The capture and recycling of carbon dioxide in the atmosphere may be the first stop toward a “methanol economy.”

For the first time, researchers have successfully proven that carbon dioxide captured from the environment can be transformed into methanol. This not only removes damaging carbon dioxide emissions, but also produces an exciting alternative fuel. For some, this is an inevitable step toward an economy where fuel and energy storage would be primarily based on methanol.

The study was led by the University of Southern California professors G. K. Surya Prakash and George A. Olah and was published in the Journal of the American Chemical Society.

“Direct CO2 capture and conversion to methanol using molecular hydrogen in the same pot was never achieved before. We have now done it!” Prakash says.

Methanol is especially attractive because of its use as an alternative fuel in fuel cells and for hydrogen storage. Some believe that methanol is the future, with 70 million tons already being produced annually via the production of plastics.

This from Phys.org:

In the new study, the researchers developed a stable catalyst based on the metal ruthenium that does not decompose at high temperatures. The catalyst’s good stability allows it to be reused over and over again for the continuous production of methanol.

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Uphill Battle for Electric Cars

With plunging oil prices, it is proving to be more difficult than ever to entice buyers into purchasing an electric vehicle. While the low oil prices may be good for consumers’ gas tanks, the transportation sector continues to account for 27 percent of the United States’ greenhouse gas emissions.

The question then arises of how electric car manufacturers can steer folks back toward electric vehicles and away from gas-guzzling cars?

(MORE: Read Interface: PV, EV, and Your Home)

Impact of falling oil prices

“It definitely makes the transition to sustainable energy more difficult,” said Elon Musk, Tesla CEO, at a business conference in Hong Kong about the impact of the free-falling oil prices.

Tesla rose to prominence in 2003 when oil prices soared, making electric vehicles all the more tempting. With oil prices continually on the decline, it’s now up to companies like Tesla to compel buyers and stress the importance of transitioning toward cleaner vehicles.

New features for electric cars

For companies like Tesla, that means developing things like autonomous cars with “summon” features – allowing the user to call their car just like a pet. Even aesthetic aspects have become more important, with Tesla focusing on futuristic designs.

“What we’re aspiring to do is to make the cars so compelling that even with lower gas prices, it’s still the car you want to buy,” Musk said.

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Importance of Energy Storage

While society as a whole is moving toward cleaner, more renewable energy sources, there is one key component that is typically glossed over in the energy technology conversation: energy storage.

Developments in solar and wind are critical in the battle against climate change, but without advances in energy storage, our efforts may fall short. What happens when the sun isn’t shining or the wind isn’t blowing?

The folks at Popular Science are providing a friendly analogy to explain the the importance of energy storage.

Fighting the good fight in energy technology? Present your work at IMLB! Submit your abstracts today!

Advancing Lithium-Air Batteries

As electronics advances, the demand for high-performance batteries increases. The lithium-ion battery is currently leading the charge in powering portable electronic devices, but another lithium-based battery contender is on the horizon.

The lithium-air battery is one of the most promising research areas in current lithium-based battery technology. While researchers such as ECS’s K.M. Abraham have been on the Li-air beat since the late 90s, current research is looking to propel this technology with the hopes of commercializing it for practical use.

A new contender: Lithium-air batteries

Recently, Khalil Amine, IMLB chair; and Larry Curtiss, IMLB invited speaker, co-authored a paper detailing a lithium-air battery that could store up to five times more energy than today’s lithium-ion battery.

(MORE: Submit your abstract for IMLB today!)

This work brings society one step closer to the commercial use of lithium-air batteries. In previous works regarding Li-air, researchers continuously encountered the same phenomenon of the clogging of the pores of the electrode.

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SOFC

New material could help SOFCs operate more efficiently and cheaply.
Image: Bloom Energy

Solid oxide fuel cells may be producing cleaner energy at a more efficient level soon, thanks to a development at the University of Cambridge.

A new thin-film electrolyte material, developed by a team including ECS member Sergei Kalinin, has the potential to propel portable power sources due to its ability to achieve high performance levels and very low temperatures.

Advancing fuel cells

With a huge scientific focus shift toward developing new energy technologies, fuel cells have emerged as a big contender. Transitioning from a simple laboratory curiosity in the 19th century to a main contender for powering electric vehicles, researchers have dedicated much energy to building an efficient, cost effective fuel cell.

(MORE: Read “Battery and Fuel Cell Technology“)

This from University of Cambridge:

By using thin-film electrolyte layers, micro solid oxide fuel cells offer a concentrated energy source, with potential applications in portable power sources for electronic consumer or medical devices, or those that need uninterruptable power supplies such as those used by the military or in recreational vehicles.

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ECS Member Makes Strides in Battery Safety

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Image: Penn State

With the newly popular hoverboards bursting into flames, safety in batteries has made its way to the public spotlight. To increase lithium ion battery safety, one ECS member is working to develop batteries with built in sensors to warn users of potential problems.

