Last week, Samsung ordered a global recall of its Galaxy Note 7 phones after investigations into claims of exploding devices revealed faulty lithium-ion batteries. Now, the FAA is strongly urging passengers to forge bringing the device on airliners due to safety risks.

Earlier this year, we spoke to ECS member K.M. Abraham about lithium-ion battery devices and safety concerns associated with them.

“It is safe to say that these well-publicized hazardous events are rooted in the uncontrolled release of the large amount of energy stored in Li-ion batteries as a result of manufacturing defects, inferior active and inactive materials used to build cells and battery packs, substandard manufacturing and quality control practices by a small fraction of cell manufacturers, and user abuses of overcharge and over-discharge, short-circuit, external thermal shocks and violent mechanical impacts,” Abraham said. “Safety hazards of Li-ion batteries occur when the fundamental principle of controlled release of energy on which battery technology is based is compromised by materials and manufacturing defects and operational abuses.”

Read Abraham’s full paper on Li-ion safety and building better batteries.

A Stanford University-led team recently published research detailing how particles charge and discharge at the nanoscale, giving new insight into the fundamental functioning of batteries and opening doors for the development of better rechargeables.

This new insight into the electrochemical action that powers Li-ion batteries provides powerful knowledge into the building blocks of batteries.

“It gives us fundamental insights into how batteries work,” says Jongwoo Lim, a co-author of the study. “Previously, most studies investigated the average behavior of the whole battery. Now, we can see and understand how individual battery particles charge and discharge.”

At the heart of every Li-ion battery lies the charge/discharge process. In theory, the ions in the process insert uniformly across the surface of the particles. However, that never happens in practice. Instead, the ions get unevenly distributed, leaving inconsistencies that lead to mechanical stresses and eventually shortened battery life. One way to develop batteries with longer life spans is to understand why these phenomena happens and how to prevent it at the nanoscale.

The recently published research uses x-rays and cutting-edge microscopes to look at this process in real time.

“The phenomenon revealed by this technique, I thought would never be visualized in my lifetime. It’s quite game-changing in the battery field,” says Martin Bazant, co-author of the study.

(more…)

A new open access paper published in the Journal of The Electrochemical Society entitled, “Lithium-Ion Cathode/Coating Pairs for Transition Metal Containment,” finds a new cathode coating for li-ion batteries that could extend the technology’s lifespan.

According to Green Car Congress, the dissolution of transition metals is a major contributor to a li-ion battery’s expedited aging and degradation. However, this new study published in JES by ECS members David Snydacker, Muratahan Aykol, Scott Kirklin, and Christopher Wolverton from Northwestern University makes the case for a new, promising candidate that can act as a stable coating and limit the dissolution of transition metals into the lion electrolyte. That candidate is Li₃PO₄.

This from “Lithium-Ion Cathode/Coating Pairs for Transition Metal Containment”:

There are several distinct categories of strategies for limiting TM dissolution from the cathode. Electrolytes can be tailored to reduce reactivity with the cathode. Cathode materials can be doped to control the oxidation states of transition metals. This doping can be applied to the entire cathode particle or just near the surface. Cathode materials can also be covered with surface coatings to limit TM dissolution. Surface coatings can perform a variety of functions for different cathode materials. In this work, we evaluate the ability of coating materials to contain TMs in the cathode and thereby prevent TM dissolution into the electrolyte.

(more…)

There is no short supply of bourbon in Kentucky. But like many products, the distillation of the state’s unofficial beverage produces a sludgy waste known as bourbon stillage. The question for one researcher from the University of Kentucky’s Center for Applied Energy Research was how to repurpose that waste into something with tremendous potential.

To answer that question, ECS member Stephen Lipka and his Electrochemical Power Sources group set out to transform the bourbon stillage through a process called hydrothermal carbonization, where the liquid waste gets a dose of water and heat to produce green materials.

(MORE: See more of Lipka’s work in the ECS Digital Library.)

“In Kentucky, we have this stillage that contains a lot of sugars and carbohydrates so we tried it and it works beautifully,” says Lipka. “We take these [green materials] and we then do additional post-processing to convert it into useful materials that can be used for batteries.”

(more…)

New research from the University of Washington is opening another avenue in the quest for better batteries and fuel cells. But this research is not a breakthrough in efficiency or longevity, rather a tool to more closely analyze how batteries work.

While we’ve come a long way from the voltaic pile of the 1800s, there is still much work to be done in the field of energy storage to meet modern day needs. In a society that is looking for ways to power electric vehicles and implement large scale grid energy storage for renewables, batteries and fuel cells have never been more important.

A research team from the University of Washington – including ECS members Stuart B. Adler and Timothy C. Geary – believes that these improvements will likely have to happen at the nanoscale. But in order to improve batteries and fuel cells at that microscopic level, we must first understand and see how they function.

[MORE: Read the full journal article.]

The newly developed probe offers a window for researchers to understand how batteries and fuel cells really work.

(more…)

In the field of batteries, lithium is king. But a recent development from scientists at the Toyota Research Institute of North America (TRINA) may introduce a new competitor to the field.

The researchers have recently developed the first non-corrosive electrolyte for a rechargeable magnesium battery, which could open the door to better batteries for everything from cars to cell phones.

