Fuel cells play a major role in creating a clean energy future, with a broad set of applications ranging from powering buildings to electrifying transportation. But, as with all emerging technologies, researchers have faced many barriers in developing affordable, efficient fuel cells and creating a way to cleanly produce the hydrogen that powers them.

In a new Perspective article, published in the Journal of The Electrochemical Society, researchers are aiming to tackle a fundamental debate in key reactions behind fuel cells and hydrogen production, which, if solved, could significantly bolster clean energy technologies.

In the open access article, “Perspective—Towards Establishing Apparent Hydrogen Binding Energy as the Descriptor for Hydrogen Oxidation/Evolution Reactions,” Yushan Yan and his coauthors from the University of Delaware provide an authoritative overview of work done in the areas of hydrogen oxidation and evolution, present key questions for debate, and provide paths for future innovation in the field.

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Researchers have proposed three different methods for providing consistent power in 139 countries using 100 percent renewable energy.

The inconsistencies of power produced by wind, water, and sunlight and the continuously fluctuating demand for energy often hinder renewable energy solutions. In a new paper, which appears in Renewable Energy, the researchers outline several solutions to making clean power reliable enough for all energy sectors—transportation; heating and cooling; industry; and agriculture, forestry, and fishing—in 20 world regions after all sectors have converted to 100 percent clean, renewable energy.

The researchers previously developed roadmaps for transitioning 139 countries to 100 percent clean, renewable energy by 2050 with 80 percent of that transition completed by 2030. The present study examines ways to keep the grid stable with these roadmaps.

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By: Naga Srujana Goteti, Rochester Institute of Technology; Eric Hittinger, Rochester Institute of Technology, and Eric Williams, Rochester Institute of Technology

Carbon-free energy: Is the answer blowing in the wind? Perhaps, but the wind doesn’t always blow, nor does the sun always shine. The energy generated by wind and solar power is intermittent, meaning that the generated electricity goes up and down according to the weather.

But the output from the electricity grid must be controllable to match the second-by-second changing demand from consumers. So the intermittency of wind and solar power is an operational challenge for the electricity system.

Energy storage is a widely acknowledged solution to the problem of intermittent renewables. The idea is that storage charges up when the wind is blowing, or the sun is shining, then discharges later when the energy is needed. Storage for the grid can be a chemical battery like those we use in electronic devices, but it can also take the form of pumping water up a hill to a reservoir and generating electricity when letting it flow back down, or storing and discharging compressed air in an underground cavern.

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By: Joshua D. Rhodes, University of Texas at Austin

Editor’s note: On Jan. 22, 2018, the Trump administration announced plans to impose punitive duties on solar panels imported from abroad. This decision came in response to a complaint filed by two solar companies, but much of the industry opposes the action, which trade groups say will increase the cost of solar projects and depress demand. To illustrate what’s at stake, energy scholar Joshua Rhodes provides some context on the U.S. solar industry and its opportunities and challenges.

How big is the U.S. solar industry, and what is its growth trajectory?

The U.S. solar industry generated US$154 billion in economic activity in 2016, including direct sales, wages, salaries, benefits, taxes and fees. Its revenues have grown from $42 million in 2007 to $210 million in 2017.

About 25 percent of total new power plant capacity installed in 2017 came from solar. Total installed U.S. solar capacity is over 50 gigawatts – the equivalent generating capacity of 50 commercial nuclear reactors.

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Superior high-voltage performance of Li-ion full cell with Li-rich layered oxide cathode prepared with fluorinated polyimide (FPI) binder, compared to the cell with conventional binder PVdF. (Click to enlarge.)
Image: Seung Wan Song

In order to increase the driving range of electric vehicles, researchers across the globe are working to develop lithium-ion batteries with higher energy storage. Now, scientists at Chungnam National University and Kumoh National Institute of Technology in Korea are taking a step toward that goal with their development of the first high-voltage cathode binder for higher energy Li-ion batteries.

Today’s Li-ion batteries are limited to charge to 4.2V due to the electrochemical instability of the liquid electrolyte and cathode-electrolyte interface, and loosening of conventional binder, polyvinylidenefluoride (PVdF), particularly at elevated temperatures. The fabrication of Li-rich layered oxide cathode with a novel high-voltage binder, as the research team demonstrated, can overcome these limitations.

