printablelii

The batteries have the ability to be integrated into the surface of the objects, making it seem like seem like there is no battery at all.

A new development out of the Ulsan National Institute of Science and Technology (UNIST) has yielded a new technique that could make it possible to print batteries on any surface.

With recent interests in flexible electronics—such as bendable screen displays—researchers globally have been investing research efforts into developing printable functional materials for both electronic and energy applications. With this, many researchers predict the future of the li-ion battery as one with far less size and shape restrictions, having the ability to be printed in its entirety anywhere.

The research team from UNIST, led by ECS member Sang-Young Lee, is setting that prediction on the track to reality. Their new paper published in the journal Nano Letters details the printable li-ion battery that can exist on almost any surface.

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We recently sat down with esteemed battery engineer Esther Takeuchi, the key contributor to the battery system that is still used to power the majority of life-saving implantable cardiac defibrillators.

Takeuchi’s career has made an immense impact on science and has been recognized globally. She currently holds more than 150 U.S. patents, more than any American woman, which earned her a spot in the Inventors Hall of Fame.

Her innovative work in battery research also landed her the National Medal of Technology and Innovation in 2008, where the president complimented her on her work that is “responsible for saving millions of lives.”

Listen to the podcast and download this episode and others for free through the iTunes Store, SoundCloud, or our RSS Feed. You can also find us on Stitcher.

PS: Check out the video version of this podcast and interviews with other world-leaders in electrochemical and solid state science as part of our Masters Series.

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viswanathan-news-brief-chart_500x429-minLithium-air batteries are—in theory—an extremely attractive alternative for affordable, efficient energy storage for electric vehicles. However, as researchers explore this technology, they are met with many critical challenges. If researchers can overcome these challenges, there is a great likelihood that the lithium-air battery will surpass the energy density of today’s lithium-ion battery.

Researchers from Carnegie Mellon University and the University of California, Berkley feel like they may have part of the answer to this critical challenge, which could propel the practicality of the lithium-air battery. The team, which included researchers from Bryan McCloskey and Venkat Viswanathan‘s laboratories, has found a way to both increase the capacity while preserving the recharge ability of the lithium-air battery by blending different types within the battery’s electrolytes.

“The electrolytes used in batteries are just like Gatorade electrolytes,” says Venkat Viswanathan, assistant professor of mechanical engineering at Carnegie Mellon. “Every electrolyte has a solvent and a salt. So if you take Gatorade, the solvent would be water and the salt would be something like sodium chloride, for instance. However, in a lithium air battery, the solvent is dimethoxyethane and the salt is something like lithium hexafluorophosphate.”

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Researchers believe that as work continues in relation to this study, battery technology will accelerate forward.Image: Stony Brook University

Researchers believe that as work continues in relation to this study, battery technology will accelerate forward.
Image: Stony Brook University

A collaborative group of six researchers from Stony Brook University and Brookhaven National Laboratory are using pioneering x-ray techniques to build a better and more efficient battery.

The researchers—four of whom are active ECS members, including Esther Takeuchi, Kenneth Takeuchi, Amy Marschilok, and Kevin Kirshenbaum—have recently published their internal mapping of atomic transformations of the highly conductive silver matrix formation within lithium-based batteries in the journal Science.

(PS: You can find more of these scientists’ cutting-edge research by attending the 228th ECS Meeting in Phoenix, where they will be giving presentations. Also, Esther Takeuchi will be giving a talk at this years Electrochemical Energy Summit.)

This from Stony Brook University:

In a promising lithium-based battery, the formation of a silver matrix transforms a material otherwise plagued by low conductivity. To optimize these multi-metallic batteries—and enhance the flow of electricity—scientists need a way to see where, when, and how these silver, nanoscale “bridges” emerge. In the research paper, the Stony Brook and Brookhaven Lab team successfully mapped this changing atomic architecture and revealed its link to the battery’s rate of discharge. The study shows that a slow discharge rate early in the battery’s life creates a more uniform and expansive conductive network, suggesting new design approaches and optimization techniques.

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ECS Masters – Esther Takeuchi

“Scientific discovery is a marathon, not a sprint. Sometimes you’re running faster or slower, but you always have to keep going.”
Esther Takeuchi

Esther Takeuchi was the key contributor to the battery system that powers life-saving cardiac defibrillators.


She currently holds more than 150 U.S. patents, more than any other American woman, which earned her a spot in the Inventors Hall of Fame. Her innovative work in battery research also landed her the National Medal of Technology and Innovation in 2008.

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You can also listen to this installment of ECS Masters as an audio podcast.