“When magnesium batteries become a reality, they’ll be much smaller than current lithium-ion,” says Rana Mohtadi, principal scientist and ECS patron member through TRINA. “They’ll also be cheaper and much safer.”

Magnesium has long been looked at as a possible alternative to lithium due to its high energy density. However, these batteries have not seen much attention in research and development due to the previously non-existent electrolyte. Now that the electrode has been developed, the researchers believe they will be able to demonstrate the value of this system.

(more…)

While you may be unfamiliar with Khalil Amine, he has made an immense impact in your life if you happen to use batteries in any way.

As a researcher with a vision of where the science can be applied in the market, Amine has been monumental in developing and moving some of the biggest breakthroughs in battery technology from the lab to the marketplace.

Amine is currently head of the Technology Development Group in the Battery Technology Department at Argonne National Laboratory. From 1998-2008 he was the most cited scientist in the world in the field of battery technology.

He is the chair of the organizing committee for the 18th International Meeting on Lithium Batteries being held this June in Chicago.

Listen to the podcast and download this episode and others for free through the iTunes Store, SoundCloud, or our RSS Feed. You can also find us on Stitcher.

(more…)

Researchers at the University of California, Irvine may have just developed the ever-lasting battery.

A recent study, published in ACS Energy Letters, details a nanowire-based battery material that can be recharged hundreds of thousands of times – making more realistic the idea of a battery that would never need to be replaced.

Potential applications for the battery range from computers and smartphones to cars and spacecrafts.

Highly-conductive nanowires have always been thought appropriate for battery design, but were held back by the fact that their fragility causes them to breakdown after multiple charging cycles. By coating a gold nanowire in a manganese dioxide shell and encasing the assembly in an electrolyte, the researchers have turn the frail structure into something that has almost infinite recharging capabilities.

Mya Le Thai, a doctoral candidate, led the charge on the research – cycling the tested electrode up to 200,000 times over a three month period without loss of capacity or damage to the nanowire.

“Mya was playing around, and she coated this whole thing with a very thin gel layer and started to cycle it. She discovered that just by using this gel, she could cycle it hundreds of thousands of times without losing any capacity,” said Reginald M. Penner, chair of UC Irvine’s chemistry department and ECS member. “That was crazy, because these things typically die in dramatic fashion after 5,000 or 6,000 or 7,000 cycles at most.”

Thai believes that this study shows that nanowire-based batteries could be commercially viable, and potentially the next big break in battery technology.

When the loaves in your breadbox begin to develop a moldy exterior caused by fungi, they tend to find a new home at the bottom of a trash can. However, researchers have recently developed some pretty interesting results that suggest bread mold could be the key to producing more sustainable electrochemical materials for use in rechargeable batteries.

For the first time, researchers were able to show that the fungus Neurospora crassa (better known as the enemy to bread) can transform manganese into mineral composites with promising electrochemical properties.

(MORE: Read the full paper.)

“We have made electrochemically active materials using a fungal manganese biomineralization process,” says Geoffrey Gadd of the University of Dundee in Scotland. “The electrochemical properties of the carbonized fungal biomass-mineral composite were tested in a supercapacitor and a lithium-ion battery, and it [the composite] was found to have excellent electrochemical properties. This system therefore suggests a novel biotechnological method for the preparation of sustainable electrochemical materials.”

This from University of Dundee:

In the new study, Gadd and his colleagues incubated N. crassa in media amended with urea and manganese chloride (MnCl2) and watched what happened. The researchers found that the long branching fungal filaments (or hyphae) became biomineralized and/or enveloped by minerals in various formations. After heat treatment, they were left with a mixture of carbonized biomass and manganese oxides. Further study of those structures show that they have ideal electrochemical properties for use in supercapacitors or lithium-ion batteries.

Read the full article here.

The manganese oxides in the lithium-ion batteries are showing an excellent cycling stability and more than 90 percent capacity after 200 cycles.

An interdisciplinary team, including 32 year ECS member Stuart Licht and ECS student member Matthew Lefler, has developed a way to make electric vehicles that are not only carbon neutral, but carbon negative – capable of reducing the amount of atmospheric carbon dioxide as they operate by transforming the greenhouse gas.

By replacing the graphite electrodes that are currently being used in the development of lithium-ion batteries for electric cars with carbon materials recovered from the atmosphere, the researchers have been able to develop a recipe for converting collected carbon dioxide into batteries.

This from Vanderbilt University:

The team adapted a solar-powered process that converts carbon dioxide into carbon so that it produces carbon nanotubes and demonstrated that the nanotubes can be incorporated into both lithium-ion batteries like those used in electric vehicles and electronic devices and low-cost sodium-ion batteries under development for large-scale applications, such as the electric grid.

Read the full article.

The research is not the first time scientists have shown progress in collecting and converting harmful greenhouse gases from the environment.

Typically, carbon dioxide conversion revolves around transforming the gas into low-value fuels such as methanol. These conversions often do not justify the costs.

(MORE: Read “Carbon Nanotubes Produced from Ambient Carbon Dioxide for Environmentally Sustainable Lithium-Ion and Sodium-Ion Battery Anodes.“)

However, the new process produces better batteries that are not only expected to be efficient, but also cost effective.

(more…)