Charging the batteries with Li-rich layered oxide cathode (xLi₂MnO₃∙(1−x)LiMO2, M = Mn, Ni, Co) to higher than 4.5V produces approximately doubled capacity than those with LiCoO₂ cathode, so that doubled energy density batteries can be achieved.

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One year ago, the Chinese government’s energy agency made a long-term commitment to the development of renewable energy sources, investing more than $360 billion in an effort to shift away from coal-powered energy. Now, the country is following through on those promises, paving the way to becoming the global leader in the overall development of clean energy technology.

According to a new report from the Institute of Energy Economics and Financial Analysis (IEEFA), China has continued to grow its clean energy sector in 2017, installing over 50 GW of solar-powered generation.

“The clean energy market is growing at a rapid pace and China is setting itself up as a global technology leader while the U.S. government looks the other way,” said Tim Buckley, co-author of the report. “Although China isn’t necessarily intending to fill the climate leadership void left by the U.S. withdrawal from Paris, it will certainly be very comfortable providing technology leadership and financial capacity so as to dominate fast-growing sectors such as solar energy, electric vehicles, and batteries.”

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Water-based rechargeable batteries could be one step closer to commercial viability, thanks to research from Empa. According to a new report, a team of researchers has successfully doubled the electrochemical stability of water with a special saline solution.

Energy storage is the backbone of many technological innovations. As researchers explore new ways to develop low-cost, safe batteries, the research team from Empa is looking to water to function as a battery electrolyte.

While a water-electrolyte offers many potential benefits such as low cost and high availability, it does have at least one major drawback: low chemical stability. At a voltage of 1.23 volts, a water cell supplies three times less voltage than a typical lithium-ion cell. While water-based batteries may not see an application in such technologies as electric vehicles, the team of researchers at Empa believe they could be utilized for stationary electricity storage applications.

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Nitrogen-doped carbon nanotubes or modified graphene nanoribbons could be effective, less costly replacements for expensive platinum in fuel cells, according to a new study.

In fuel cells, platinum is used for fast oxygen reduction, the key reaction that transforms chemical energy into electricity.

The findings come from computer simulations scientists created to see how carbon nanomaterials could be improved for fuel-cell cathodes. Their study reveals the atom-level mechanisms by which doped nanomaterials catalyze oxygen reduction reactions (ORR).

Doping with nitrogen

Boris Yakobson, a professor of materials science and nanoengineering and of chemistry at Rice University, and his colleagues are among many researchers looking for a way to speed up ORR for fuel cells, which were discovered in the 19th century but not widely used until the latter part of the 20th. Fuel cells have since powered transportation modes ranging from cars and buses to spacecraft.

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ECS members M. Stanley Whittingham and Yury Gogotsi will be panelists at the upcoming “Electrical Energy Storage Technologies That Enable the Future” symposium, hosted by the Chemical Heritage Foundation. The event will take place on January 11, 2018 in Philadelphia, PA. Read the full program below.

Moderator
Daryl Boudreaux, Principal, Boudreaux & Associates

Panelists
M. Stanley Whittingham, Distinguished Professor of Chemistry and Materials Science and Engineering, SUNY Binghamton

Yury Gogotsi, Distinguished University Professor of Materials Science and Engineering, Drexel University

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A new flexible, transparent electrical device inspired by electric eels could lead to body-friendly power sources for implanted health monitors and medication dispensers, augmented-reality contact lenses, and countless other applications, researchers report.

The soft cells—made of hydrogel and salt—form the first potentially biocompatible artificial electric organ that generates more than 100 volts. It produces a steady buzz of electricity at high voltage but low current, a bit like an extremely low-volume but high-pressure jet of water. It could be enough to power a small medical device like a pacemaker.

While the technology is preliminary, Michael Mayer, a professor of biophysics at the Adolphe Merkle Institute of the University of Fribourg in Switzerland and the paper’s corresponding author, believes it may one day be useful for powering implantable or wearable devices without the toxicity, bulk, or frequent recharging that come with batteries.

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