Big Energy Boost for Small Electronics

Yarn made of niobium nanowires can be used to make very efficient supercapacitors.Image: MIT

Yarn made of niobium nanowires can be used to make very efficient supercapacitors.
Image: MIT

With the recent surge in wearable electronics, researchers and looking for a way to get larger amounts of power to these tiny devices. Due to the limited size of these devices, it is difficult to transmit data via the small battery.

Now, MIT researchers have found a way to solve this issue by developing an approach that can deliver short but big bursts of power to small devices. The development has the potential to affect more than wearable electronics through its ability to deliver high power in small volumes to larger-scale applications. The key to this new development is the team’s novel supercapacitor.

This from MIT:

The new approach uses yarns, made from nanowires of the element niobium, as the electrodes in tiny supercapacitors (which are essentially pairs of electrically conducting fibers with an insulator between). In this new work, [Seyed M. Mirvakili] and his colleagues have shown that desirable characteristics for such devices, such as high power density, are not unique to carbon-based nanoparticles, and that niobium nanowire yarn is a promising an alternative.

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Li-Ion Battery with Double the Life

Two-dimensional layered structure of graphene and its silicon carbide-free integration with silicon can serve as a prototype in advancing silicon anodes to commercially viable technology.Source: Nature Communications

Two-dimensional layered structure of graphene and its silicon carbide-free integration with silicon can serve as a prototype in advancing silicon anodes to commercially viable technology.
Source: Nature Communications

Researchers from various institutes across Korea have found a way to nearly double the life of the lithium-ion battery.

In an ever-pressing race to create a more efficient and longer-lasting battery for electronics, researchers across the globe are looking toward alternative materials to make the li-ion battery stronger. A team of researchers associated with Samsung’s Advanced Institute of Technology, including ECS member Jang Wook Choi, have combined silicon and graphene to yield an amazing increase in lithium-ion battery efficiency.

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The new structure has high mobility of Na+ ions and a robust framework.Ia

The new structure has high mobility of Na+ ions and a robust framework.
Image: Nature Communications

With the demand for hand-held electronics at an all-time high, the costs of the materials used to make them are also rising. That includes materials used to make lithium batteries, which is a cause for concern when projecting the development of large-scale grid storage.

In order to find an alternative solution to the high material costs connected with lithium batteries, the researchers at the Australian Nuclear Science and Technology Organisation (ANSTO) and the Institute of Physics at the Chinese Academy of Science in Beijing have begun focusing their attention on sodium-ion batteries.

The science around sodium-ion batteries dates back to the 1980s, but the technology never took off due to resulting low energy densities and short life cycles.

However, the new research looks to combat those issues by improving the properties of a class of electrode materials by manipulating their electron structure in the sodium-ion battery.

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PNNL scientist Jian Zhi Hu shows a tiny experimental battery mounted in NMR apparatus.Image: PNNL

PNNL scientist Jian Zhi Hu shows a tiny experimental battery mounted in NMR apparatus.
Image: PNNL

While working on a unique lithium-germanide battery, Pacific Northwest National Laboratory (PNNL) researchers knew something was happening inside the battery to dramatically increase its energy storage capacity, but they couldn’t see it. With no way to analyze the reaction occurring, the researchers could not understand the process. In order to solve the problem, the researchers developed a novel nuclear magnetic resonance (NMR) technique to allow insight and understanding of the electrochemical reactions taking place in the battery. Essentially, they have developed an NMR “camera.”

In the end, this leaves the scientists with not only a novel lithium-germanide battery with a distinctly high energy density, but also an NMR device that can be used to examine reactions as they happen inside the battery.

This from PNNL:

By using the NMR process to look inside the battery and observe this reaction as it happened, the scientists found a way to protect the germanium from expanding and becoming ineffective after it takes on lithium. The secret proved to be forming the germanium into tiny “wires” and encasing them in small, protective carbon tubes to limit the expansion. This technique significantly stabilizes battery performance. Without embedding germanium in carbon tubes, a battery performs well for a few charging-discharging cycles, but fades rapidly after that. Using the “core-shell” structure, however, the battery can be discharged and charged thousands of times.

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Engineering Stretchable Batteries

Recently, scientists have been looking at the Japanese paper-folding art of origami as inspiration for novel flexible energy-storage technologies. While there have been breakthroughs in battery flexibility, there has yet to be a successful development of stretchable batteries. Now, researchers from Arizona State University have unveiled a way to make batteries stretch, yielding big potential outcomes for wearable electronics.

The Arizona State University research team includes ECS member and advisor of the ECS Valley of the Sun student chapter, Candace K. Chan. Chan and the rest of the team were inspired by a variation of origami called kirigami when developing this new generation of lithium-ion batteries.

According to the researchers, the new battery can be stretched more than 150 percent of its original size and still maintain full functionality.