By now we’ve heard about the seemingly endless possibilities for the wonder material graphene. The engineers at Brown University are looking to make those possibilities even more appealing through a process that could make the nanomaterial both water repellant and enhance its electrochemical properties.

The research team is looking to improve upon the already impressive graphene by wrinkling and crumpling sheets of the material by placing it on shrink polymers to enhance its properties, potentially leading to new breakthroughs in batteries and fuel cells.

This from Brown University:

This new research builds on previous work done by Robert Hurt and Ian Wong, from Brown’s School of Engineering. The team had previously showed that by introducing wrinkles into graphene, they could make substrates for culturing cells that were more similar to the complex environments in which cells grow in the body. For this latest work, the researchers led by Po-Yen Chen, a Hibbit postdoctoral fellow, wanted to build more complex architectures incorporating both wrinkles and crumples.

Read the full article.

Crumpling the graphene makes it superhydrophobic, a property that could be used to develop self-cleaning surfaces. Additionally, the enhanced electrochemical properties could be used in next-generation energy storage and production.

“You don’t need a new material to do it,” said Po-Yen Chen, co-author of the study. “You just need to crumple the graphene.”

In an effort to encourage young girls in STEM, Marvel and the National Academy of Sciences’ Science & Entertainment Exchange are working to creating scientific superheroes through the “Girls Reforming the Future Change” challenge.

In conjunction with the upcoming release of Captain America: Civil War, the two organizations have created a program for girls ages 15 to 18 to submit projects they believe could change the world. Through short videos, each contestant is encouraged to explain a STEM related project that could have a far-reaching impact globally.

The project will select five finalists to receive a $500 savings account. Additionally, one lucky contestant will receive the grand prize of an internship at Marvel Studios.

“I’m really excited to meet these exceptional young women who have STEM backgrounds and who maybe also want to be part of more of a creative- and science-based world,” says Elizabeth Olson, actor in the film. “And Marvel’s a perfect place for that.”

Learn more about the project at captainamericachallenge.com.

ECS will be offering five short courses at the 229^th ECS Meeting this year in San Diego.

What are short courses? Taught by academic and industry experts in intimate learning settings, short courses offer students and professionals alike the opportunity to greatly expand their knowledge and technical expertise. 

Short Course #3: Advanced Impedance Spectroscopy

Mark Orazem, Instructor

This course is intended for chemists, physicists, materials scientists, and engineers with an interest in applying electrochemical impedance techniques to study a broad variety of electrochemical processes. The attendee will develop a basic understanding of the technique, the sources of errors in impedance measurements, the manner in which experiments can be optimized to reduce these errors, and the use of graphical methods to interpret measurements in terms of meaningful physical properties.

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Upcycling has become a huge trend in recent years. People are reusing and repurposing items that most wouldn’t give a second glance, transforming them into completely new, high-quality products. So what if we could take that same concept and apply it to the greenhouse gas emissions in the environment that are accelerating climate change?

An interdisciplinary team from UCLA is taking a shot at upcycling carbon dioxide by converting it into a new building material named CO₂NCRETE, which could be fabricated by 3D printers.

“What this technology does is take something that we have viewed as a nuisance – carbon dioxide that’s emitted from smokestacks – and turn it into something valuable,” says J.R. DeShazo, senior member of the research team.

The fact that the team is attempting to produce a concrete-like material is also important. Currently, the extraction and preparation of building materials like concrete is responsible for 5 percent of the world’s greenhouse gas emissions. The upcycling of carbon could cut that number drastically all while reducing the enormous emissions being released from power plants (30 percent of the world’s emissions).

“We can demonstrate a process where we take lime and combine it with carbon dioxide to produce a cement-like material,” says Gaurav Sant, lead scientific contributor. “The big challenge we foresee with this is we’re not just trying to develop a building material. We’re trying to develop a process solution, an integrated technology which goes right from CO₂ to a finished product.”

When the loaves in your breadbox begin to develop a moldy exterior caused by fungi, they tend to find a new home at the bottom of a trash can. However, researchers have recently developed some pretty interesting results that suggest bread mold could be the key to producing more sustainable electrochemical materials for use in rechargeable batteries.

For the first time, researchers were able to show that the fungus Neurospora crassa (better known as the enemy to bread) can transform manganese into mineral composites with promising electrochemical properties.

(MORE: Read the full paper.)

“We have made electrochemically active materials using a fungal manganese biomineralization process,” says Geoffrey Gadd of the University of Dundee in Scotland. “The electrochemical properties of the carbonized fungal biomass-mineral composite were tested in a supercapacitor and a lithium-ion battery, and it [the composite] was found to have excellent electrochemical properties. This system therefore suggests a novel biotechnological method for the preparation of sustainable electrochemical materials.”

This from University of Dundee:

In the new study, Gadd and his colleagues incubated N. crassa in media amended with urea and manganese chloride (MnCl2) and watched what happened. The researchers found that the long branching fungal filaments (or hyphae) became biomineralized and/or enveloped by minerals in various formations. After heat treatment, they were left with a mixture of carbonized biomass and manganese oxides. Further study of those structures show that they have ideal electrochemical properties for use in supercapacitors or lithium-ion batteries.

Read the full article here.

The manganese oxides in the lithium-ion batteries are showing an excellent cycling stability and more than 90 percent capacity after 200 cycles.

