201st Meeting - Philadelphia, PA

May 12-17, 2002


AE1 - Fifth International Manuel M. Baizer Award Symposium On Organic Electrochemistry

Organic and Biological Electrochemistry

Monday, May 13, 2002

Salon C, Level 5

Synthetic Aspects

Co-Chairs: H.J. Schafer and S. Torri

10:001219 Reduction of "Cation Pool". A New Approach to Radical Mediated C-C Bond Formation - S. Suga, S. Suzuki, and J.-I. Yoshida (Kyoto University)
10:251220 Anodic Partial Fluorination under Ultrasonication - T. Fuchigami, T. Sunaga, H. Ishii, and M. Atobe (Tokyo Institute of Technology)
10:501221 Electrosynthesis using New Biphasic Organic Reaction System with Mutual Miscibility - K. Chiba, Y. Kono, S. Kim, Y. Kitano, and M. Tada (Tokyo University of Agriculture and Technology)
11:151222 Use of Electrogenerated Highly Reactive Zinc in Facile Synthesis of 2-Arylpropenoic Acid Esters and Anti-inflammatory Agents - M. Tokuda, A.A. Jalil, and N. Kurono (Hokkaido University)
11:401223 Optimizing Turnover of a Metallopolyion-Coated Electrode in a Flow Cell in Microemulsions - A. Vaze and J. Rusling (University of Connecticut)

Synthetic Aspects

Co-Chairs: H. Lund and H. Tanaka

1:301224 N-Oxyl-Mediated Electro-oxidation of Alcohols in Silica Gel-Water Disperse System. Column-Flow System - H. Tanaka, M. Mine, A. Morimoto, J. Chou, and M. Kuroboshi (Okayama University)
1:551225 Intramolecular Cyclization of Hetero-atom Containing Non-conjugated Unsturated Keytones by Electrochemical Reduction - I. Nishiguchi, S. Goda, K. Yamada, and H. Maekawa (Nagaoka University of Technology)
2:201226 Functional Group Transformation of Trifluoromethyl-substituted Organic Compounds by Electrochemical Oxidation - Y. Matsumura, K. Shirai, T. Maki, and O. Onomura (Nagasaki University)
2:451227 Electrochemical Carbonylation of Primary Amines to Symmetrical N,N'-Disubstituted Ureas Using Palladium (II) Catalyst in Combination with Its Anodic Recycling - I. Chiarotto and M. Feroci (Universita degli Studi "La Sapienza")
3:101228 Enantioselective Electroreduction of 3-Methylinden-1-one in the Presence of Chiral Catalysis - H.J. Schafer and T. Kupper (University of Munster)
3:35 Twenty-Minute Intermission -
3:551229 The Use of Solid Metallic Cathodes in Organic Electrochemistry - J. Simonet and C. Cougnon (Universite de Rennes)
4:201230 Highly Selective and Facile Synthesis of Dihydro- and Tetrohydropyridine Dicarbxylic Acid Derivatives Using Electroreduction as a Key Step - I. Nishiguchi (Nagaoka University of Technology), Y. Kita (Orient Chemical Undustries, Ltd.), H. Maekawa (Nagaoka University of Technology), and Y. Yamasaki (Orient Chemical Undustries, Ltd.)
4:451231 Electrochemical Molecular Transformations catalyzed by Vitamin B12 Derivatives - Y. Hisaeda, H. Shimakoshi, A. Nakazato, and T. Hayashi (Kyushu University)
5:101232 Deoxygenation of Aliphatic Acetate Derivatives Using Electrogenerated Organic Amalgams - L.M. Fragoso-Luna, B.A. Frontana-Uribe, and J. Cardenas (Universidad Nacional Autonoma de Mexico)
5:351233 Cathodic Dechlorination of Trichloroethylene - M.-H. Chen and T.-C. Chou (National Cheng Kung University)

Tuesday, May 14, 2002

Salon C, Level 5

Mechanistic Aspects

Co-Chairs: D. Evans and F. Maran

8:001234 Endoperoxides as Probes into Electron Transfer Kinetics:: A Mechanistic Investigation of the Electron Transfer Reduction of 3,3,6,6-tetraryl-1,2-dioxanes - M. Workentin and D. Stringle (The University of Western Ontario)
8:251235 Polarographic Study Of The Kinetics And Equilibria Of The Reaction Of Benzaldehydes With Hydrazine - P. Zuman and S. Baymak (Clarkson University)
8:501236 Mediated Electrochemistry of Horseradish Peroxidase. Catalysis and Inhibition - D. Murielle (Faculte de Medecine et de Pharmacie), L. Benoit, M. Jacques, and S. Jean-Michel (Universite de Paris 7)
9:151237 Dissociative Electron Transfer of Phenyl-Substituted Bicyclic Endoperoxides - D.C. Magri and M.S. Workentin (The University of Western Ontario)
9:401238 Electrochemically-Induced Reactivity of Fullerene Derivatives - M. Carano, M. Marcaccio, M. Margotti, F. Paolucci, and S. Roffia (University of Bologna)
10:051239 Electrochemistry in Ionic Liquids . Voltammetry and Electro chemical Reduction of Dinitro Compounds. - A. Fry (Wesleyan University) and D. Peters (Indiana University)
10:301240 Ion / Radical Pair from Dissociative Electron Transfer. Stability as a Function of the Solvent - L. Pause, M. Robert, and J.-M. Saveant (University Paris 7)