Chao-Yang Wang, 19-year ECS member, is taking on the challenge of making the highly popular lithium ion battery safer in light of demands for smaller, more energy efficient devices.

“Li-ion batteries essentially provide portable power for everything,” says Wang. “Your cell phone charge can now last for a week instead of a day, but it’s still the same size. The battery has a lot more energy density, you are compressing more and more energy into a smaller space, and you have to be careful when you do that. Our job is to come up with solutions to provide safety while at the same time increasing performance.”

While lithium ion batteries are typically safe under normal conditions, the battery’s flammable electrolyte solution could overheat and catch fire if it is punctured or overcharged.

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Harnessing Energy from Small Bending Motions

When we think of energy, often large-scale grid storage or sleek, highly-efficient lithium ion batteries that power most of our electronics are the first things that come to mind. However, for applications such as biomedical or environmental monitoring devices, there could be an alternative way to harness energy without the use of pricy technology.

Researchers have discovered the through harnessing the energy crated by small motions, a small but unlimited power supply could be generated. With electrochemical principals as the backbone of the study, MIT researchers have developed a new way to harvest energy from natural motions and activates, including something as simple as walking.

The system is based on the slight bending of a sandwich of metal and polymer sheets.

This from MIT:

Most previously designed devices for harnessing small motions have been based on the triboelectric effect (essentially friction, like rubbing a balloon against a wool sweater) or piezoelectrics (crystals that produce a small voltage when bent or compressed). These work well for high-frequency sources of motion such as those produced by the vibrations of machinery. But for typical human-scale motions such as walking or exercising, such systems have limits.

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Teaching Bacterium a New Trick

Scientists are teaching old bacterium some new tricks in an effort to advance artificial photosynthesis.

The bacterium Moorella thermoacetica has been trained to perform photosynthesis, even though it is non-photosynthetic. All of this comes with a push to convert sunlight into valuable chemical products for a cleaner, greener energy future.

“We’ve demonstrated the first self-photosensitization of a non-photosynthetic bacterium, M. thermoacetica, with cadmium sulfide nanoparticles to produce acetic acid from carbon dioxide at efficiencies and yield that are comparable to or may even exceed the capabilities of natural photosynthesis,” says Peidong Yang, lead researcher of this work.

Previously, Yang’s work has centered around the development of the artificial “leaf,” which aims to produce natural gas from carbon dioxide. This extension of that work is still in line with the development of a clean energy future.

(MORE: Read more of Yang’s research in the ECS Digital Library.)

“In our latest study, we combined the highly efficient light harvesting of an inorganic semiconductor with the high specificity, low cost, and self-replication and self-repair of a biocatalyst,” Yang says. “By inducing the self-photosensitization of M. thermoacetica with cadmium sulfide nanoparticles, we enabled the photosynthesis of acetic acid from carbon dioxide over several days of light-dark cycles at relatively high quantum yields, demonstrating a self-replicating route toward solar-to-chemical carbon dioxide reduction.”

Observing a Chemical Reaction

In order to improve upon existing technology, researchers typically take a deeper look into current generation models to get a deeper understanding of everything that is happening on the small-scale. Answering questions as to why something happens or when it happens could allow researchers to make current technology more efficient.

One of the things that researchers have been working to more fully understand for some time now is that of a chemical reaction. For the first time ever, researchers from MIT have observed the exact moment when a chemical reaction occurs between two substances. From this, the researchers were able to measure the energy of the transition state—something that was previously thought impossible due to the complexity of chemical reactions.

“Your reactants and products are stable valleys on either side of a mountain range, and the transition state is the pass,” said Josh Baraban, lead author of the study. “It’s the most convenient way to get from one to the other. Because it only exists as you go from as one thing to another, it’s never really been thought of as something that you can easily study directly.”

This from IFL Science:

The team studied a chemical process called isomerization. In this reaction, one molecule is transformed into another molecule that has the same atoms but they are arranged in a different way. The researchers looked at acetylene, a molecule formed by two carbon atoms bound to each other, and each bound to a hydrogen atom.

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From Solar Energy to Liquid Fuel

Bill Gates—tech mogul, business magnate, and philanthropist for all things good—recently spoke to CNN about the newest technology he believes could transform the world’s energy infrastructure: solar fuels.

Solar fuels have the ability to address energy storage intermittency issues, which is currently one of the biggest challenges in sustainable energy technology according to Gates.

gates-video

Nate Lewis, ECS member since 1982, is one of the leading scientists at the forefront of solar fuel research. Taking inspiration from nature, Lewis and his team aspire to mimic the naturally occurring process of photosynthesis but with higher efficiency levels. Through taking the energy of the sun and storing it in chemical fuels, Lewis and other researchers in the field are propelling the vision of a clean, efficient, and affordable future of energy.

ECS
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