Renewable grideThe world’s next energy revolution is looming nearer.

In order to bolster this transformation, the U.S. Department of Energy has been funding 75 projects in the energy technology field, enabling cutting-edge research into energy conversion and storage. This effort is part of the DOE’s goal to “decarbonize” the U.S. energy infrastructure by the middle of the country.

One of the most promising projects funded by the DOE is led by ECS member Michael Aziz, where he and his team from Harvard are addressing challenges in grid energy storage.

Energy storage has become one of the largest barriers in the widespread implementation of renewables. By offering a cost-effective, efficient answer to energy storage, the issues of intermittency in power sources such as wind and solar could be answered.

Aziz and his team are addressing issues in energy storage with the development of a flow battery based on inexpensive organic molecules in a water-based electrolyte. The team is focusing on using quinone molecules, which can be found in such plant sources as rhubarb or even oil waste. The quinone molecules allow energy to be stored in a water-based solution at room temperature.

Aziz recently discussed some of his work in quinon-bromide flow batteries as part of the Journal of The Electrochemical Society Focus Issue on Redox Flow Batteries-Reversible Fuel Cells.

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EVElectric vehicles have become more visible in the automobile market over the past few years, but many potential buyers still cite one thing as a major deterrent in going electric: range anxiety.

Range anxiety is a term many use to describe the fear of an EV’s battery running out of juice while driving, leaving them stranded away from a charging station.

However, a new study published by a team from MIT and the Santa Fe Institute looked at data in order to come to a conclusion that range anxiety is not something that most drivers really need to worry about.

Overcoming range anxiety

“What we found was that 87 percent of vehicles on the road could be replaced by a low cost electric vehicle available today, even if there’s no possibility to recharge during the day,” senior author of the study, Jessika Trancik, told The Washington Post.

As technology progresses, EVs continue to have a leg up on traditional gasoline-powered vehicles. In 2015, battery prices for EVs fell by 35 percent. By 2040, experts predict that long-range EV prices will be less than $22,000. Additionally, an expected 35 percent of all new cars world-wide are expected to come with a plug.

Even as the technology progresses, sociological barriers such as range anxiety remain as a factor that stands in the way of a full market boom of EVs.

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A Stanford University-led team recently published research detailing how particles charge and discharge at the nanoscale, giving new insight into the fundamental functioning of batteries and opening doors for the development of better rechargeables.

This new insight into the electrochemical action that powers Li-ion batteries provides powerful knowledge into the building blocks of batteries.

“It gives us fundamental insights into how batteries work,” says Jongwoo Lim, a co-author of the study. “Previously, most studies investigated the average behavior of the whole battery. Now, we can see and understand how individual battery particles charge and discharge.”

At the heart of every Li-ion battery lies the charge/discharge process. In theory, the ions in the process insert uniformly across the surface of the particles. However, that never happens in practice. Instead, the ions get unevenly distributed, leaving inconsistencies that lead to mechanical stresses and eventually shortened battery life. One way to develop batteries with longer life spans is to understand why these phenomena happens and how to prevent it at the nanoscale.

The recently published research uses x-rays and cutting-edge microscopes to look at this process in real time.

“The phenomenon revealed by this technique, I thought would never be visualized in my lifetime. It’s quite game-changing in the battery field,” says Martin Bazant, co-author of the study.

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Lithium battery

Image: ANL/Flickr

A new open access paper published in the Journal of The Electrochemical Society entitled, “Lithium-Ion Cathode/Coating Pairs for Transition Metal Containment,” finds a new cathode coating for li-ion batteries that could extend the technology’s lifespan.

According to Green Car Congress, the dissolution of transition metals is a major contributor to a li-ion battery’s expedited aging and degradation. However, this new study published in JES by ECS members David Snydacker, Muratahan Aykol, Scott Kirklin, and Christopher Wolverton from Northwestern University makes the case for a new, promising candidate that can act as a stable coating and limit the dissolution of transition metals into the lion electrolyte. That candidate is Li3PO4.

This from “Lithium-Ion Cathode/Coating Pairs for Transition Metal Containment”:

There are several distinct categories of strategies for limiting TM dissolution from the cathode. Electrolytes can be tailored to reduce reactivity with the cathode. Cathode materials can be doped to control the oxidation states of transition metals. This doping can be applied to the entire cathode particle or just near the surface. Cathode materials can also be covered with surface coatings to limit TM dissolution. Surface coatings can perform a variety of functions for different cathode materials. In this work, we evaluate the ability of coating materials to contain TMs in the cathode and thereby prevent TM dissolution into the electrolyte.

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Lithium-oxygen battery

Image: MIT

New lithium-oxygen battery technology proposed by researchers from MIT, Argonne National Laboratory, and Peaking University, promises a scalable, cheap, and safe option in energy storage.

There is immense promise for lithium-oxygen batteries in such applications as electric cars and portable electronics. In fact, they are between five and 15 times more efficient than lithium-ion batteries in transportation applications due to their high energy output potential in proportion to their weight.

But there have been complications in developing and especially implementing these batteries in the marketplace. Primarily, they’ve been known to waste energy and degrade quickly.