Mechanistic Aspects

Co-Chairs: J. Lessard and J. Simonet

1:301241 Intramolecular Dissociative Electron Transfer Through Peptide Bridges - S. Antonello, F. Formaggio, A. Moretto, C. Toniolo, and F. Maran (University of Padova)
1:551242 Electron Transfer to Sulfenate Esters - D. Stringle and M. Workentin (University of Western Ontario)
2:201243 Single Two-Electron Transfers in the Electrochemical Oxidation and Reduction of Carotenoids - V. Konovalov (University of Alabama at Birmingham), P. Hapiot (Universite de Paris 7 -Denis Diderot), L. Kispert (University of Alabama), and J.-M. Saveant (Universite de Paris 7 -Denis Diderot)
2:451244 Reduction of Alkyl Halides by Electrogenerated Cobalt(I) Salen and Nickel(I) Salen: Reactions of Alkyl Radicals with NO and O2 - D. Peters, C. Ji, and P. Vanalabhpatana (Indiana University)
3:101245 Electron Transfer at Interfaces - R.A. Marcus (California Inst. of Technology)
3:35 Twenty-Five Minute Intermission -
4:001246 Electrochemical Reduction of 1,3,5-Triphenylbenzene to 1,3,5.Triphenylcyclohexane - H. Lund (University of Aarhus)
4:251247 Voltammetric Studies of the Reduction of cis- and trans-alpha-Nitrostilbene - D. Evans, C. Kraiya, and Z. Todres (University of Delaware)
4:501248 Stepwise and Concerted Reaction Paths Triggered by Electrochemical, Homogeneous, and Photoinduced Electron Transfer - J.-M. Saveant (Universite de Paris 7)

Materials and Applications

Co-Chairs: M.S. Workentin and I. Nishiguchi

8:001249 New Methodologies for Preparation of Highly -Regulated Structure Films of Conducting Polymers - M. Atobe and T. Fuchigami (Tokyo Institute of Technology)
8:251250 Investigations into the Role of Metal Ion Linkers in the Self-Exchange ET Between Monolayer Protected Cluster Molecules - R.L. Donkers and R.W. Murray (The University of North Carolina at Chapel Hill)
8:501251 Stability Improvement of Solid-state Dye-sensitized Photovoltaic Cell by Adding Imidazolium Thiocyanate to Copper Iodide P-type Semiconductor Layer - A. Konno, G.R.A. Kumara (Shizuoka University), and K. Tennakone (Institute of Fundamental Studies)
9:151252 Electrochemical Reduction and Carboxylation of Chloroacetonitrile - A.A. Isse and A. Gennaro (University of Padova)
9:401253 Electrochemical Conversion of Brown Coal (Victoria Brown Coal) into @ Soluble Fumic Acid Derivatives by Using Small Zappi Cell for Bio-Gassification Process - S. Torii and K. Inoue (The Institute of Creative Chemistry)
10:051254 Development of Hydrogenolysis-free Hydrogenation Selective Pd Black Catalyst Deposited on Sheet - S. Maki (The University of Electro-Communications)
10:301255 Towards Molecular-Level Understanding of Electrocatalytic Hydrogenation. Part 1. Behavior of Benzene at Pt(111) - Z. Radovic-Hrapovic, J.-P. Tessier, G. Jerkiewicz, and J. Lessard (Universite de Sherbrooke)

Wednesday, May 15, 2002

Co-Chairs: D. Peters and J. Rusling

1:301256 Electrochemical Reductions of Alkyl (HET)Aryl Ketoximes and Their Ni2+, Cu2+ And Zn2+ Complexes on Mercury - J. Ludvik (Academy of Sciences of the Czech Republic), R. Cibulka (Prague Institute of Chemical Technology), G. Ekmekci (Academy of Sciences of the Czech Republic), and P. Zuman (Clarkson Univ.)
1:551257 Redox-Triggered Molecular Switches. Electronic Communication in Heterobimetallic Indacenyl Mixed Valence Complexes. - S. Santi, F. Carli, A. Ceccon, L. Crociani, A. Gambaro, M. Tiso (Universita' degli Studi di Padova), and A. Venzo (CNR)
2:201258 Experimental and Theoretical Study of Electrochemical Oxidation of 4-Hydroxyiminopyrazol-2-IN-5-ONES - V.V. Yanilkin, A.V. Toropchina, V.I. Morozov (Russian Academy of Sciences), and G.A. Chumtova (Kazan State University)
2:451259 Conversions of Nitrogen-containing Heterocycles Induced by Eelctron Transfer - V.V. Yanilkin, N.V. Nastapova, V.I. Morozov, R.M. Eliseenkova, Z.A. Bredikhina, A.A. Bredikhin, and B.I. Buzykin (Russian Academy of Sciences)