Researchers have traced the paths of three water channels in an ancient photosynthetic organism—a strain of cyanobacteria—to provide the first comprehensive, experimental study of how that organism uses and regulates water to create energy.

The finding advances photosynthesis research but also presents an advance in green fuels research.

Photosynthesis is the chemical conversion of sunlight into chemical energy via an electron transport chain essential to nearly all life on our planet. All plants operate by photosynthesis, as do algae and certain varieties of bacteria.

‘Damage trails’

To convert sunlight into a usable form of energy, photosynthetic organisms require water at the “active site” of the Photosystem II protein complex. But the channels through which water arrives at the active site are difficult to measure experimentally. Reactive oxygen species are produced at the active site and travel away from it, in the opposite direction as water, leaving a “damage trail” in their wake.

“We identified the damaged sites in Photosystem II using high-resolution mass spectrometry and found that they reveal several pathways centered on the active site and leading away from it all the way to the surface of the complex,” says lead study author Daniel A. Weisz, a postdoctoral researcher in biology at Washington University in St. Louis.

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Image: CC0 Public Domain

An interdisciplinary team of researchers based out of the University of Illinois at Chicago believes they may have just changed the game in solar cell technology.

According to the recently published study, the team promises a solar cell that not only harvests energy, but cheaply and efficiently transforms atmospheric carbon dioxide into useable hydrocarbon fuel – all with a little help from the sun.

The new development differs from typical solar technology, where the cells convert sunlight into energy to be stored in batteries or other energy storage devices. Instead, the new research uses solar cells in a way similar to organic photosynthesis, just amplified.

By capturing dangerous greenhouse gases and converting them into alternative, clean fuels, the researchers believe a farm full of these “artificial leaf” solar cells could begin to significantly reduce the amount of carbon dioxide in the environment and help shift the energy landscape toward more green alternatives.

“The new solar cell is not photovoltaic—it’s photosynthetic,” says Amin Salehi-Khojin, senior author of the study. “Instead of producing energy in an unsustainable one-way route from fossil fuels to greenhouse gas, we can now reverse the process and recycle atmospheric carbon into fuel using sunlight.”

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Krishnan Rajeshwar, ECS senior vice president and co-founder of UTA’s Center for Renewable Energy, Science and Technology

New research headed by ECS senior vice president Krishnan Rajeshwar has developed “green fuels” to power cars, home appliances, and even impact critical energy storage devices.

Solar fuels addressing global issues

Rajeshwar’s research works to address critical global and environmental issue by creating an inexpensive way to generate fuel from harmful emissions such as carbon dioxide.

(MORE: Read additional publications by Rajeshwar.)

The University of Texas at Arlington professor and 35 year ECS member has developed a novel high-performing material for cells that harness sunlight to split carbon dioxide and water into usable fuels like methanol and hydrogen gas.

From harmful to helpful

“Technologies that simultaneously permit us to remove greenhouse gases like carbon dioxide while harnessing and storing the energy of sunlight as fuel are at the forefront of current research,” Rajeshwar said. “Our new material could improve the safety, efficiency and cost-effectiveness of solar fuel generation, which is not yet economically viable.”

(MORE: Read the full study as published in ChemElectroChem Europe.)

This from University of Texas at Arlington:

The new hybrid platform uses ultra-long carbon nanotube networks with a homogeneous coating of copper oxide nanocrystals. It demonstrates both the high electrical conductivity of carbon nanotubes and the photocathode qualities of copper oxide, efficiently converting light into the photocurrents needed for the photoelectrochemical reduction process.

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