203rd Meeting - Paris, France

April 27-May 2, 2003


AC3 - Mechanistic and Synthetic Aspects of Organic and Biological Electrochemistry

Organic and Biological Electrochemistry

Wednesday, April 30, 2003

Room 242B, Level 2, Le Palais des Congres

Co-Chairs: J. Simonet and J. Rusling

8:202526 Homo- and Heterocoupling of Aldehydes, Ketones, Acrylesters and Imines at a Graphite Cathode in Protic Electrolytes - H.J. Schafer and K. Burger (University of Munster)
8:402527 Electroauxiliary-Assisted Sequential Introduction of Two Carbon Nucloephiles on the Same a-Carbon of Nitrogen: Application to the Synthesis of Spiro Compounds - J.-I. Yoshida, M. Watanabe, and S. Suga (Kyoto University)
9:002528 Approaches to Chiral Electrogenerated Bases - H. Groombridge, R. Horcajada, A. Mateo-Alonso, J. Utley, and P. Wyatt (University of London)
9:202529 Mechanistic Study on Electrochemical Generation of Chiral Iminium Ions from Chiral Amino Acids - Y. Matsumura, G. Wanyoike, T. Maki, and O. Onomura (Nagasaki University)
9:40 Twenty-Minute Intermission
10:002530 On the Mechanism of Formation of Cyclobutanes by Cathodic Cyclodimerization of Vinylarylsulfones: Spectroelectrochemical Study and MO-Modeling - E. Volanschi, M. Hillebrand (University of Bucharest), P. Hapiot, C. Lagrost, J.F. Berganimi, and J. Simonet (University of Rennes 1)
10:202531 Novel Electrosynthesis of Arylboronic Acids and Esters - E. Dunach and C. Laza (Universite Nice-Sophia Antipolis)
10:402532 Electrochemical Preparation of Strong Bases - H. Lund (University of Aarhus)
11:002533 Electrochemically Induced Diastereoselective Functionalization of N-acyloxazolidin-2-Ones - M. Feroci (Universita "La Sapienza), M. Orsini, L. Palombi, and A. Inesi (Universita degli Studi)
11:202534 Electrocatalytic Hydrogenation of Substituted Naphthalenes at Raney Nickel Electrodes in Aqueous Media - S. Jobin and J. Lessard (Universite de Sherbrooke)
11:402535 Selective Electrochemical Fluorination of Organooxygen Compounds in Ionic Liquids - T. Fuchigami, M. Hasegawa, and H. Ishii (Tokyo Institute of Technology)

Co-Chairs: H.J. Schafer and J.I. Yoshida

14:002536 Facile Synthesis of Useful Carboxylic Acids by Electrochemical Carboxylation - M. Tokuda, D. Furuya, H. Komatsu, H. Kanaya, N. Kurono, and H. Senboku (Hokkaido University)
14:202537 Electrochemical Synthesis in Microemulsions with Crosslinked Poly(L-lysine)-Protein Films - J. Rusling, A. Vaze, and B. Nuthakki (University of Connecticut)
14:402538 Electrochemical Functioning of White Phosphorus as a Novel Way to Efficient Organophosphorous Compound Preparation - Y. Budnikova, D. Yakhvarov, and O. Sinyashin (Institute of Organic and Physical Chemistry)
15:002539 Adsorption of Phosphonic Acid Terminated Ferrocene Molecules on ITO Electrodes - V. Barbara, Z. Gianni, S. Gilberto, Z. Sandro (Istituto per l'Energetice e le Interfasi IENI-CNR), and B. Anna (Istituto CNR di Scienze e Tecnologie Molecolari)
15:202540 Development of Selective Hydrogenation Pd Black Catalyst Deposited on Pd Sheet - S. Maki (The University of Electro-communications)
15:40 Twenty-Minute Intermission
16:002541 New Metal-Oxide Electrodes for Fast Direct Electron Transfer to the Redox Proteins - V. Reipa and V. Vilker (National Institute of Standards and Technology)
16:202542 The Use of Tetraalkylammonium Salts as Electrolytes for Reduction at Metallic Solid Cathodes. Why Tetramethylammonium Salts Behave so Differently - J. Simonet and C. Cougnon (Universite de Rennes I)
16:402543 Electrooxidation of Alcohols in an N-Oxyl Immobilized Rigid Polymer Particles Disperse Water System - H. Tanaka, T. Ido, J. Kubota, M. Kuroboshi, T. Uchida, and K. Shimamura (Okayama University)
17:002544 Investigation of Electrochemical Behavior of Stimulation/Sensing Electrode Materials - II. RuO_2 and IrO2-Coated Electrodes - A. Norlin, J. Pan, and C. Leygraf (Royal Institute of Technology)
17:202545 Cyclic Voltammetry and Scanning Electrochemical Microscopic Study of Menadione Permeability through Self-Assembled Monolayer on a Gold Electrode - C. Cannes (Universite d'Orsay), F. Kanoufi (Laboratoire d'Environnement et de Chimie Analytique), and A.J. Bard (University of Texas at Austin)