But this new study, co-authored by ECS member and past IMLB chair Khalil Amine, states that the theoretical potential for lithium-oxygen batteries could be met while overcoming some of the biggest barriers prohibiting the technology.

Once of the primary focuses of the group was overcoming the mismatch in voltages that happens in charging and discharging the battery. Because the output voltage is more than 1.2 volts lower that that used to charge, there is typically a significant power loss.

“You waste 30 percent of the electrical energy as heat in charging,” says Ju Li, professor at MIT and co-author of the paper. “It can actually burn if you charge it too fast.”

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As the landscape of energy harvesting evolves, so do the devices that store that energy. According to researchers from Toyohashi University, all-solid-state lithium rechargeable batteries are at the top of the list of promising future energy storage technologies due to their high energy density, safety, and extreme cycle stability.

ECS member Yoji Sakurai and a team from the university’s Department of Electrical and Electronic Information Engineering recently published a paper detailing their development to advance the all-solid-state batteries, which pushes past barriers related to electrochemical performance.

(MORE: Read Sakurai’s previously published paper in ECS Electrochemistry Letters.)

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From Bourbon to Batteries

There is no short supply of bourbon in Kentucky. But like many products, the distillation of the state’s unofficial beverage produces a sludgy waste known as bourbon stillage. The question for one researcher from the University of Kentucky’s Center for Applied Energy Research was how to repurpose that waste into something with tremendous potential.

To answer that question, ECS member Stephen Lipka and his Electrochemical Power Sources group set out to transform the bourbon stillage through a process called hydrothermal carbonization, where the liquid waste gets a dose of water and heat to produce green materials.

(MORE: See more of Lipka’s work in the ECS Digital Library.)

“In Kentucky, we have this stillage that contains a lot of sugars and carbohydrates so we tried it and it works beautifully,” says Lipka. “We take these [green materials] and we then do additional post-processing to convert it into useful materials that can be used for batteries.”

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A new report by TechXplore examines a recently published review paper on the potential in nanomaterials for rechargeable lithium batteries. In the paper, lead-author and ECS member Yi Cui of Stanford University, explores the barriers that still exist in lithium rechargeables and how nanomaterials may be able to lend themselves to the development of high-capacity batteries.

When trying to design affordable batteries with high-energy densities, researchers have encountered many issues, including electrode degradation and solid-electrolyte interphase. According to the paper’s authors, possible solutions for many of these hurdles lie in nanomaterials.

Cui’s comprehensive overview of rechargeable lithium batteries and the potential of nanaomaterials in these applications came from 100 highly-reputable publications, including the following ECS published papers:

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Modified Cathode

Cathode particles treated with the carbon dioxide-based mixture show oxygen vacancies on the surface.
Image: Laboratory for Energy Storage and Conversion, UC San Diego

An international team of researchers has recently demonstrated a 30 to 40 percent increase in the energy storage capabilities of cathode materials.

The team, led by ECS member and 2016 Charles W. Tobias Young Investigator Award winner, Shirley Meng, has successfully treated lithium-rich cathode particles with a carbon dioxide-based gas mixture. This process introduced oxygen vacancies on the surface of the material, allowing for a huge boost to the amount of energy stored per unit mass and proving that oxygen plays a significant role in battery performance.

This greater understanding and improvement in the science behind the battery materials could accelerate developments in battery performance, specifically in applications such as electric vehicles.

(READ: “Gas-solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries“)

“We’ve uncovered a new mechanism at play in this class of lithium-rich cathode materials,” says Meng, past guest editor of JES Focus Issue on Intercalation Compounds for Rechargeable Batteries. “With this study, we want to open a new pathway to explore more battery materials in which we can control oxygen activity.”

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When lithium-ion pioneers M. Stanley Whittingham, Adam Heller, Michael Thackeray, and of course, John Goodenough were in the initial stages of the technology’s development in the 1970s through the late 1980s, there was no clear idea of just how monumental the lithium-based battery would come to be. Even up to a few years ago, the idea of an electric vehicle or renewable grid dependent on lithium-ion technology seemed like a pipe dream. But now, electric vehicles are making their way to the mainstream and with them comes the commercially-driven race to acquire lithium.

Just look at the rise of Tesla and success of the Nissan LEAF. Not only are these cars speaking to a real concern for environmental protection, they’re also becoming the more affordable option in transportation. For example, the LEAF goes for less than $25,000 and gets more than 80 miles per charge. Plus, electric vehicles can currently run on electricity that’s costing around $0.11 per kWh, which is roughly equivalent to $0.99 per gallon. The last year alone saw a 60 percent spike in the sale of electric vehicles.

“Electric cars are just plain better,” says James Fenton, director of the Florida Solar Energy Center and newly appointed ECS Secretary. “They’re cheaper to buy up front and they’re cheaper to operate, which years ago, was not the case.”

All things considered, lithium may just be the number one commodity of our time.

But this movement is not specific to the U.S. alone. In Germany – a country dedicated to a renewable future – there is a mandate that all new cars in the country will have to be emission-free by 2030. Similarly in Norway, the government is looking to ban gasoline-powered cars by 2025.

So with the transportation sector heading away from gasoline-powered cars and toward lithium battery-based vehicles globally, what will that do to lithium supplies?

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