS Journal of Solid State Science and Technology focus issue called: Printable Functional Materials for Electronics and Energy Applications.

(Read/download the focus issue now. It’s entirely free.)

Printing technologies in an atmospheric environment offer the potential for low-cost and materials-efficient alternatives for manufacturing electronics and energy devices such as luminescent displays, thin-film transistors, sensors, thin-film photovoltaics, fuel cells, capacitors, and batteries. Significant progress has been made in the area of printable functional organic and inorganic materials including conductors, semiconductors, and dielectric and luminescent materials.

These new printable functional materials have and will continue to enable exciting advances in printed electronics and energy devices. Some examples are printed amorphous oxide semiconductors, organic conductors and semiconductors, inorganic semiconductor nanomaterials, silicon, chalcogenide semiconductors, ceramics, metals, intercalation compounds, and carbon-based materials.

A special focus issue of the ECS Journal of Solid State Science and Technology was created about the publication of state-of-the-art efforts that address a variety of approaches to printable functional materials and device. This focus issue, consisting of a total of 15 papers, includes both invited and contributed papers reflecting recent achievements in printable functional materials and devices.

The topics of these papers span several key ECS technical areas, including batteries, sensors, fuel cells, carbon nanostructures and devices, electronic and photonic devices, and display materials, devices, and processing. The overall collection of this focus issue covers an impressive scope from fundamental science and engineering of printing process, ink chemistry and ink conversion processes, printed devices, and characterizations to the future outlook for printable functional materials and devices.

The video below show demonstrates Inkjet Printed Conductive Tracks for Printed Electronic conducted by S.-P. Chen, H.-L. Chiu, P.-H. Wang, and Y.-C. Liao, Department of Chemical Engineering, National Taiwan University, No. 1 Sec. 4 Roosevelt Road, Taipei 10617, Taiwan.

Step-by-step explanation of the video:

For printed electronic devices, metal thin film patterns with great conductivities are required. Three major ways to produce inkjet-printed metal tracks will be shown in this video.

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Breaking Dependence on Fossil Fuels

Abruna_Hector_D“You’re not going to solve the energy problem by separating paper and plastic. We need to transition out of our dependency on fossil fuels and into renewables. As a society, it is really up to us to change.”

ECS Fellow Héctor D. Abruña recently spoke on the importance of developing better batteries to change the energy landscape at a Charter Day Weekend lecture at Cornell University.

The energy infrastructure as it exists today cannot maintain in its current form in the years to come. The United Nations expects the world’s population to reach 9.6 billion by 2050. Compare this to the current 7.2 billion population and the current issues with the energy infrastructure and the need for change becomes quite apparent.

Fortunately, Abruña and scientists like him are working to move us toward a more energy efficient and sustainable future through developments in fuel cells and batteries, which will power energy efficient and environmentally safe cars, as well as reshape the energy infrastructure itself.

“If we have any hope of solving the energy problems, we need better energy conversion and storage,” said Abruña.

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