Thursday, May 1, 2003

Co-Chairs: A.J. Fry and D.G. Peters

8:202546 Electron Transfer at the Liquid-Liquid Interface, between Lu(III) Bisphthalocyanines in a Solvent and Fe(III)/Fe(II) in Water. Studies at a Micro-Interface and at Solvent Film Electrodes. - M. L'Her, S. Peulon, K. Bongue-Boma (Universite de Bretagne Occidentale), A. Nassi (Universite de Douala), E. Ngameni (Universite de Bretagne Occidentale), A. Pondaven (Universite de Yaounde), and C. Cadiou (Universite de Bretagne Occidentale)
8:402547 Electroreductive Double Carbon-Carbon Bond Formation of Alkyl Methacrylates - I. Nishiguchi, Y. Yamamoto, and H. Maekawa (Nagaoka University of Technology)
9:002548 Electro-oxidative N-Halogenation of 2-Azetidinone Derivatives. Reaction of N-Halo-2-azetidinones - H. Tanaka, S.-Y. Arai, Y. Ishitobi (Okayama University), and S. Torii (Institute of Creative Chemistry)
9:202549 Mechanistic and Synthetic Aspects of the Simons Process. Electrochemical Synthesis of New Organo-Phosphorus Compounds - N. Ignat'ev, U. Welz-Biermann, M. Weiden, U. Heider (Merck KGaA, NB-C), A. Kucheryna, P. Sartori, and H. Willner (Gerhard-Mercator-University of Duisburg)
9:40 Twenty-Minute Intermission
10:002550 Electrochemically Induced Ring-Closing and Ring-Opening Reactions of Photochromic Dithienylalkenes - N. Branda and A. Peters (Simon Fraser University)
10:202551 New Aspects of Electrochemical Synthesis in Organosilicon Chemistry - B. Loidl, H. Fallmann, H. Stueger, and C. Grogger (Graz University of Technology)
10:402552 Contribution to Electroreduction of Hydrazones - P. Zuman, M.S. Baymak, H. Celik (Clarkson University), and H. Lund (Aarhus University)
11:002553 Synthesis, Electrochemical, and Spectroscopic Studies on a New Series of Pyrrole and Thiophene Derivatives - N. Ono, S. Ito, Z. Shen, Y. Shimizu, and H. Uno (Ehime University)
11:202554 Mechanistic and Synthetic Aspects of N-arylazoles Formation in Undivided Electrolysis of the Mixture Azole / Arene in MeCN - V. Petrosyan, V. Chauzov, and A. Burasov (Russian Academy of Sciences)
11:402555 Electrochemical Synthesis of Stereoisomeric 1,2-bis (2-spirobifluorenyl)1,2-ethanediols - G. Fioravanti, L.B. Rampazzo, and L. Mattiello (University of Rome “La Sapienza”)

Co-Chairs: J. Lessard and J.H.P. Utley

14:002556 Electrochemical Nitrogen Transfer Reactions for Organic Synthesis - T. Siu, C. Picard (Ylektra, Inc.), and A. Yudin (University of Toronto)
14:202557 Reductive Molecular Transformations on Vitamin B12 Modified Electrode - Y. Hisaeda, H. Shimakoshi, and M. Tokunaga (Kyushu University)
14:402558 Electrolytic Cyclization of Dipeptides Involving Proline-Moiety for Construction of Conformation-Constrained Peptidomimetics - T. Suzuki, K. Hayashi, Y. Kitano, M. Tada, and K. Chiba (Laboratory of Bio-organic Chemistry)
15:002559 Synthetic Studies on Bioactive Natural Products Employing Electrochemical Methodology, Synthesis of Heliannuol E - F. Doi, T. Ogamino, T. Sugai, and S. Nishiyama (Keio University)
15:202560 Electrochemical Oxidation and Reduction of alpha-Dimethylsilyl Esters. A Novel Anodic Silicon Gamma-Aryl Effect - A. Fry and C. Kaimakliotis (Wesleyan University)
15:40 Twenty-Minute Intermission
16:002561 Underpotential Oxidation Peak (UPO) and Potentiodynamic Evaltuation of Kinetics for Anodic Aldehyde Behavior - M. Kotorcevic, D. Simovic, J.M. Jaksic, C. Lacnjevac, and M.M. Jaksic (University of Belgrade)
16:202562 Substituent Effect on the Cyclization Reactions of Diphenylamine Derivative Cation Radicals in Acetonitrile - M. Oyama, H. Park, and T. Imabayashi (International Innovation Center, Kyoto University)
16:402563 Electrochemical Reduction of Aryl Thiocyanates: A Unique Autocatalytic Process and Evidence for a Concerted-Stepwise Mechanism Transition - A. Houmam, E.M. Hamed (University of Guelph), and I.W.J. Still (University of Toronto at Mississauga)
17:002564 Alkylation of [2,2'-([2,2'-Bipyridine]-6,6'-diyl)bis[phenolato]-N,N',O,O']nickel(II) - D. Goken and D. Peters (Indiana University)
17:202565 Asymmetric Dihydroxylation of Olefins in (DHQD)2PHAL-Immobilized Silica Gel-Water Disperse System. An Approach to Fe/Os-Mediated Electrooxidation (Ex-cell Method) - M. Kurpoboshi, T. Mizone, M. Nishiguchi, and H. Tanaka (Okayama University)