A recent pistachio recall is bringing Salmonella and other foodborne illnesses back into the national spotlight. The popularity of the in-shell pistachio brands recalled paired with the long shelf-life of the nut has health experts concerned for the potential of the foodborne illness to spread rapidly. Many are again asking: how can we better control food safety?

Shin Horikawa and his team at Auburn University believe their novel biosensor technology could resolve many of the current issues surrounding the spread of foodborne illnesses. As the principal scientist for a concept hand-picked for the FDA’s Food Safety Challenge, Horikawa is looking to make pathogen detection faster, more specific, and cheaper.

Faster, cheaper, smarter

“The current technology to detect Salmonella takes a really long time, from a few days to weeks. Our first priority is to shorten this detection time. That’s why we came up with a biosensor-based detection method,” Horikawa, Postdoctoral researcher at Auburn University and member of ECS, says.

Horikawa and his team’s concept revolves around the placement of a tiny biosensor—a sensor so small that it’s nearly invisible to the human eye—on the surface of fresh fruits and vegetables to detect the presence of pathogenic organisms such as Salmonella. This on-site, robust detection method utilizes magnetoelastic (ME) materials that can change their shape when a magnetic field is applied. The materials respond differently to each magnetic field, changing their shapes accordingly. This allows the researchers to detect if a specific pathogen—such as Salmonella—has attached to the biosensor.

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Christian Amatore has given a new direction to electrochemistry and has had a pioneering role in the development of ultramicroelectrodes worldwide. He is currently the Director of Research at CNRS and will be giving the ECS Lecture at the 229th ECS Meeting in San Diego, CA, May 29-June 2, 2016. His talk is titled, “Seeing, Measuring and Understanding Vesicular Exocytosis of Neurotransmitters.”

Listen to the podcast and download this episode and others for free through the iTunes Store, SoundCloud, or our RSS Feed. You can also find us on Stitcher.

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ECS will be offering five short courses at the 229^th ECS Meeting this year in San Diego.

What are short courses? Taught by academic and industry experts in intimate learning settings, short courses offer students and professionals alike the opportunity to greatly expand their knowledge and technical expertise. 

Short Course #2: Fundamentals of Electrochemistry: Basic Theory and Thermodynamic Methods

Jamie Noël, Instructor

This course covers the basic theory and application of electrochemical science. It is targeted toward people with a physical sciences or engineering background who have not been trained as electrochemists, but who want to add electrochemical methods to their repertoire of research approaches. There are many fields in which researchers originally approach their work from another discipline but then discover that it would be advantageous to understand and use some electrochemical methods to complement the work that they are doing. The course begins with a general, basic foundation of electrochemistry and uses it to develop the theory and experimental approaches to electrochemical problems of a thermodynamic nature. It complements a sister course, “Fundamentals of Electrochemistry: Basic Theory and Kinetic Methods”, offered alternately by the same instructor. The two courses have different emphasis, and each is designed to be a stand-alone introduction to electrochemical fundamentals. If both courses are desired, they can be taken in either order.

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New research out of Ruhr Universitaet Bochum is showing big gains for water electrolysis, with new efficiency levels double that of previous efforts.

By applying a layer of copper atoms in conventional platinum electrodes, researchers were able to desorption easier for the catalyst surface. This system then generated twice the amount of hydrogen than a platinum electrode without a copper layer.

This breakthrough could help water electrolysis gain a better reputation as a method for hydrogen production. Prior to this breakthrough, too much energy was lost in the process to prove it efficient. Now, the efficiency level has been doubled.

This from Ruhr Universitaet Bochum:

The researchers modified the properties of the platinum catalyst surface by applying a layer of copper atoms. With this additional layer, the system generated twice the amount of hydrogen than with a pure platinum electrode. But only if the researchers applied the copper layer directly under the top layer of the platinum atoms. The group observed another useful side effect: the copper layer extended the service life of the electrodes, for example by rendering them more corrosion-resistant.

Read the full article.

“To date, hydrogen has been mainly obtained from fossil fuels, with large CO2 volumes being released in the process,” said Wolfgang Schuhmann, ECS member and lead author of the study. “If we succeeded in obtaining hydrogen by using electrolysis instead, it would be a huge step towards climate-friendly energy conversion. For this purpose, we could utilize surplus electricity, for example generated by wind power.”

Measuring the pH level of a solution is usually a relatively simple process. However, that process begins to get more complicated as things get smaller.

Examining changes in acidity or alkalinity at the nanoscale, for example, has been a nearly impossible feat for researchers. Now, a team from the Polish Academy of Sciences in Warsaw, including 11 year ECS member Gunter Wittstock, has developed a novel method of pH measurement at the nanoscale.

The group has developed a nanosensor with the ability to continuously monitor changes in pH levels.

This from the Polish Academy of Sciences in Warsaw:

Used as a scanning electrochemical microscope probe, it allows for the precise measurement of changes in acidity/alkalinity occurring over very small fragments of the surface of a sample immersed in a solution. The spatial resolution here is just 50 nm, and in the future, it can be reduced even further.

Read the full article.

“The ability to monitor changes in the acidity or alkalinity of solutions at the nanoscale, and thus over areas whose dimensions can be counted in billionths of a meter, is an important step toward better understanding of many chemical processes. The most obvious examples here are various kinds of catalytic reactions or pitting corrosion, which begins on very small fragments of a surface,” said Marcin Opallo, lead author in the study.

The team hopes that this new method could lead to monitoring of pH changes taking place in the vicinity of individual chemical molecules.