Friday, May 2, 2003

Co-Chairs: P. Zuman and H. Tanaka

8:202566 Localized Graft Copolymerization of Polytetrafluoroethylene Following Carbonization by Scanning Electrochemical Microscopy (SECM) - C. Combellas, F. Kanoufi, D. Mazouzi, and A. Thiebault (Ecole Superieure de Physique et Chimie Industrielles de Paris)
8:402567 Understanding Solvent-Solute Interactions In Ionic Liquids: Studies of the Ferricenium/Ferrocene Redox Couple - M.C. Lagunas, W.R. Pitner, J. van den Berg, and K.R. Seddon (The Queen's University of Belfast)
9:002568 Electrocatalytic Oxidation of Cyclic Ketones - M. Elinson, S. Feducovich, A. Dorofeev, and G. Nikishin (Russian Academy of Sciences)
9:202569 Electroanalytical Determination of the Mechanism of the Cobalt-Catalyzed Electrochemical Coupling Between Aromatic Halides and Allylic Acetates - P. Gomes, C. Gosmini, O. Buriez, E. Labbe, and J. Perichon (CNRS 7582)
9:40 Twenty-Minute Intermission
10:002570 Catalytic Reduction of Oxygen and Trichloroacetic Acid on Myoglobin/Polyethyleneimine Modified Electrodes - A. Pardo, R. Basseguy, and A. Bergel (Universite Paul Sabatier)
10:202571 Ti(III)- and Electrochemically-induced Anti-Selective Reformatsky Reactions - D. Shelton, J. Parrish, and D. Little (UC Santa Barbara)
10:402572 Electrocatalytic Oxidation of Sugars on Single Crystal Gold Electrodes Modified with Ad-metals in Alkaline Solutions - I. Taniguchi, S. Ben Aoun, G.S. Bang, T. Koga (Kumamoto University), and T. Sotomura (Matushita Electric Industrial Co., Ltd.)
11:002573 Catalytic Reduction of Alkyl Halides with Electrogenerated Nickel(I) Salen: Formation of Aldehydes and Ketones - P. Vanalabhpatana and D. Peters (Indiana University)
11:202574 Silver Cathodes as Electrocatalysts in the Carboxylation of Benzyl Chlorides - A.A. Isse and A. Gennaro (Universita di Padova)
11:402575 Electroactivation of Modified Carbon Paste Electrodes in the Presence of Phase Transfer Catalysts - S. Serban, M. Boujtita, and N. El Murr (University of Nantes)

Co-Chairs: R.D. Little and A. Gennaro

14:002576 Influence of the Intra- and Intermolecular Hydrogen Bonds on the Redox Properties of Aminoanthraquinone Derivatives - H. Randriamahazaka, G. Sini, and C. Chevrot (Universite de Cergy-Pontoise)
14:202577 Rates and Mechanism of Organozinc Electrosynthesis Catalyzed by Co^(2+) in Pure Acetonitrile - O. Buriez, S. Seka, and J. Perichon (CNRS 7582)
14:402578 Electron Transfer-Induced Conformational Changes of Highly Hindered Aromatic Compounds. Case of Hexakis(Alkylsulfonyl)Benzenes - B. Fabre, P. Hapiot, and J. Simonet (Universite de Rennes 1)
15:002579 Oxidation of Priamry Aliphatic Amines Catalyzed by an Electrogenerated Quinoid Species: A Small Molecule Mimic of Amine Oxidases - M. Largeron, A. Neudorffer, M. Benoit, and M.-B. Fleury (Universite Rene Descartes)
15:202580 Novel Redox-Active Pai-Conjugated Systems - T. Hirao, K. Saito, M. Ritonga, S. Naka, T. Moriuchi, and H. Sakurai (Osaka University)
15:40 Twenty-Minute Intermission
16:002581 Miniaturized Potentiometric Sensors Based on pH-Dependent Polymers - B. Lakard, G. Herlem (Universite de Franche Comte), M. de Labachelerie, J.C. Jeannot, W. Daniau, G. Martin (Laboratory of Physics Metrology and Oscillators), and B. Fahys (Universite de Franche Comte)
16:202582 Anodic Polymerization of Diamines leading to Polyalkyleneimine : Mechanism, Properties, and Applications - G. Herlem, G. Herlem (University of Franche-Comte), M. Herlem (Institut Lavoisier), and B. Fahys (University of Franche-Comte)
16:402583 In Situ Spectroelectrochemical Studies of Radical Reactions in New Ladder Type Oligomers - L. Dunsch, P. Rapta (IFW Dresden), N. Schulte, and A.D. Schluter (Institut fur Chemie der FU Berlin)
17:002584 Electrochemistry of Various Organosilicon Derivatives - J.Y. Becker (University of the Negev)